• Title/Summary/Keyword: (m, n)-ideal

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Relationship between the porosity of the nanostructured $TiO_2$ electrode and Dye Loading for Dye-sensitized Solar Cells (염료감응태양전지를 위한 $TiO_2$ 분말 기공도와 염료 흡착량의 관계)

  • Hwang, Seongjin;Jung, Hyunsang;Jeon, Jaeseung;Kim, Hyungsun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.68.2-68.2
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    • 2010
  • Dye-sensitized solar cells (DSSC) show great promise as an inexpensive alternative to conventional p-n junction solar cells. Investigations into the various factors influencing the photovoltaic efficiency have recently been intensified. The conventional absorber electrode in DSSC is composed of compacted or sintered $TiO_2$ nanopowder that carries an anchored organic dye. The absorbance of incident light in the DSC is realized by specifically engineered dye molecules placed on the semiconductor electrode surface ($TiO_2$). The dye absorbs light at wavelengths up to about 920nm, the energy of the exited state of the molecule should be about 1.35eV above the electronic ground state corresponding to the ideal band gap of a single band gap solar cell. The dye molecules ar adhered onto the nanostrutured $TiO_2$ electrode by immersing the sintered electrode into a dye solution, typically 3mM in alcohol, for a long enough period to fully impregnate the electrode. However, the concentrations of the dye is slightly changed due to the evaporation of the alcohol. The dye is more expensive than other materials in DSSC and related to the efficiency of DSSC. Therefore, the concentrations of the dye should be carefully measured. In this study, we investigated to the dye loading on fired $TiO_2$ powder as a function of temperature by the TG-DTA and the dye solution by UV-visible spectroscopy after the impregnation process. The dye loading is related to the porosity of the nanostructured $TiO_2$ electrode.

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Electrochemical Detection of Hydrogen Peroxide based on Hemoglobin-DNA/pyterpy Modified Gold Electrode (Hemoglobin-DNA/pyterpy 박막을 이용한 과산화수소의 전기화학적 검출)

  • Lee, Dong-Yun;Choi, Won-Suk;Park, Sang-Hyun;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1295-1296
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    • 2008
  • Hydrogen peroxide ($H_2O_2$) biosensor is one of the most developing sensors because this kind of sensors is highly selective and responds quickly to the specific substrate. Hemoglobin (Hb) has been used as ideal biomolecules to construct hydrogen peroxide biosensors because of their high selectivity to $H_2O_2$. The direct electron transfer of Hb has widely investigated for application in the determination of $H_2O_2$ because of its simplicity, high selectivity and intrinsic sensitivity. An electrochemical detection for hydrogen peroxide was investigated based on immobilization of hemoglobin on DNA/Fe(pyterpy)$^{2+}$ modified gold electrode. The pyterpy monolayers were firstly an electron deposition onto the gold electrode surface of the quartz crystal microbalance (QCM). It is offered a template to attach negatively charged DNA. The fabrication process of the electrode was verified by quartz crystal analyzer (QCA). The experimental parameters such as pH, applied potential and amperometric response were evaluated and optimized. Under the optimized conditions, this sensor shows the linear response within the range between $3.0{\times}10^{-6}$ to $9.0{|times}10^{-4}$ M concentrations of $H_2O_2$. The detection limit was determined to be $9{\times}10^{-7}$ M (based on the S/N=3).

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Genetics and Breeding for Modified Fatty Acid Profile in Soybean Seed Oil

