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Synthesis, characterization, and toxicity of multi-walled carbon nanotubes functionalized with 4-hydroxyquinazoline

  • Tahermansouri, Hasan;Mirosanloo, Atieh;Keshel, Saeed Heidari;Gardaneh, Mossa
    • Carbon letters
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    • v.17 no.1
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    • pp.45-52
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    • 2016
  • The attachment of 2-aminobenzamide to carboxylated multi-wall carbon nanotubes (MWCNTs)-COOH was achieved through the formation of amide bonds. Then, the functionalized MWCNTs, MWCNT-amide, were treated by phosphoryl chloride to produce MWCNT-quin. The products were characterized by Fourier transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy, thermogravimetric analysis, derivative thermogravimetric, steady-state fluorescence spectroscopy, and solubility testing. MWCNT-quin showed photo-electronic properties, which is due to the attachment of the 4-hydroxyquinazoline groups to them as proved by steady-state fluorescence spectroscopy. This suggests intramolecular interactions between the tubes and the attached 4-hydroxyquinazoline. The toxicity of the samples was evaluated in human embryonic kidney HEK293 and human breast cancer SKBR3 cell lines, and the viable cell numbers were measured by 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyltetrazolium bromide (MTT) after the cells were cultured for 24 h. Cellular investigations showed that the modified MWCNTs, particularly MWCNT-quin, have considerably significant toxic impact on SKBR3 as compared to HEK293 at the concentration of 5 µg/mL.

Study on the Isomerization and Dehydrobromination Mechanism of Brominated Butyl Rubber (브롬화된 부틸고무의 탈브롬화 밑 이성질체화 메커니즘에 대한 연구)

  • Wu, Yibo;Guo, Wenli;Li, Shuxin;Gong, Liangfa;Shang, Yuwei
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.69-73
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    • 2010
  • Effects of reaction time and temperature on the isomerization and dehydrobromination reactions of brominated butyl rubber were investigated. The structural composition of brominated butyl rubber was determined by Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy($^1H$-NMR), Density functional theory (DFT) was used to study on the isomerization and dehydrobromination mechanisms of model compounds. The geometries for model compounds of 3-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-1-octylene (3BrOE), 1-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-2-octylene (1Br2OE) and 5,5,7,7-tetramethyl-2(2',2', 4',4'-tetramethyl)pentyl-1,3-octadiene (CD) had been optimized by using density functional theory at B3LYP/3-21G and B3LYP/6-31G levels. The predicted energy of 3BrOE lies higher than that of 1Br2OE which suggests that 1Br2OE configuration is more stable than the 3BrOE configuration. Compared with the energy barrier, the pathway of dehydrobromination is less competitive than that of isomerization. This is qualitatively consistent with the experimental results.

Effect of EEG Wave Type of Visual Cortex on Conjugate Movement of Eyeball according to Movement of Visual Target (시 표적의 이동에 따른 안구의 동향운동이 대뇌 시피질의 뇌파에 미치는 영향)

  • Kim, Douk Hoon
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.1
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    • pp.51-55
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    • 2002
  • This study was to investigate the effect of EEG wave type of visual cortex on conjugate movement of eyeball according to movement of visual target. Visual evoked potential(VEP) system used the Bio-Pag(production in USA) and recorded to 586 computer. The illumination of test room was 50lux and the visual target was red light dot of 3cm size. The results of dextroversion and levoversion as follows : The visual stimulation waves on the visual cortex have about 71% of delta wave, about 12% of beta wave, about 9% theta wave and about 6% of alpha wave respectively. The dextroversion and levoversion state was similar results on the histogram amplitude of EEG wave, frequency of EEG wave type, EEG wave style and phase diagram of amplitude. Expecially the histogram amplitude of EEG wave appeared almost the Gaussian shape and the phase analysis of amplitude of EEG wave was nearly linear shape. On the fast fourier transform of the amplitude and Hz, the frequency was almost low frequency under 20 Hz, and the dextroversion and levoversion shape was similar results.

