• Journal of the Korean Chemical Society
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• v.38 no.10
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• pp.719-725
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• 1994

Kinetic studies were carried out for substitution reaction of $cis-[Co(NH_3)_4Cl(OH_2)]^{2+}(\mu$ = 0.75) with GlyOR (R = $C_2H_5$, $CH_3$, H) in pH 5 buffer solution at $20^{\circ}C$ by UV/Vis-spectrophotometry. We obtained cis-[Co$(NH_3)_4$Cl(glyOR)]$^{2+}$ as product. The reaction turns out to be first order for Co(III) and GlyOR, respectively. The rate constants are obtained as 9.21, 11.66 and 15.33 l${\cdot}\;mol^{-1}{\cdot}sec^{-1}$ for GlyOEt, GlyOMt and GlyOH, respectively. The activation parameters $E_a,\;{\Delta}H^{\neq}\;and\;{\Delta}S^{\neq}$ for GlyOEt were obtained as 65.77, 63.35 kJ/mol and -53.51(e.u.), respectively and were obtained as 70.91, 68.50 kJ/mol and -38.42(e.u.) for GlyOMt. In case of GlyOH, respectable values of 79.72, 77.30 kJ/mol and -26.59(e.u.) were obtained. On the basis of kinetic data and the observed activation parameters, we propose that the proper mechanism involves $S_N$2 step.

• Korean journal of communication and information
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• v.37
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• pp.204-236
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• 2007

This study explores the corrections on the Korean and the U. S. daily newspapers for the characteristics and differences through the content analysis. For the research, Chosun Ilbo, Hankyoreh Shinmun, The New York Times and The San Francisco Chronicles are selected. The main differences between the Korean and American newspapers are as follows: Firstly, the average number of newspaper errors in Korean dailies are as half as little of those in the U. S. dailies. Secondly, regarding the subcategory of mistakes, the largest thematical number is the societal matters(36.0%), followed by politics(18.3%) and economy(12.1%) for the Korean newspapers. By contrast, errors in culture(17.4%) is the most frequently made by the American newspaper reporters and editors, followed by lifestyle(8.6%), and sports(7.0%). Thirdly, in terms of content of mistakes, errors in names(26.2%) that occurred the most, followed by misidentifications(18.1%) and misattribution(15.8%) for the Korean dailies; the errors in numbers(33.7%), spelling and typographical errors(12.1%) and date(5.6%) for the U. S. dailies. Fourthly, one of the critical reasons that mistakes occurred because Korean reporters are lack of double checking the stories; the U. S. reporters simply by overlooking the articles. Finally, the Korean newspapers make use of only two kinds of correction formats, while the U.S. newspapers use six different correction formats for their newspaper readers.

• Culinary science and hospitality research
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• v.20 no.6
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• pp.200-210
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• 2014

The purpose of this study was to investigate the quality changes and contamination of microorganisms such as Escherichia coli, mold and yeast in cherry tomatoes during storage at different temperatures, gas composition and periods(7 and 14 days). This study determined pH, color change and the growth pattern of microorganisms in cherry tomato during storage at $5^{\circ}C$, $10^{\circ}C$ and $15^{\circ}C$. According to the results, pH level was a little raised with storage period. On average, $L^*$, $a^*$ and $b^*$ value of cherry tomato were irregular value of increase and decrease of all gas packaging with storage period. In regard of the types of microorganism, aerobic count plate, coliform count, mold and yeast were detected when cherry tomatoes were stored at $5^{\circ}C$, $10^{\circ}C$ and $15^{\circ}C$ during storage for 14 days. Equally, all microorganisms of cherry tomato were irregular with storage period and complex gas packaging. However, this study determined that packaging with a higher $CO_2$ concentration than $O_2$ concentration can reduce growth of microorganism. These studies can be used as primary data for determining the optimal complex gas to storage enlargement.

• The Korean Journal of Food And Nutrition
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• v.17 no.3
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• pp.278-285
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• 2004

The effects of water, rye flour and vital gluten on the sensory properties of bread were studied by response surface methodology and sensory evaluations. A response surface model was used to evaluate the effects observed and to determine the optimum variations for rye bread. The study included 12 combinations of the following independent variables: Water(57, 62, 67%), Rye flour(0, 10, 30, 50%), and Vital gluten(0, 1, 3, 5%). Bread quality attributes determined were specific volume, color, texture, appearance, taste, chewiness, moisture, overall. Rye bread specific volume, sensory evaluation values and Instrumental testing results were significantly affected by variety (water, rye flour and vital gluten). Rye bread with a high specific volume was produced using water 67%, rye flour 10% and vital gluten 3%. Whereas, rye breads with a high overall sensory evaluation were water 62 %, rye flour 10 % and vital gluten 5%. And Specific volume predicted and overall preference also was shown high. It was shown that the experimental design used provided information about the rye bread of variation of water, rye flour and vital gluten and can be a useful supplement to standardized and optimized formulas in rye bread making. The results suggest that water, rye flour, vital gluten can be combined in rye bread making at various levels, contributing to optimize the functional properties of rye bread. These result represents that breads loaf volume related to directly consumer preference.

