• Title/Summary/Keyword: (D/C) ratio

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Separation of Tryptophan Enantiomers by using Chirobiotic® T HPLC Column (Chirobiotic® T HPLC 컬럼을 이용한 Tryptophan 이성질체 분리)

  • Song, Sung-Moon;Rang, Moon Jung;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.515-518
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    • 2010
  • D,L-tryptophans were separated by using $Chirobiotic^{(R)}$ T HPLC column. Mobile phases were the mixture of methanol and water(70:30, 80:20, 90:10, v/v). Experimental temperatures were adjusted as 25, 40 and $55^{\circ}C$ in order to compare retention times. Difference in D,L-tryptophan retention times was studied in terms of the interaction between stationary phase and tryptophans. Selectivity, resolution and efficiency of column were utilized to find an optimum separation condition. Retention times were shortened by increasing the amount of methanol in mobile phase and the temperature of column. The best selectivity and resolution was obtained with the temperature($25^{\circ}C$) and the ratio of mobilephase(70/30 v/v%).

Effect of Magnesium Oxide on Physical and Chemical Properties of FKM Elastomer (FKM Elastomer의 물리적 및 화학적 성질에 미치는 산화마그네슘의 영향)

  • Lee, Chang-Seop;Choi, Gi-Tae;Choi, Han-Hwal
    • Elastomers and Composites
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    • v.38 no.1
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    • pp.57-64
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    • 2003
  • Metal oxide(MgO) was added to FKM rubber in order to develop automotive fuel hose which ran show elastic characteristics under extreme condition. Cure characteristics, physical properties, thermal resistance and fuel resistance of FKM compounded rubber with MgO were investigated. MgO was mixed to FKM rubber materials within the range of $0{\sim}20phr$. From the test results of rheological properties and Mooney viscosity, the $t_{s2}$, $T_{c90}$ values increased as the MgO contents increased in FKM rubber compounding. Hardness and 100% modulus of FKM compounded rubber slightly increased, but tensile strength and elongations at break slightly decreased. From the test results of thermal resistance of rubber specimens at 130, 150, and $170^{\circ}C$ for 70 hrs, the changing rate of physical properties was found to be relatively small. Fuel resistance tests were carried out for fuel A, B, C and D at $40^{\circ}C$ for 70hrs, and the results showed that the changing rate in physical properties was found to increase from Fuel A to D, Furthermore thermal properties of FKM compounded rubber containing MgO were also investigated by using TGA/DSC. The optimum mixing ratio of additive to FKM rubber to get the maximum effect on thermal resistance and fuel resistance, within the range of desirable specification for rubber material, was determined to be 6 phr for MgO.

Electra-Optic and Ionic Properties of Twisted Nematic Cells With Different Chiral Pitch

  • Kim, Sung-Woon;Park, Hee-Do;Kim, Hee-Cheol;Park, Young-Il;Suh, Dong-Hae;Lee, Won-Geon;Park, Hae-Sung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.504-507
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    • 2002
  • We investigated electro-optic and ionic properties of twisted nematic cells by using control of chiral pitch. These properties are observed in practical experiment and simulations. C-V and V-T curve characteristics were obtained from three types of cells with d/p. It is shown that d/p ratio of short cells exhibit faster response time improved by 20% than normal cell. Also, inter-gray response time is improved each rise time and decay time. And, the increase of saturation voltage is happened because of the small twist angel change from initial state at high voltage near 5V. To compensate for longer black level tail, gamma curve index was varied from g = 2.2 to g = 2.7 in module status. Additionally, adding chiral dopant into TN cells improved ionic characteristics such as increasing VHR, Ion density and DC Hysteresis were decreased..

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A study on the design for mobile satellite receiver antenna (이동체의 위성 수신용 안테나 설계에 관한 연구)

  • Ju, Sang-Ho;Ko, Jeong-Ho;Kim, Young-Goo;Choi, Ik-Guen
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.7
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    • pp.1529-1536
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    • 2010
  • In this paper, we propose a Axially displaced ellipse gregorian antenna with conical feed horn operating in Ku-band. For fast searching satellite position, it is designed the sub-reflector rotates about $1.5^{\circ}$ tilted by the central axis. the curvature and feed center of the main-reflector and sub-reflector are optimized to achieve maximum antenna efficiency. The designed reflector antenna shows the gain of 33dB and the cross polarization level of less than -21dB and the side-lobe level of less than -14 dB at 12.2 GHz. and C/N ratio of 19dB is proved by reception experiment of Koreasat with fabricated antenna.

