• Title/Summary/Keyword: [O]/[$N_2$] ratio

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A study on the nature of needle-like inclusions in corundum crystals (커런덤의 침상내포물 본질에 관한 연구)

  • 배상덕;김상기;최종건;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.3
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    • pp.101-104
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    • 2004
  • It was realized that MC-XRD is useful for phase analyzing of inclusions in crystals because it can focus the X-Ray beam to the small particles sized dozens of $\mu\textrm{m}$ with high S/N ratio. By using this MC-XRD, needle-like inclusions which are seen generally in corundum crystals known as rutile was found to be the iron titanium oxide and iron oxide which has the chemical composition of $Fe_2TiO_4,\; Fe_2TiO_5,\; Fe_2O_3$respectively

Measurement of excited species in discharges using Laser Absorption spectroscopy

  • Sakai, Yosuke
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.5-8
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    • 2000
  • The population density of excited species in dc, rf and laser ablation plume plasmas has been measured using laser absorption spectroscopy. It was shown that, when the plasma was modulated by on and off with, the sensitivity and signal to noise (S/N) ratio became high. For example, the atomic O(3$^{5}$ S$^{o}$ $_2$) Population density, No* in $O_2$/He mixtures was obtained by the highest S/N ratio at a frequency of 2.7kHz. In a 20Torr room air, the lowest No* level to be detectable was shown to be an order of 10$^{7}$ cm$^{-3}$ . The population densities of resonance Ar(1S$_2$) and Xe(1S$_4$) levels were also measured in barrier discharges and laser ablation plasmas.

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Nutrients removal and microbial activity for A2O Process Using Activated Sludge Models (활성슬러지 모델을 이용한 A2O공법 영양염류 제거 및 미생물 거동)

  • Yoon, Hyunsik;Kim, Dukjin;Choi, Bongho;Kim, Moonil
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.889-896
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    • 2012
  • In this study, simulation results of nitrogen and phosphorus removals and microbial activities for an $A_2O$ process in wastewater treatment plant are presented by using Activated Sludge Models (ASMs). Simulations were performed using pre-calibrated model and layout implemented in GPS-X simulation software. The models were used to investigate variations of SRT, water temperature, DO and C/N ratio effect on nutrients removal and microbial activity. According to the simulated results, the successful nitrification required SRT higher than 10.3 days, whereas increase of $NO_3$-N loading in the anaerobic reactor caused phosphorus release by PAOs; the effluent $NH_4$-N showed rapid change between $12^{\circ}C$(21.7 mg/L) and $13^{\circ}C$(3.2 mg/L); the effluent phosphorus was increased up to 1.9 mg/L at water temperature of $25^{\circ}C$; the DO increase was positive for heterotrophs and autotrophs growths but negative for PAOs growth; the PAOs showed low activity when C/N ratio was lower than 2.5. The experimental results indicated that the calibrated models can assure the prediction quality of the ASMs and can be used to optimize the $A_2O$ process.

Studies on the Chemical Structure of the New Polysaccharide C - (The New Polysaccharides of Gum Tragacanth. II) - (Tragacanth gum 의 신다당류(新多糖類) C 의 화학구조(化學構造) - Tragacanth gum의 신다당류(新多糖類)에 관(關)한 연구(硏究) 제2보(第二報) -)

  • Lee, Sung-Hwan
    • Applied Biological Chemistry
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    • v.3
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    • pp.25-48
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    • 1962
  • The polysaccharide C prepared from gum tragacanth powder (U. S. P. grade) by the precipitation method with 85% ethanol was a neutral polysaccharide, $[{\alpha}]^{30}_D-72.2$. The polysaccharide C consisted of L-rhamnose, D-xylose, L-arabinose and D-galactose in the molar ratio 2:1:17:9 (Table 1, 2, 3, ). The polysaccharide C was methylated with dimethylsulphate and 40% NaOH, and Purdies regent. The hydrolyzate of fully methlated product ($[{\alpha}]^{22}_D-102$ in chloroform, the methoxy content 40.6%) was composed of 2, 3, 5-tri-O-methyl-L-arabofuranose (I), 3,4-di-O-methyl-L-rhamnopyranose (II), 2,3-di-O-methyl-D-xylose (III), 2,3,4-tri-O-methyl-D-galactopyranose (IV), 2,4-di-O-methyl-L-arabopyranose (?), 2,4-di-O-methyl-D-galactose(VI), 2-O-methyl-D-arabinose (VII), and L-arabopyranose(VIII) (Table 4, 5, and Fig. 4). The first partial hydrolysis (A) of the polysaccharide C with 0.05N-HCl for 4.5 hours at $80-85^{\circ}C$ released only L-arabinose: the second hydrolysis (B) with 0.1N-HCl for 5 hours at $80-85^{\circ}C$, L-arabinose and D-galactose; and the third hydrolysis (C) with 0.3N-HCl at $90-95^{\circ}C$ in sealed tube, L-rhamnose, D-xylose, L-arabinose and D-galactose. From the unhydrolyzate A' were found L-rhamnose, D-xylose, L-arabinose, and D-galactose; from B' L-rhamnose, d-xylose, L-arabinose and D-galactose; and from C' D-xylose and D-galactose respectively (Table 6). The periodate consumption and formic acid production of the polysaccharide C were measured at various time intervals. After 120 hours periodat was consumed by 1.23 mole per $C_5H_8O_4$ and formic acid was produced 0.78 mole per $C_5H_8O_4$ (Table 7). Although a definite chemical structure for this polysaccharide C may not be formulated, experimental data, especially, from methylation, partial hydrolysie and determination of its molar ratio, and periodate analysis showed that the polysaccharide C is a highly branched polysaccharide and would be constructed of galactoaraban as a main chain residue and L-arabofuranose, D-galactopyranosyl $(1{\rightarrow}1)$-L-arabofuranose, D-xylopyranosyl $(1{\rightarrow}2)$-L-rhamnopyranosyl $(1{\rightarrow}1)$-L-arabofuranose, and L-rhamnopyranosyl $(1{\rightarrow}1)$-arabofuranose, and D-galactopyranosyl-$(1{\rightarrow}2)$-L-arabopyranosyl-$(1{\rightarrow}1)$-I-arabofuranose as a branch chain or end group (page 21).

