• Title/Summary/Keyword: $zeta$-component

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Characterization of Surface Properties of $BaTiO_3$ Powder by XPS

  • Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.678-679
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    • 2006
  • The effects of particle size on the surface properties of hydro-thermally synthesized barium titanate powders were investigated by means of particle size analysis, specific surface area, SEM, zeta potential and XPS. Particle sizes were measured by laser light scattering and are in the range of 150 to 1100nm. Zeta potential increased with increasing particle size and it was large minus value in the range of particle size from 500 to 900nm, which seems to be related with the dissolution of $Ba^{2+}$ ion in these particle sizes from the analysis of surface properties by XPS.

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Continuous Surface Treatment and Dyeability of PTT Film via $UV/O_3$ Irradiation (UV/Ozone 조사에 의한 PTT 필름의 연속식 표면처리와 염색성)

  • Jang Jinho;Park Dae Sun
    • Textile Coloration and Finishing
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    • v.17 no.1
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    • pp.7-13
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    • 2005
  • Continuous and intense UV irradiation on PTT film using two types of UV bulbs at different irradiation power level was carried out to modify surface characteristics of the film including zeta potential, wettability, surface energy, and dyeability. ESCA analysis of the irradiated film showed higher O/C ratio than the untreated film indicating photooxidation of outer surface layer. ATR analysis showed that the ester bonds were broken and some new groups were produced such as carboxylic acid, phenolic hydroxy, and other esters, implying that ester bonds of PTT was responsible for the observed photooxidation effect. The surface of the treated PTT film became more hydrophilic and wettable to water, coupled with increased surface energy. Polar component of the surface energy increased and nonpolar component decreased with increasing irradiation energy. The treatment also decreased zeta potential of the modified surface and nanoscale roughness increased with increasing irradiation. The dyeability of the treated films to catonic dyes was significantly improved by electrostatic and polar interaction between dye molecules and the anionic film surface. The UV irradiation seems to be a viable polymer surface modification technology, which has advantages such as no vacuum requirement and continuous process unlike plasma treatment.

RI PHOTOMETRY OF 32 CYGNI

  • Jeong, Jang-Hae;Kim, Yong-Gi;Nha, Il-Seong
    • Journal of Astronomy and Space Sciences
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    • v.9 no.2
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    • pp.135-142
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    • 1992
  • Surface activity of the late-type supergiant component of $\zeta$ Aurtype eclipsing binary 32 Cyg has been searched in R and I passbands for 53 nights in the 1991 season. Atmospheric extinctions in these wavelength regions are made and a linear relation between the two coefficients has been found. All the data are standardized and determined the magnitudes and colors of 32 Cyg. R, I and color curves of 32 Cyg at the outside eclipse phase are presented.

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Biflorin Ameliorates Memory Impairments Induced by Cholinergic Blockade in Mice

  • Jeon, Se Jin;Kim, Boseong;Ryu, Byeol;Kim, Eunji;Lee, Sunhee;Jang, Dae Sik;Ryu, Jong Hoon
    • Biomolecules & Therapeutics
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    • v.25 no.3
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    • pp.249-258
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    • 2017
  • To examine the effect of biflorin, a component of Syzygium aromaticum, on memory deficit, we introduced a scopolamine-induced cognitive deficit mouse model. A single administration of biflorin increased latency time in the passive avoidance task, ameliorated alternation behavior in the Y-maze, and increased exploration time in the Morris water maze task, indicating the improvement of cognitive behaviors against cholinergic dysfunction. The biflorin-induced reverse of latency in the scopolamine-treated group was attenuated by MK-801, an NMDA receptor antagonist. Biflorin also enhanced cognitive function in a naïve mouse model. To understand the mechanism of biflorin for memory amelioration, we performed Western blot. Biflorin increased the activation of protein kinase C-${\zeta}$ and its downstream signaling molecules in the hippocampus. These results suggest that biflorin ameliorates drug-induced memory impairment by modulation of protein kinase C-${\zeta}$ signaling in mice, implying that biflorin could function as a possible therapeutic agent for the treatment of cognitive problems.

Principle Component Analysis on Electrokinetic Measurements for Amphoteric Fibers/Acid Dye System (앰포테릭섬유/산성염료계의 계면동전압 측정치에 대한 PCA)

  • Park, Byeong-Gi
    • Journal of Korean Society for Quality Management
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    • v.13 no.1
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    • pp.26-30
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    • 1985
  • In the light of the properties of colloids, in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Nylon, wool and silk, the typical amphoteric fibers were dyed with Acid dye and various combinations were prepared by combining pH, temperature and dye concentration, in order to generate flowing electric potential which were measured by microviolt meter and specific conductivity meter. The results were transformed to Zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers, and these data were statistically analysed by principle component analysis.

