• 제목/요약/키워드: , amorphous

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동기지 동계 Bulk Amorphous 복합재의 압축 변형거동 (Deformation behavior in Cu-based bulk amorphous alloys composite during compression)

  • 이창호;김지수;박은수;허무영
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2004년도 추계학술대회논문집
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    • pp.203-206
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    • 2004
  • Copper-based bulk amorphous alloy composite was synthesized by using the copper-coated $Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ amorphous powder which was obtained by argon gas atomization. The amorphous powder having a super-cooled liquid region of 53 K was coated by crystalline copper by electroless coating. The consolidation was carried out by manufacturing performs and by the subsequent warm extrusion at 743 K. During the compression test at the room temperature, the composite containing a large fraction of crystalline copper displayed a larger plastic strain after yielding. FEM simulation revealed change in fracture modes in the composites depending on the amount of crystalline copper in the composites.

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Vertical Diffusion of Ammonia Into Amorphous Ice Sturcture

  • 김영순;문의성;강헌
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.280-280
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    • 2012
  • We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

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Switching Characteristics of Amorphous GeSe TFT for Switching Device Application

  • 남기현;김장한;조원주;정홍배
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.403-404
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    • 2012
  • We fabricated TFT devices with the GeSe channel. A single device consists of a Pt source and drain, a Ti glue layer and a GeSe chalcogenide channel layer on SiO2/Si substrate which worked as the gate. We confirmed the drain current with variations of gate bias and channel size. The I-V curves of the switching device are shown in Fig. 1. The channel of the device always contains amorphous state, but can be programmed into two states with different threshold voltages (Vth). In each state, the device shows a normal Ovonic switching behavior. Below Vth (OFF state), the current is low, but once the biasing voltage is greater than Vth (ON state), the current increases dramatically and the ON-OFF ratio is high. Based on the experiments, we draw the conclusion that the gate voltage can enhance the drain current, and the electric field by the drain voltage affects the amorphous-amorphous transition. The switching device always contains the amorphous state and never exhibits the Ohmic behavior of the crystalline state.

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Electrical Switching Characteristics of Thin Film Transistor with Amorphous Chalcogenide Channel

  • 남기현;김장한;정홍배
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.280-281
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    • 2011
  • We fabricated the devices of TFT type with the amorphous chalcogenide channel. A single device consists of a Pt source and drain, a Ti glue layer and a GeSe chalcogenide channel layer on SiO2/Si substrate which worked as the gate. We confirmed the drain current with variations of gate bias and channel size. The I-V curves of the switching device are shown in Fig. 1. The channel of the device always contains amorphous state, but can be programmed into two states with different threshold voltages (Vth). In each state, the device shows a normal Ovonic switching behavior. Below Vth (OFF state), the current is low, but once the biasing voltage is greater than Vth (ON state), the current increases dramatically and the ON-OFF ratio is about 4 order. Based on the experiments, we contained the conclusion that the gate voltage can enhance the drain current, and the electric field by the drain voltage affects the amorphous-amorphous transition. The switching device always contains the amorphous state and never exhibits the Ohmic behavior of the crystalline state.

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Cu-Zr-Ti-Ni-Pd계 비정질 벌크합금의 형성과 성질 (Cu-based Bulk Amorphous Alloys in the Cu-Zr-Ti-Ni-Pd System)

  • 김성규;배차헌
    • 한국주조공학회지
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    • 제22권6호
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    • pp.304-308
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    • 2002
  • The new Cu-Zr-Ti-Ni-Pd amorphous alloy system has been introduced and manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties of the alloys were examined. The reduced glass transition temperature(Trg = Tg/Tm) and the supercooled liquid region(${\Delta}$Tx = Tx-Tg) of $Cu_{49}Zr_{30}Ti_{10}Ni_5Pb_6$ alloy were 0.620 and 57 K respectively. $Cu_{49}Zr_{30}Ti_{10}Ni_5Pb_6$ amorphous alloy was produced in the rod shape with 2mm diameter using the Cu-mold die casting. The hardness value of the amorphous bulk alloy was 432 DPN.

Ni기 비정질 벌크합금의 제조와 기계적 성질 (Fabrication and Mechanical Properties of Ni-based Amorphous Bulk Alloys)

  • 김성규
    • 한국주조공학회지
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    • 제22권6호
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    • pp.288-292
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    • 2002
  • Ni-base amorphous alloys were manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The reduced glass transition temperature and the supercooled liquid region of $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$alloy were 0.621 and 46 K respectively. $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$ alloy was produced in the rod shape 3mm diameter using the Cu-mold die casting. Hardness, compression strength, elongation and elastic modulus of the alloy were 850 DPN, 2.75 GPa, 1.8% and 150 GPa respectively. Moreover, compression strength of 2.75 GPa was the highest value in the amorphous bulk alloy produced up to now.