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Efficient DSP Architecture For High- Quality Audio Algorithms (고음질 오디오 알고리즘을 위한 효율적인 DSP 설계)

  • Moon, Jong-Ha;SunWoo, Myung-Hoon
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.44 no.5
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    • pp.112-117
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    • 2007
  • This paper presents specialized DSP instructions and their hardware architecture for audio coding algorithms, such as the MPEG-2/4 Advanced Audio Coding(AAC), Dolby AC-3, MPEG-2 Backward Compatible(BC), etc. The proposed architecture is specially designed and optimized for the MDCT/IMDCT(Inverse Modified Discrete Cosine Transform), and Huffman decoding of the AAC decoding algorithm. Performance comparisons show a significant improvement compared with TMS320C62x and ASDSP21060 for the MDCT/IMDCT computation. In addition, the dedicated Huffman decoding accelerator performs decoding and preparing operand in only one cycle. The proposed DPU(Data Processing Unit) consists of 107,860 gates and achieves 150 MIPS.

Short Periodicities in Latitudinal Variation of Sunspots

  • Kim, Bang-Yeop;Chang, Heon-Young
    • Journal of Astronomy and Space Sciences
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    • v.28 no.2
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    • pp.103-108
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    • 2011
  • The latitudinal variation of sunspots appearing during the period from 1874 to 2009 has been studied in terms of centerof-latitude (COL). The butterfly diagram has been used to study the evolution of the magnetic field and the dynamics at the bottom of the solar convection zone. Short-term periodicities have been of particular interest, in that they are somehow related to the structure and dynamics of the solar interior. We thus have focused our investigation on shortterm periodicities. We first calculated COL by averaging the latitude of sunspots with the weight function in area. Then, we analyzed the time series of COL using the wavelet transform technique. We found that a periodicity of ~5 years is the most dominant feature in the time series of COL, with the exception of the ~11 year solar cycle itself. This periodicity can be easily understood by considering small humps between the minima in the area-weighted butterfly diagram. However, we find that periodicities of ~1.3 (0.064), ~1.5 (0.056), or ~1.8 (0.046) years ($\frac{1}{month}$), month ), which have been previously suggested as evidence of links between the changing structure of the sunspot zone and the tachocline rotation rate oscillations, are insignificant and inconsistent. We therefore conclude that the only existing short-term periodicity is of ~5 years, and that periodicities of ~1.3, ~1.5, or ~1.8 years are likely to be artifacts due to random noise of small sunspots.

Measurement of nonlinear optical constant of organic single crystal para-toluene sulfonate prepared by slow solution evaporation method (늦은 용액증발법으로 제작한 유기단결정 para-toluene sulfonate의 비선형 광학상수 측정)

  • 황보창권
    • Korean Journal of Optics and Photonics
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    • v.9 no.2
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    • pp.76-85
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    • 1998
  • Organic single crystal of p-toluene sulfonate(PTS) bulks and thin films were fabricated using a slow solution evaporation method. Third and fifth order nonlinear refractive indices, $n_2$and $n_3$, of PTS crystals at 1600 nm were determined by the Z-scan method and the multimode output of the PTS thin film waveguide was observed at 1350 nm. When the beam intensity is in 2-5 GW/$cm^2$, the nonlinear refractive indices are $n_{2}=6{\times}10^{-4}cm^{2}$/GW and $n_{3}=-7{\times}10^{-5}cm^{4}/GW^{2}$ and the two and three photon absorption coefficients are zero. When the beam intensity is in 5~16 GW/$cm^2$, the split-step fast Fourier transform beam propagation method simulation shows that the beam propagation in the PTS is distorted from the gaussian shape.

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Chemical Composition and Rheological Properties of Polysaccharides Isolated from Different Parts of Brown Seaweed Undaria pinnatifida (미역(Undaria pinnatifida) 부위별로 추출한 다당의 이화학적 특성)

  • Koo, Jae-Geun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.5
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    • pp.665-671
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    • 2020
  • The chemical and rheological properties of fucoidan and alginate prepared from different parts of Undaria pinnatifida (sporophyll, frond, stipe) were investigated. The algal materials were extracted with HCl (pH 2.0, 3 h at 70℃) to prepare fucoidan, and the remaining solid was continuously re-extracted with Na2CO3 (pH 10.0, 70℃, 3 h) to prepare alginic acid. The fucoidan and alginic acid contents in the sporophyll, frond, and stipe were 11.14%, 3.84%, and 1.73% and 22.04%, 37.14%, and 31.74%, respectively. The content of fucoidan and alginate depends on the part extracted. The fucoidan extracted from the sporophyll mainly consists of fucose and galactose, but the fucoidan extracted from frond and stipe contains mannose in addition to fucose and galactose. Fourier-transform infrared spectroscopy analysis of fucoidan and alginate suggests the presence of sulfate groups (1261 and 840 cm-1) and carboxyl groups (1626 and 1419 cm-1), respectively. Alginate solutions (5%) had a low viscosity of 10.84-31.63 mPa·s. The activation energies of fucoidan and sodium alginate were 14.45-18.38 kJ/mol and 18.61-22.06 kJ/mol, respectively. The D-mannuronic acid/L-guluronic acid (M/G) ratios of alginate showed a relatively high (frond, 3.72; stipe, 2.88; and sporophyll, 1.80).