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A Parallel Algorithm for Merging Heaps on MasPar Machine (MasPar 머쉰상의 병렬 힙 병합 알고리즘)

  • Min, Yong-Sik
    • The Transactions of the Korea Information Processing Society
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    • v.2 no.4
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    • pp.554-560
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    • 1995
  • In this paper, we suggest a parallel algorithm to merge priority queues organized in two heaps, kheap and nheap of sizes k and n, correspondingly. Employing max(2$^{-1}$, $\ulcorner$(m+1)/4$\lrcorner$'s processors, this algorithm requires O(log(n/k)*log(n)) on an EREW-PRAM, where i is the height of the heap and m is the summation of sizes n and k. Also, when we run it on the MasPar machine, this method achieves a 33.934-fold speedup with 64 processors to merge 8 million data items which consist of two heaps of different sizes. So our parallel algorithm's EPU is close to 1, which is considered as an optimal speedup ratio.eedup ratio.

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Characteristics of Piezoelectric and dielectric of PMWN-PZT Ceramics (PMWN-PZT계 압전세라믹의 압전 및 유전특성)

  • 홍종국;이종섭;채홍인;윤만순;정수현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.6
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    • pp.455-459
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    • 2001
  • In this paper, the dielectric and pizoelectric properties of 0.05Pb(M $n_{04}$ $W_{0.2}$N $b_{0.4}$) $O_3$-0.95(PbZ $r_{x}$ $Ti_{1-x}$ ) $O_3$+yN $b_2$ $O_{5}$ , are investigated as a function of the mole ratio of Zr and the amount of N $b_2$ $O_{5}$ . Also, the phase is analyzed by XRD. When the mole ratio of Zr is 0.51, the electromechanical coupling coefficient( $k_{p}$ ), relative dielectric constant ($\varepsilon$$^{T}$ $_{33}$ /$\varepsilon$$_{0}$ ), piezoelectric stain constrain ( $d_{33}$ and dielectric loss tangent show maximum, while the mechanical quality factor shows minimum value ; $k_{p}$ =56.5%, $d_{33}$ =258pC/N, $\varepsilon$$^{T}$ $_{33}$ /$\varepsilon$$_{0}$ =1170, $Q_{m}$ =1150, tan$\delta$=0.51%. At that composition, MPB which rhombohedral and tetragonal phase coexist in this ternary system is shown by the results of XRD analysis. Also, when the amount of N $b_2$ $O_{5}$ is 0.3wt%, the mechanical quality factor is increased to about 2000. The phase transition temperature of the ternary piezoelectric ceramic system showed about 35$0^{\circ}C$.TEX>.>.>.

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Strength Development Characteristics of Clay Stabilized with Electric Furnace Steel Slag (전기로 제강슬래그로 안정화된 연약점토의 강도 발현 특성)

  • Hyeongjoo Kim;Taegew Ham;Taewoong Park;Taeeon Kim
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.5
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    • pp.29-37
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    • 2024
  • This study aimed to investigate the changes in chemical components that occur when weak clay is mixed with steel slag modified with calcium oxide, and to understand the expression characteristics of compressive strength according to hydrophilicity and curing time. XRF testing, SEM imaging, vane shear strength and uniaxial compressive strength testing were conducted. Calcium (Ca) released from the steel slag increases the Ca content in clay by increasing the number of crystal particles and forming a coating layer known as calcium silicate hydrate (CaO-SiO2-H2O) through chemical reactions with SiO2 and Al2O3 components. The weak clay stabilized with steel slag is classified into an initial inactive zone where strength relatively does not increase and an activation zone where strength increases over curing time. The vane shear strength of the initial inactive area was found to be 4.4 to 18.4 kN/m2 in the state of the weight mixing ratio Rss 30% (steel slag 30% + clay 70%). In the case of the active area, the maximum uniaxial compressive strength increased to 431.8 kN/m2 after 480 hours of curing time, which increased due to the apparent adhesion strength of clay through pozzolanic reaction. Therefore, considering the strength expression characteristics of stabilized mixed clay based on the mixing ratio (Rss) during the recycling of steel slag can enhance its practicality in civil engineering sites.