메조스코픽 구조를 가지는 급냉응고 Al-Nd-(Cu,Ag)합금의 기계적 성질 (Mechanical Properties in Rapidly Solidified Al-Nd-(Cu,Ag) Alloys with Mesoscopic Structure)

  • 고근우;김영환;김한군
    • 열처리공학회지
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    • 제12권4호
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    • pp.320-326
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    • 1999
  • In rapidly solidified $Al_{92-x}Nd_8$(Cu,Ag)x ($0{\leq}X{\leq}10at%$) alloys, amorphous single phases were obtained in the ranges of $Oat%{\leq}X{\leq}4at%$ for Al-Nd-Cu system and $Oat%{\leq}X{\leq}6at%$ for Al-Nd-Ag system, respectively. Mesoscopic structures consisted of amorphous and crystalline phases were formed above solute ranges. It was founded that the mesoscopic structures were also formed near 1st exothermic peak on DSC curve by aging in amorphous single phase alloys. For example, amorphous $Al_{92-x}Nd_8$(Cu,Ag)x (X=2.4at%) alloys containing nanoscale Al particles and compounds, i.e., mesoscopic structure, exhibited higher tensile fracture strength(${\sigma}_f$) than those of amorphous single phase alloys with the same composition. The ${\sigma}_f$ showed a maximum value in the $V_f$ ranges of 10~15%. The reason is presumed that the nanoscale precipitates which have higher mechanical strength compared with the amorphous phase with the same composition act as an effective resistance to shear deformation of the amorphous matrix.

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기계적 손상이 비정질 규소박막의 결정화에 미치는 영향 (Effect of mechanical damage on the crystallization of amorphous silicon thin film)

  • 문권진;김영관;윤종규
    • 한국결정성장학회지
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    • 제8권2호
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    • pp.299-306
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    • 1998
  • 비정질 규소가 결정질로 되기 위해서는 활성화가 필요하다. 이 활성화는 레이저 및 로내에서의 열처리로 열에너지를 가하면 달성될 수 있다. 이때 이 열에너지 외에 기계적 에너지 등을 가하면 활성화에 도움이 될 수 있을 것이다. 본 연구에서는 습식연마와 자기이온주입 등의 방법으로 기계적 손상을 주어서 이것이 LPCVD로 증착된 비정질 규소 박막의 결정화에 미치는 영향을 조사하였다. 결정성 확인을 위해서는 XRD와 라만분석법을 사용하였다. 본 연구의 결과, 기계적 손상이 비정질 규소 박막의 결정화를 증진시키는 것을 확인하였다.

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Digital Radiography용 amorphous selenium 시편의 누설전류에 관한 연구 (The Study of Dark Current of Amorphous Selenium Plate for Digital Radiography Applications)

  • 강영수;강원석;정성훈;박성광;남상희
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1998년도 추계학술대회
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    • pp.293-294
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    • 1998
  • In this paper, the electric properties of amorphous selenium specimen has been investigated. Amorphous selenium was thermally evaporated on the glass plate which had been deposited onto the interface by aluminium as an electrode. On the surface of the amorphous selenium, the aluminium electrode was deposited again in order to make an unit cell for dark current measurement. The dark current was measured while applying the bias voltage across the selenium layer in the range of 0V-2500 Volts. The leakage property of the amorphous selenium was significantly low at even high voltage range so it has good advantage as a X-ray receptor for digital radiography. For further study, the C-V curves measurement according to thicker amorphous selenium layer.

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게터용 Zr57V36Fe7 합금의 수소 흡수특성에 미치는 비정질화의 영향 (The Effects of Amorphization on Hydrogen Absorption Properties of Zr57V36Fe7 Getter alloy)

  • 박제신;서창열;김원백
    • 한국재료학회지
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    • 제15권12호
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    • pp.802-808
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    • 2005
  • The hydrogen sorption speeds of $Zr_{57}V_{36}Fe_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature $Zr_{57}V_{36}Fe_7$ amorphous alloy was prepared by ball milling. The amorphous alloy was crystallized through two stages. Initially, $\alpha-Zr$ solid solution was appeared from the amorphous phase. Two cubic Laves compounds were precipitated afterwards from the remained amorphous and from excessively saturated solid solution at higher temperature. The hydrogen sorption speed of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption speed of partially crystallized alloy was explained in terms of surface oxygen stability which has been known to retard the activation of amorphous alloys. The retardation could be reduce by crystallization process resulting in the observed increase in sorption property.