A Prioritized Transmission Scheme for Three-Dimensional Integral Imaging (3차원 집적 영상을 위한 우선순위 전송 기법)

  • Cho, Myungjin;Choi, Hyun-Ho
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39C no.5
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    • pp.447-455
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    • 2014
  • In this paper, we consider a representative integral imaging method in glasses-free 3D image processing and propose a prioritized transmission scheme for guaranteeing a received video quality in error-prone environments. According to the correlation of pixels consisting of each voxel of integral image, we set the priority differently and apply the modulation level according to this priority value. That is to say, the corresponding pixels with small variance are set to a high priority and transmitted by using a low level modulation that is robust under transmission errors, but the corresponding pixels with greater variance are set to a lower priority and transmitted by using a high level modulation that has a high bit error rate but fast transmission rate. Result shows that the proposed scheme that applies the error-robust modulation level to the important image bit stream with the high priority improves the peak to sidelobe ratio (PSR) of the received 3D image, compared with a typical method that use the same modulation level without distinction of priorities.

The Surface Properties of Blend Film of Natural Rubber and Graft Latex by Dipping Process (Dipping법에 의한 천연고무와 그라프트 라텍스 블렌드 필름의 표면특성)

  • Kim, Kong-Soo;Park, Jun-Ha;Eum, Ju-Song
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.990-997
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    • 1994
  • The vulcanized NR and blend films were prepared with mixing of natural rubber latex (NRL) and methyl methacrylated grafted latex(MGL) with various additives by dipping process. It was investigated the basic properties of vulcanized NR films that is optimum condition of the mature time, swelling degree, cure time at $110^{\circ}C$, and measured the mechanical properties of tensile strength and elongation of its condition. In order to identify the surface structure and the slip properties of blend films contact angles and static and kinetic friction coefficient were measured. Contact angles were decreased with increment of blend ratio of MGL, and static and kinetic friction coefficient were decreased rapidly for the NR/MG and NR-d-MG films than for the NR films. From the results, NR/MG and NR-d-MG films has slip's reinforcement in skin contact surface with increased of blend ratio of MGL.

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Diffusion Behavior of n-Alkanes by Molecular Dynamics Simulations

  • Goo, Geun-Hoi;Sung, Gi-Hong;Lee, Song-Hi;Chang, Tai-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1595-1603
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    • 2002
  • In this paper we have presented the results of diffusion behavior of model systems for eight liquid n-alkanes ($C_{12}$-$C_{44}$) in a canonical (NVT) ensemble at several temperatures using molecular dynamics simulations. For these n-alkanes of small chain length n, the chains are clearly <$R_{ee}^2$>/6<$R_g^2$>>1 and non-Gaussian. This result implies that the liquid n-alkanes over the whole temperatures considered are far away from the Rouse regime, though the ratio becomes close to the unity as n increases. Calculated self-diffusion constants $D_{self}$ are comparable with experimental results and the Arrhenius plot of self-diffusion constants versus inverse temperature shows a different temperature dependence of diffusion on the chain length. The global rotational motion of n-alkanes is examined by characterizing the orientation relaxation of the end-to-end vector and it is found that the ratio ${\tau}1/{\tau}2$ is less than 3, the value expected for a isotropically diffusive rotational process. The friction constants ${\xi}$of the whole molecules of n-alkanes are calculated directly from the force auto-correlation (FAC) functions and compared with the monomeric friction constants ${\xi}_D$ extracted from $D_{self}$. Both the friction constants give a correct qualitative trends: decrease with increasing temperature and increase with increasing chain length. The friction constant calculated from the FAC's decreases very slowly with increasing temperature, while the monomeric friction constant varies rapidly with temperature. By considering the orientation relaxation of local vectors and diffusion of each site, it is found that rotational and translational diffusions of the ends are faster than those of the center.