• Journal of the Korean Chemical Society
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• v.32 no.5
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• pp.428-435
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• 1988

Some nickel(Ⅱ) and palladium(Ⅱ) complexes of the ambidentate ligands derived from condensation of the isonitrosoacetylacetone and various diamines, $Ni(IAA)_2-en$, $Ni(IAA)_2-pn$, $Ni(IAA)_2-tn$, $Pd(IAA)_2-en$, PdCl(IAA)-pn, and $Pd(IAA)_2$-tn, where (IAA)$_2$-en, $(IAA)_2$-tn, and (IAA)-pn represent N,N'-enthylenbis(isonitrosoacetylacetone imine), N,N'-propylenebis(isonitrosoacetylacetone imine), N,N'-trimethylenebis(isonitrosoacetylacetone imine) and N-(2-aminopropyl)isonitrosoacetylacetone imine, respectively, have been prepared. The nickel(Ⅱ) and palladium(Ⅱ) complexes were characterized on the bases of the elemental analysis, IR, NMR, and electronic spectra. It is suggested that a isonitroso group of (IAA)$_2$-en or (IAA)$_2$-tn coordinates to the metal ion through the nitrogen atom to form five-membered ring, while the other isonitroso group of (IAA)$_2$-en or (IAA)$_2$-tn coordinates to the metal ion through the oxygen atom to form six membered ring in square-planar complexes of Ni(IAA)$_2$-tn and Pd(IAA)$_2$-en. And two isonitroso groups of (IAA)$_2$-en, (IAA)$_2$-pn, or (IAA)$_2$-tn coordinate to the metal ion through the nitrogen atom to form five-membered rings in square-planar complexes of Ni(IAA)$_2$-en, Ni(IAA)$_2$-pn, and Pd(IAA)$_2$-tn. On the other hand, square-planar PdCl(IAA)-pn is formed by the reaction of propylenediamine with a isonitrosoacetylacetone in the presence of palladium(Ⅱ)ion.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.9
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• pp.1209-1215
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• 2010

The effects of multi-walled carbon nanotube (MWCNT) content, carbon black (CB) content, atmospheric-pressure flame plasma (APFP) treatment, and acid treatment on the mechanical properties of elastomeric composites were investigated. For pure or filled rubbers with the given amount of CB (20 and 40 phr), the tensile strength and modulus of the elastomeric composites increase similarly with the MWCNT content. A composite with APFP-treated MWCNTs shows a hardening effect (high strength, high modulus, and high ductility) unlike the one with untreated MWCNTs. On the other hand, a composite with APFP-treated CB shows a softening effect (high strength, low modulus, and high ductility), which is unlike a composite with untreated CB. As the refluxing time increases from 1 h to 2 h and the sulfuric acid concentration increases from 60% to 90%, the tensile strength and modulus of a composite decrease. Thus, it is found that the MWCNT content, CB content, APFP treatment, sulfuric acid concentration, and refluxing time have an important effect on the mechanical properties of NBR composites.

• Journal of the Korean Institute of Landscape Architecture
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• v.31 no.4
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• pp.90-100
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• 2003

본 연구는 기존 건축물 옥상녹화에 이용 가능한 저토심 옥상녹화 시스템 을 연구하고 개발하고자 수행되었다. 연구목적을 달성하기위해서 시스템의 개념적 모델이 선행 연구로부터 유추되었고 개념적 모델로부터 실험을 위한 시스템들이 제안되었다. 건축물 옥상 위에 설치된 이 시스템들에서 기린초의 생육에 대하여 인공배지 종류, 토심, 그리고 배수 형태의 효과들이 2002년 4월 3일부터 10월 18일까지 연구되었다. 인공배지 종류는 단용과 혼용이고, 토심은 5cm, l0cm,그리고 15cm이며, 배수 형태는 저수$.$배수형과 배수형으로 하였다. 여기서, 인공배지 단용은 폐유리 미분 100에 발포제를 1∼2정도 첨가하고, 착색제를 1정도 첨가한 후, 6∼8$^{\circ}C$/min로 승온하여 750∼85$0^{\circ}C$의 온도에서 발포시킨 다공질 유리를 수냉식으로 급랭하고, 분쇄기로 이송하여 l0mm이하로 분쇄하고 입도를 조절하여 얻어진 다공질 유리 파쇄물과 수피를 부피 비 6:4로 혼합하여 조성된 것이며 인공배지 혼용은 인공배 지 단용에 양토(모래 46%, 미사 40%, 점토 14%)를 부피비 5:5로 혼합하여 조성된 것이다. 피복면적, 지상부와 지하부의 생체중과 건물중, 그리고 시각적 질을 조사하였다. 각 변수들은 던칸의 다중범위 검정으로 통계처리 하였으며 처리들간의 유의수준은 5%였다. 그리고 기존 건축물 옥상에 대한 과부하의 위험을 피하기 위해서 각 시스템의 중량이 평가되었다. 그 결과를 요약하면 다음과 같다. 실험기간 중에 피복면적에 대한 배수 형태의 효과는 유의성 있는 차이를 나타내지 않았다. 인공배지 혼용의 피복면적은 인공배지 단용의 것보다 통계적으로 유의성 있게 높았다. 토심 5cm처리의 피복면적은 나머지 처리들의 피복면적보다 통계적으로 유의성 있게 낮았다. 토심 l0cm처리와 토심 15cm처리는 통계적으로 유의성이 없는 것으로 나타났다. 지상부와 뿌리의 생체중 및 건물중과 시각적 질에 대한 처리들의 효과는 피복면적에 대한 것과 유사하거나 동일하였다. 결과적으로, 기린초의 생육은 인공배지 단용보다 인공배지 혼용에서 더 높았고, 토심 10∼15cm에서 더 높았으며, 배수 형태에서는 뚜렷한 차이를 나타내지 않았다. 이 결과를 토대로, 기존 건축물 옥상에 적용 가능한 시스템의 허용하중과 기린초의 생육을 동시에 고려해볼 때, 저토심 옥상녹화 시스템 은 인공배지 종류에서는 혼용이, 토심은 10cm, 그리고 배수형태는 배수형이 적합하다고 보았다. 제안된 조건으로 조성된 시스템은 인공배지가 포장용수량상태일 때 그 중량이 약 115kg/$m^2$정도로 나타났다.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.41 no.3
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• pp.286-294
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• 1996