  • Lee, Jeong-Dong;Bilyeu, Kristin D.;Shannon, James Grover
    • Journal of Crop Science and Biotechnology
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    • v.10 no.4
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    • pp.201-210
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    • 2007
  • Soybean [Glycine max(L.) Merr.] oil is versatile and used in many products. Modifying the fatty acid profile would make soy oil more functional in food and other products. The ideal oil with the most end uses would have saturates(palmitic + stearic acids) reduced from 15 to < 7%, oleic acid increased from 23 to > 55%, and linolenic acid reduced from 8 to < 3%. Reduced palmitic acid(16:0) is conditioned by three or more recessive alleles at the Fap locus. QTLs for reduced palmitic acid have mapped to linkage groups(LGs) A1, A2, B2, H, J, and L. Genes at the Fad locus control oleic acid content(18:1). Six QTLs($R^2$=4-25%) for increased 18:1 in N00-3350(50 to 60% 18:1) explained four to 25% of the phenotypic variation. M23, a Japanese mutant line with 40 to 50% 18:1 is controlled by a single recessive gene, ol. A candidate gene for FAD2-1A can be used in marker-assisted breeding for high 18:1 from M23. Low linolenic acid(18:3) is desirable in soy oil to reduce hydrogenation and trans-fat accumulation. Three independent recessive genes affecting omega-3 fatty acid desaturase enzyme activity are responsible for the lower 18:3 content in soybeans. Linolenic acid can be reduced from 8 to about 4, 2, and 1% from copies of one, two, or three genes, respectively. Using a candidate gene approach perfect markers for three microsomal omega-3 desaturase genes have been characterized and can readily be used in for marker assisted selection in breeding for low 18:3.

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Vegetation Characteristics of Evergreen Broad-Leaved Forest in the Duryunsan Provincial Park -Focusing on the Daeheungsa(Temple) Area- (두륜산도립공원 상록활엽수림의 식생 특성)

  • Kang, Hyun-Mi
    • Korean Journal of Environment and Ecology
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    • v.33 no.5
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    • pp.552-564
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    • 2019
  • The purpose of this study was to investigate vegetation characteristics of evergreen broad-leaved forests in the area of Duryunsan Provincial Park, where the deciduous broad-leaved trees and evergreen broad-leaved trees are mixed and thus had a high botanical value. To investigate the vegetation characteristics, we installed 40 quadrats with an area of $100m^2$ each for survey and analysis. Haenam-gun, where the Duryunsan Provincial Park is located, is a warm-temperate forest region. The meteorological data for the past 40 years showed a coldness index of $-8^{\circ}C$, a monthly warmth index of $109.2^{\circ}C$, and annual mean precipitation of 1,310.5mm, indicating it is an ideal habitat for the distribution of evergreen broad-leaved forest. The results of community classification based on TWINSPAN showed three categories of vegetation communities in the surveyed region: Quercus acuta community-I, Q. acuta community-II, and Neolitsea sericea-Aphananthe aspera community. In the evergreen broad-leaved forest in the Duryunsan Provincial Park, Q. acuta dominant in the canopy were expanding their presence in the understory. In addition to the Q. acuta, N. sericea and Cinnamomum yabunikkei, which are evergreen broad-leaved trees of the canopy, were found in all layers. The deciduous broad-leaved trees such as Q. variabilis, Q. serrata, and Carpinus tschonoskii were culled, and the transition to Q. acuta evergreen broad-leaved trees was ongoing. N. sericea community appeared locally. The species diversity index of N. sericea-A. aspera community was lower at 1.0798 than that of Q. acuta Community-I at 1.3208 and Q. acuta Community-II at 1.4916.

A Study on the Spalling Properties of High Strength Concrete Using Synthetic Fiber (유기섬유를 혼입한 고강도 콘크리트의 폭렬 특성에 관한 실험적 연구)

  • Jeon, Chan Ki;Jeon, Joong Kyu
    • Journal of the Society of Disaster Information
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    • v.8 no.1
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    • pp.18-26
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    • 2012
  • Accordingly architectural structure is getting high-rise and bigger, a use of high strength and high performance concrete has been increasing. High performance concrete has cons of explosion in a fire. This Explosion in the fire can cause the loss of the sheath on a concrete surface, therefore it effects that increasing a rate of heat transmission between the steel bar and inner concrete. Preventing this explosion of high performance concrete in the fire, many kinds of researches are now in progressing. Typically, researches with using Polypropylene-fiber and Steel-fiber can prove controling the explosion, but the reduction of mobility was posed as a problem of workability. Consequently, to solve the problem as mentioned above, concrete cans secure fire resisting capacity through the using of coating liquid, including Ester-lubricant and non-ionic characteristic surfactant. This research has been drawn a ideal condition in compressive strength areas of concrete by an experiment. When applying 13mm of polyamide-fiber, proper fiber mixing volume by compressive strength areas of concrete is $0.8kg/m^3$ in 60MPa, $1.0kg/m^3$ in 80MPa, $1.5kg/m^3$ in $100MPa/m^3$. These amount of a compound can control the explosion.