Changes of Methyl trans-cinnamate Levels During Fruit-body Development in Tricholoma matsutake

  • Lee, Wi Young;Park, Youngki;Ahn, Jin Kwon;Ka, Kang Hyeon
    • Journal of Korean Society of Forest Science
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    • v.94 no.5 s.162
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    • pp.330-333
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    • 2005
  • The relationship between the contents of methyl trans-cinnamate and the ratio of DP/DS (diameter of pileus / diameter of stalk) in the fruit-body of Tricholoma matsutake during its development was investigated. The stages of development were divided as follows: stage A is less than 1, stage B is from 1 to less than 2, stage C is from 2 to less than 3, and stage D is more than 3 of the values of DP/DS. The contents of methyl trans-cinnamate in pileus and stalk of pine mushroom ranged from $77{\mu}g/g$ to $824{\mu}g/g$ and from $7.6{\mu}g/g$ to $22.4{\mu}g/g$, respectively during its development. In the part of pileus, there is no relevance of the methyl trans-cinnamate content of pine mushroom between the stage A and B, but there was significantly different among the stage of B, C and D. In the case of stalk, the relevance of the methyl trans-cinnamate content of pine mushroom between stage D and other stages showed a low difference. In addition, as pileus of pine mushroom developed the level of the aroma compound increased as well and showed higher correlation relationship ($r^2=0.877$) between the contents of methyl trans-cinnamate in the pileus and the ratio of DP/DS. From the results of this study, we can conclude that the aromatic component of pine mushroom can be deduced from the value of DP/DS, which indicates the stage of the development appearance.

Effects of Various Addition and Exclusion Time of Glucose on Development of Mouse Two-Cell Embryos

  • Park S. B.;Park K S.;Lee T. H.;Chun S. S.;Kim K S.;Song H. B.
    • Reproductive and Developmental Biology
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    • v.28 no.4
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    • pp.227-233
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    • 2004
  • This study was conducted to investigate the effect of various addition and exclusion time of glucose (Control: no addition, A: 24~72 h, B: 24~48 h, C: 48~72 h, D: 0~72 h, E: 0~48 h, F: 0~24 h and 48~72 h, G: 0~24 h) on embryonic developmental capacity of 2-cell embryos in mice. Developed blastocysts were assessed for mean cell number by differential staining. The zona-intact blastocyst (ZiB) rates were higher (p<0.05) in group B than control. However, the zona-escape blastocyst (ZeB) rates were not significantly different in all groups. At 72 h, total blastocyst (ZiB + ZeB) formation rates were not significantly different in all groups. The mean cell number was not significantly different among all groups. The inner cell mass (ICM) cell number was higher (p<0.05) in group F than control, group A, B and G. The trophectoderm (TE) cell number was higher (p<0.05) in control than group A and D. The %ICM was higher (p<0.05) in group C, D and F than control. The ICM : TE ratio was not significantly different in all groups. Between control and glucose group, no significant difference was observed in the total blastocysts (ZiB + ZeB) formation rates. Also, no significant difference was observed in the mean cell number, ICM cell number and ICM : TE ratio. However the TE cell number was higher (p<0.05) in control than glucose group and %ICM was higher (p<0.05) in glucose group than control. In conclusion, glucose added in culture medium was not inhibitory on blastocyst formation but glucose added for 48 ~72 h in culture medium increases %ICM of blastocysts in mice.

Increase of Recovery Ratio by Two Stage Membrane Process (the Pressurized PVDF Membrane Followed by Submerged PE Membrane) (PVDF 가압식과 PE 침지식 분리막을 결합한 2단 막여과 공정의 성능검토 및 회수율 증대 방안 연구)

  • Kim, Junhyeon;Mun, Baeksu;Jang, Hong-Jin;Kim, Jinho;Kim, Byungseok
    • Membrane Journal
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    • v.23 no.1
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    • pp.45-53
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    • 2013
  • Membrane filtration processes are increasingly popular for drinking water treatment that requires high quality of water. But pre-treatment system (Coagulation/Flocculation/Sedimentation) requires increased footprint and installation cost. In addition, 5~10% of the concentrate are formed. In this study, the pressurized PVDF membrane (ECONITY Co., Ltd.) system was tested with surface water (Han River, South Korea) without pre-treatment. As a result, permeate flux was operated between 1 m/d and 2.4 m/d (at $25^{\circ}C$) without chemical cleaning for one year and membrane permeate turbidity was maintained stably under 0.05 NTU regardless of raw water turbidity. And we studied application of concetrate treatment of pressurized PVDF membrane by submerged PE membrane (ECONITY Co., Ltd.). As a result, we increased recovery of total treatment process to 99.5%.