This experiment was conducted to determine the rice quality between slowlelease fertilizer(SRF) and conventional fertilizer (CF) with the amount of 100% and 80% under direct seeding on dry paddy field, respectively. In rice quality, the percentage of matured grain and immatured grain was higher in CF with machine transplanting than in SRF with direct seeding, and the less amount of fertilizer applied, the lower percentage of immatured grain was obtained. The percentage of carbohydrate showed the difference between CF and SRF, and higher at the level of 100% applicated than that of 80% application. The contents of fat and ash were higher in CF with less fertilizer, and there was no trend to different cultural methods but it was related to the amount of fertilizer in amylose content. The nitrogen and sodium content of milled rice was high in SRF under machine transplanting as well as direct seeding. Calcium and magnesium content showed high in direct seeding but there was not significantly difference between CF and SRF.

• Journal of Internet Computing and Services
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• v.19 no.1
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• pp.37-47
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• 2018

The number of capabilities of Internet of Things (IoT) devices will exponentially grow over the next years. These devices may generate a vast amount of time-constrained data. In the context of IoT, data management should act as a layer between the objects and devices generating the data and the applications accessing the data for analysis purposes and services. In addition, most of IoT services will be content-centric rather than host centric to increase the data availability and the efficiency of data delivery. IoT will enable all the communication devices to be interconnected and make the data generated by or associated with devices or objects globally accessible. Also, fog computing keeps data and computation close to end users at the edge of network, and thus provides a new breed of applications and services to end users with low latency, high bandwidth, and geographically distributed. In this paper, we propose Edge-Fog cloud-based Hierarchical Data Delivery ($EFcHD^2$) method that effectively and reliably delivers IoT data to associated with IoT applications with ensuring time sensitivity. The proposed $EFcHD^2$ method stands on basis of fully decentralized hybrid of Edge and Fog compute cloud model, Edge-Fog cloud, and uses information-centric networking and bloom filters. In addition, it stores the replica of IoT data or the pre-processed feature data by edge node in the appropriate locations of Edge-Fog cloud considering the characteristic of IoT data: locality, size, time sensitivity and popularity. Then, the performance of $EFcHD^2$ method is evaluated through an analytical model, and is compared to fog server-based and Content-Centric Networking (CCN)-based data delivery methods.

• Journal of The Korean Society of Grassland and Forage Science
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• v.29 no.1
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• pp.31-36
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• 2009

This study was conducted to find out an alternative way of rapid and accurate analysis of forage quality. Near reflectance infrared spectroscopy (NIRS) was used to evaluate the possibility of forage analysis and collect 258 samples such as barley for whole crop silage, forage corn and sudangrass from 2002 to 2007. The samples were analyzed for CP (crude protein), CF (crude fiber), ADF (acid detergent fiber), NDF (neutral detergent fiber) and IVTD (in vitro true digestibility), and also scanned using NIRSystem with wavelength from $400{\sim}2,400nm$. Multiple linear regression was used with wet analysis data for developing the calibration model and validate unknown samples. The important index In this experiment was SEC and SEP $r^2$ for CF, CP, NDF, ADF and IVTD in calibration set were 0.70, 0.86, 0.94, 0.94 and 0.89, also 0.47, 0.39, 0.89, 0.90 and 0.61 in validation sample, respectively. The results of this experiment indicates that NIRS was reliable analytical method to assess forage quality, specially in CF, ADF and IVTD, sample should be included for respective forage samples to get accurate result. More robust calibrations can be made to cover every forage samples if added representative sample set.