Improvement of Radiosynthesis Yield of [11C]acetate ([11C]아세트산의 방사화학적 수율 증가를 위한 연구)

  • Park, Jun Young;Son, Jeongmin
    • The Korean Journal of Nuclear Medicine Technology
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    • v.22 no.2
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    • pp.74-78
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    • 2018
  • Purpose $[^{11}C]$acetate has been proved useful in detecting the myocardial oxygen metabolism and various malignancies including prostate cancer, hepatocellular carcinoma, renal cell carcinoma and brain tumors. The purpose of study was to improve the radiosynthesis yield of $[^{11}C]$acetate on a automated radiosynthesis module. Materials and Methods $[^{11}C]$acetate was prepared by carboxylation of grignard reagent, methylmagnesium chloride, with $[^{11}C]$$CO_2$ gas, followed by hydrolysis with 1 mM acetic acid and purification using solid phase extraction cartridges. The effect of the reaction temperature ($0^{\circ}C$, $10^{\circ}C$, $-55^{\circ}C$) and cyclotron beam time (10 min, 15 min, 20 min, 25 min) on the radiosynthesis yield were investigated in the $[^{11}C]$acetate labeling reaction. Results The maximum radiosynthesis yield was obtained at $-10^{\circ}C$ of reaction temperature. The radioactivities of $[^{11}C]$acetate acquired at $-10^{\circ}C$ reaction temperature was 2.4 times higher than those of $[^{11}C]$acetate acquired at $-55^{\circ}C$. Radiosynthesis yield of $[^{11}C]$acetate increased with increasing cyclotron beam time. Conclusion This study shows that radiosynthesis yield of $[^{11}C]$acetate highly dependent on reaction temperature. The best radiosynthesis yield was obtained in reaction of grignard reagent with $[^{11}C]$$CO_2$ at $-10^{\circ}C$. This radiolabeling conditions will be ideal for routine clinical application.

Effect of Salts and Isomeric Butanols on the Mixed Micellar Properties of Cetylpyridinium Chloride with Triton X-100 (Cetylpyridinium Chloride와 Triton X-100의 혼합 미셀화에 미치는 염 및 부탄올 이성질체들의 효과)

  • Chung, Jong-Jae;Lee, Sang-Hak;Kim, Yung-Cheol;Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.968-973
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    • 1998
  • The critical micelle concentrations($CMC^*$) of the mixed surfactant systems of cationic surfactant cetylpyridinium chloride(CPC) and nonionic surfactant Triton X-100(TX-100) in aqueous solutions of salts(KCl and $Na_2CO_3$) and isomeric butanols(tert-butanol, iso-butanol and n-butanol) were determined by UV spectroscopy method. The various thermodynamic values in aqueous solutions of salts and isomeric butanols were compared with the values in pure water, calculated by means of the equation derived from the pseudo-phase separation model. Thermodynamic parameters($X_1$, $\beta$, ${\gamma}i$, $ai^M$, $C_i$ and ${\Delta}H_{mix}$) were found to have great effects of salts and isomeric butanols on the mixed micellization of CPC/TX-100 mixtures, and also in good agreements with the nonideal mixed micelle model. They showed all negative deviations from the ideal mixed micellar behavior.

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Comparative Study of Prolonged Preservation Methods in Rabbit Heart for Transplantation (이식을 위한 가토심장의 장기 보존방법에 관한 비교 연구)