A Simple Way to Prepare Nanosize NiO Powder by Mixing Acidic Ni Compound with Basic Ni Compound

  • Cheong, Deock-Soo;Yun, Dong-Hun;Park, Sang-Hwan;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.592-595
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    • 2009
  • Nanosize NiO powder was prepared by mixing acidic nickel nitrate with basic nickel carbonate. The particle size and morphology of NiO were mainly governed by the mole ratio of the nitrate to the carbonate. The effects were studied by DSC, XRD, FTIR, and SEM. Heat treatment conditions influence the particle size distribution of produced NiO powder extensively for the case of 3N7C (3 moles of the nitrate and 7 moles of the carbonate) and 4N6C, but only slightly for 1N9C and 2N8C. Uniform pseudospherical NiO particles were obtained in $50{\sim}70$ nm for 1N9C and $30{\sim}60$ nm for 2N8C by calcination at $750{^{\circ}C}$ for 2 h.

Changes of Chemical Compounds in Compost of Municipal Refuse;3. Changes of C/N Ratios in Compost (폐기물의 퇴비화 과정중 물질 변화;3. C/N 율 변화)

  • Seo, Jeoung-Yoon
    • Korean Journal of Environmental Agriculture
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    • v.8 no.1
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    • pp.55-59
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    • 1989
  • To determine the accurate C/N ratio of compost, biodegradable carbon and nitrogen in compost must be analyzed. In biodegradable nitrogen analyzed by Kjeldahl Method, nitrate and nitrite which are available for microbes can not be detected at all. By means of $F{\"{o}}rster$ Method, nitrate and nitrite can be detected. Therefore, various nitrogens in compost were analyzed by Kjeldahl and $F{\"{o}}rster$ Method to investigate the seasonal changes of various C/N ratios of compost. C/N ratios in compost analyzed by Kjeldahl and $F{\"{o}}rster$ Method were decreased rapidly within 2 weeks after composting, then were not changed to 6 weeks, and thereafter were decreased slowly with the lapse of composting time. C/N ratios analyzed by Kjeldahl Method were higher than those analyzed by $F{\"{o}}rster$ Method. C/N ratios of total carbon/total nitrogen analyzed by Kjeldahl Method were higher(5 as C/N ratio or 36%) than those of biodegradable carbon/biodegradable nitrogen analyzed by $F{\"{o}}rster$ Method. Highly positive correlations were observed among C/N ratios of total carbon/total nitrogen analyzed by Kjeldahl Method total carbon/total nitrogen analyzed by $F{\"{o}}rster$ Method and biodegradable carbon/biodegradable nitrogen analyzed by $F{\"{o}}rster$ Method one another.

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Sintering of $\alpha{\;}-{\;}Al_2O_3$ with NaOH (가성소다를 이용한 $\alpha{\;}-{\;}Al_2O_3$의 소결반응)

  • 김재용;이진수;서완주;박수길;엄명헌
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.95-101
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    • 2000
  • This study was investigated to the reaction of alumina sintering with alkaline. The soluble $NaAlO_2$ was made after the commercial ${\alpha}-Al_2O_3$ was calcinated with NaOH. The reaction of alumina was carried out to be based on the effects of calcination temperature, time, and the mixing ratio of ${\alpha}-Al_2O_3/NaOH$. The alumina was calcined over $500^{\circ}C$ with NaOH powder after it was sieved with 170/270 mesh. The calcined alumina with NaOH powder was dissolved into $25^{\circ}C$ distilled water and filtrated, and HCI was added to adapt pH 6.5~7.5. The residue was separated with vacuum pump for filtration after it was adapted to proper pH, and aluminum compound was precipitated with $Al(OH)_3$. The investigation was carried out with the variables; the calcination temperature($500-900^{\circ}C$), the calcination time (30~90 min), and the concentration of HCI when leaching(0.5~3.0N) respectively. In this investigation, the main product of ${\alpha}-Al_2O_3$ and NaOH was $NaAlO_2$ and the maximum conversion ratio was 91.4% under the optimum conditions as followed ; the ratio of NaOH/${\alpha}-Al_2O_3$ was 1.5 and the calcination conditions were $800^{\circ}C$ and 90 min.

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