A Study on the Improvement of UAV based 3D Point Cloud Spatial Object Location Accuracy using Road Information (도로정보를 활용한 UAV 기반 3D 포인트 클라우드 공간객체의 위치정확도 향상 방안)

  • Lee, Jaehee;Kang, Jihun;Lee, Sewon
    • Korean Journal of Remote Sensing
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    • v.35 no.5_1
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    • pp.705-714
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    • 2019
  • Precision positioning is necessary for various use of high-resolution UAV images. Basically, GCP is used for this purpose, but in case of emergency situations or difficulty in selecting GCPs, the data shall be obtained without GCPs. This study proposed a method of improving positional accuracy for x, y coordinate of UAV based 3 dimensional point cloud data generated without GCPs. Road vector file by the public data (Open Data Portal) was used as reference data for improving location accuracy. The geometric correction of the 2 dimensional ortho-mosaic image was first performed and the transform matrix produced in this process was adopted to apply to the 3 dimensional point cloud data. The straight distance difference of 34.54 m before the correction was reduced to 1.21 m after the correction. By confirming that it is possible to improve the location accuracy of UAV images acquired without GCPs, it is expected to expand the scope of use of 3 dimensional spatial objects generated from point cloud by enabling connection and compatibility with other spatial information data.

Synthesis and Morphological Transformation of NaA Zeolite Crystals at High Temperature

  • Kim, Young-Mi;Kim, Ik-Jin
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.1-3
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    • 2006
  • Well-shaped NaA zeolite cubic crystals of a large size of $5-7{\mu}m$ were synthesized by a hydrothermal method in a mother solution having a $3.55Na_2O:Al_2O_3:1.6SiO_2:593\~2000H_2O$ composition. Thermal treatment of NaA zeolite crystals resulted in the formation of a crystalline phase of $NaAlSiO_4-Camegeite$ between 800 and $900^{\circ}C$. Even at $1000^{\circ}C,\;NaAlSiO_4$ phase was found as a major product. Environmental Scanning Electron Microscopy (ESEM), High Resolution Transmission Electron Microscopy (HRTEM), X-Ray powder Diffraction (XRD), Fourier Transform Infrared (FT-IR) spectroscopy, and DTA/TGA and BET analyses were used to characterize the initial materials and the obtained products after various heat treatments.

Robust and Blind Watermarking for DIBR attacked 3D Digital Image (3D 디지털 영상의 DIBR 공격을 위한 강인성 블라인드 워터마킹)

  • Lee, Yong-Seok;Seo, Young-Ho;Kim, Dong-Wook
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2015.11a
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    • pp.176-179
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    • 2015
  • 본 논문에서는 3D 디지털 영상 컨텐츠의 저작권 보호를 위해 DWT(Discrete Wavelet Transform)를 이용하여 강인성(robustness), 비가시성(invisibility), 보안성(security)을 만족하는 블라인드(Blind) 워터마킹 방법을 제안한다. 이 방법은 깊이 영상 기반 랜더링(DIBR, Depth Image Based Rendering)에 효과적으로 대처하기위해 고안된 알고리즘으로, 랜더링시 발생하는 왜곡에 영향이 적은 1-Level DWT LH 부대역에 워터마크를 삽입하는 방법이다. 이 방법에서 저작권에 대한 판단은 추출한 워터마크 정보를 통합 판단하는 방법을 사용한다. 이 방법은 저작권 보호를 위해 원본 영상을 보관할 필요가 없으며, 깊이 영상 기반 랜더링 baseline distance 5% 공격에 좌,우시점 영상 모두 효율적으로 적은 에러율을 보이며 워터마크로서 충분한 강인성을 보여준다.

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