  • Jo, Hyeong-Gon;Kim, Su-Hyeon;Kim, Song-Myeong
    • Journal of Chest Surgery
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    • v.30 no.1
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    • pp.1-10
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    • 1997
  • The successful cardiac transplantation depends partly on the donor heart preservation by a solution that will ensure recovery of myocardial function. The purpose of this study was to perform the evaluation of various preservation solutions and to accumulate the data on the requisites for ideal preservation solution. The experimental setup was the constant pressure Langendorffs perfusion system. Isolated rabbit hearts were perfused for 20minutes with unarm Krebs-Henseleit solution, stored for 4 hours in cold preservation solution after cardioplegia, and then were reperfused for 20minutes. The 4 experimental groups were prepared Hartmann's solution group (group 1, control), modified Euro-collins solution group(group II. MEC), modified University of Wisconsin group (group n, MUW), and CK solution(made by the author) group (group W, CK). The parameters for assessing the preservation ability were levels of enzymes in freezed myocardial tissues (lactate, creatine kinase-MB and adenosine deaminase), coronary flow. left ventricular developing pressure and dpldt. In conclusion, the ability of preservation for isolated rabbit heart was excellent in CK solution and modified University of Wisconsin solution, and poor in modified Euro-collins solution, compared with Hartmann solution. CK solution has low potassium concentrations(34.2mEq/L) and includes various substrates to be salutary on myocardial preservation. This fact may indicates the necessity of further refinements in selection or composition of electrolytes and substrates.

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Application of OLED as the Integrated Light source for the Portable Lab-On-a-Chip (휴대형 랩온어칩을 위한 집적화 광원으로의 OLED 적용)

  • Kim, Ju-Hwan;Shin, Kyeong-Sik;Kim, Young-Min;Kim, Yong-Kook;Yang, Yeun-Kyeong;Kim, Tae-Song;Kang, Ji-Yoon;Kim, Sang-Sig;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.193-197
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    • 2004
  • The organic light emitting diode (OLED) is proposed as the novel source in the microchip because it has ideal merits (various wavelengths, thin-film structure and overall emitting) for the integration. In this paper, we fabricated the finger-type pin photodiodes for fluorescence detection and the advanced microchip with OLED integrated pn the microchannel. The finger-type in the diode design extended the depletion region and reduced the internal resistance about 31.2% than rectangular-type. The photodiodes had a 100pA leakage current and a 8720 sensitivity $(I_{Light}/I_{Dark})$ at -1 V bias. The interference filter with 32 layers ($SiO_2$, $TiO_2$) was directly deposited on the photodiode. The OLED was fabricated on the ITO coated glass and was bonded with LOC. The application of thin-film OLED increased the excitation efficiency and simplified the integration process extremely. The prototype device of this application had a superior sensitivity of 100nM-LOD in the fluorescence detection.

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BAT AGN Spectroscopic Survey - The parsec scale jet properties of the ultra hard X-ray selected local AGNs

  • Baek, Junhyun;Chung, Aeree;Schawinski, Kevin;Oh, Kyuseok;Wong, Ivy;Koss, Michael
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.35.4-35.4
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    • 2019
  • We have conducted a 22 GHz very long baseline interferometry (VLBI) survey of 281 local (z < 0.05) active galactic nuclei (AGNs) selected from the Swift Burst Alert Telescope (BAT) 70-month ultra hard X-ray (14-195 keV) catalog. The main goal is to investigate the relation between the strengths of black hole accretion and the parsec-scale nuclear jet, which is expected to tightly correlate but has not been observationally confirmed yet. The BAT AGN Spectroscopic Survey (BASS) provides the least biased AGN sample against obscuration including both Seyfert types, hence it makes an ideal parent sample for studying the nuclear jet properties of an overall AGN population. Using the Korean VLBI Network (KVN), the KVN and VERA Array (KaVA), and the Very Long Baseline Array (VLBA), we observed 281 objects with a 22 GHz flux > 30 mJy, detecting 11 targets (~4% of VLBI detection rate). This implies that the fraction of X-ray AGNs which are currently ejecting a strong nuclear jet is very small. Although our 11 sources span a wide range of pc-scale morphological types, from compact to complex, they lie on a tight linear relation between accretion luminosity and nuclear jet luminosity. Our finding may indicate that the power of nuclear jet is directly responsible for the amount of black hole accretion. We also have probed the fundamental plane of black hole activity in VLBI scale (e.g., few milli-arcsecond). The results from our high-frequency VLBI radio study support that the change of jet luminosity and size follows what is predicted by the AGN evolution scenario based on the Eddington ratio (ƛ$_{Edd}$) - column density ($N_H$) plane, proposed by a previous study.

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