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Filler-Elastomer Interactions : 4. Effect of Plasma Treatment on Surface Properties of Carbon Blacks (충전제-탄성체 상호작용 4. 플라즈마 처리가 카본블랙 표면 특성에 미치는 영향)

  • Kim, Jeong-Soon;Choi, Kyung-Eun;Park, Soo-Jin
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.94-101
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    • 2001
  • In this work, the effect of NE plasma treatment generated by radio-frequency was investigated in acid-base surface values, ion adsorption characteristics, and surface free energies of carbon blacks. As the results, it was clearly found that the obvious improvement of the treatment is in the London dispersive component (${\gamma}s^L$) of surface free energy of carbon blacks. Also both electron-acceptor ( ${\gamma}s^+$) and -donor (${\gamma}s^-$) parameters for the specific component (${\gamma}s^{sp}$) were also increased with increasing the treatment time, resulting in increasing the surface functional groups of the carbon blacks studied, together with a consequence of the increases of acidic and basic surface functional groups, ion exchange, zeta potential, and ion mobility.

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UV-induced Crosslinking of Poly(vinyl acetate) Films Containing Benzophenone (벤조페논을 함유한 폴리비닐아세테이트 필름의 자외선 조사에 의한 가교)

  • Sim, Young-Jae;Seo, Eun-Kyo;Choi, Gyong-Jun;Yoon, Sung-Jong;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.33-38
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    • 2009
  • Poly(vinyl acetate) films containing benzophenone were photocrosslinked by continuous UV irradiation.UV irradiation of PVAc film containing 5% benzophenone induced bulk crosslinking of the polymer indicated by 84.1% of gel fraction after ethyl acetate extraction. The crosslinking was attributed to the recombination of tertiary polymer radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of benzophenone. Also the UV irradiation resulted in scission of ester linkage and photooxidation of PVAc surface, which was verified by ATR and zeta potential analysis, implying that the PVAc surface became more polar and hydrophilic. The zeta potential proportionally increased from +4.5mV to -26.8 mV with increasing UV irradiation. Also the surface energy of the PVAc film increased with higher UV irradiation upto 56.5 $mJ/m^2$ by the enhanced Lewis acid/base component with larger contribution of Lewis acid parameter. Accordingly the crosslinked PVAc showed higher thermal stability with increasing UV energy.

The Interaction Between Accretion from the Interstellar Medium and Accretion from the Evolved Binary Component in Barium Stars

  • Jeong, Yeuncheol;Yushchenko, Alexander V.;Doikov, Dmytry N.
    • Journal of Astronomy and Space Sciences
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    • v.35 no.1
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    • pp.1-6
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    • 2018
  • The reanalysis of the previously published abundance pattern of mild barium star HD202109 (${\zeta}$ Cyg) and the chemical compositions of 129 thin disk barium stars facilitated the search for possible correlations of different stellar parameters with second ionization potentials of chemical elements. Results show that three valuable correlations exist in the atmospheres of barium stars. The first is the relationship between relative abundances and second ionization potentials. The second is the age dependence of mean correlation coefficients of relative abundances vs. second ionization potentials, and the third one is the changes in correlation coefficients of relative abundances vs. second ionization potentials as a function of stellar spatial velocities and overabundances of s-process elements. These findings demonstrate the possibility of hydrogen and helium accretion from the interstellar medium on the atmospheres of barium stars.

Physical Properties and Skin Penetration of Niosome Formulations Containing Minoxidil and Diaminopyrimidine Oxide (미녹시딜과 다이아미노피리미딘옥사이드 성분을 함유하는 니오좀 제형의 물성 및 피부투과)

  • Bo Kyung Kim;Won Hyung Kim;Kyung-Sup Yoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.2
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    • pp.127-139
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    • 2023
  • In this study, minoxidil, which is well known as a pharmaceutical raw material, and diaminopyrimidine oxide (DAO), which is a cosmetic raw material, were used as active ingredients to evaluate the physical properties of niosomes and compare the skin penetrations of artificial skin. To prepare niosomes of the size of nanoparticles, a high pressure homogenization method was used, and physical properties were evaluated with a zetasizer. The particle size of the noisome including the active ingredient was measured to be 99 to 123 nm according to HLB, and the zeta potential was measured in the range of -60 to -81 mV. Through DSC (differential scanning colorimetry), it was confirmed that minoxidil, a crystalline component, was uniformly dissolved in an amorphous state in niosomes. In order to confirm and compare skin penetration, it was measured by the in vitro Franz diffusion cell method, and the niosome formulation showed 3.4 times higher penetration for minoxidil and 11.1 times higher penetration for DAO than the control gel formulation. In addition, when comparing the skin penetration of minoxidil niosome and DAO niosome, a similar trend was shown, and the penetration amount of DAO was relatively high. The shapes of the niosome formulations with different HLB values were observed using Cryo-TEM, and it was confirmed that vesicles were formed in all of them and that they were intermediate between SUV (small unilamella vesicle) and LUV (large unilamella vesicle). Through this study, minoxidil, an effective drug for hair loss, and DAO, a cosmetic raw material, can be effectively delivered to the skin by encapsulating them in a noisome formulation.