• 제목/요약/키워드: $zeta$-component

검색결과 12건 처리시간 0.026초

Characterization of Surface Properties of $BaTiO_3$ Powder by XPS

  • Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.678-679
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    • 2006
  • The effects of particle size on the surface properties of hydro-thermally synthesized barium titanate powders were investigated by means of particle size analysis, specific surface area, SEM, zeta potential and XPS. Particle sizes were measured by laser light scattering and are in the range of 150 to 1100nm. Zeta potential increased with increasing particle size and it was large minus value in the range of particle size from 500 to 900nm, which seems to be related with the dissolution of $Ba^{2+}$ ion in these particle sizes from the analysis of surface properties by XPS.

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UV/Ozone 조사에 의한 PTT 필름의 연속식 표면처리와 염색성 (Continuous Surface Treatment and Dyeability of PTT Film via $UV/O_3$ Irradiation)

  • 장진호;박대선
    • 한국염색가공학회지
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    • 제17권1호
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    • pp.7-13
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    • 2005
  • Continuous and intense UV irradiation on PTT film using two types of UV bulbs at different irradiation power level was carried out to modify surface characteristics of the film including zeta potential, wettability, surface energy, and dyeability. ESCA analysis of the irradiated film showed higher O/C ratio than the untreated film indicating photooxidation of outer surface layer. ATR analysis showed that the ester bonds were broken and some new groups were produced such as carboxylic acid, phenolic hydroxy, and other esters, implying that ester bonds of PTT was responsible for the observed photooxidation effect. The surface of the treated PTT film became more hydrophilic and wettable to water, coupled with increased surface energy. Polar component of the surface energy increased and nonpolar component decreased with increasing irradiation energy. The treatment also decreased zeta potential of the modified surface and nanoscale roughness increased with increasing irradiation. The dyeability of the treated films to catonic dyes was significantly improved by electrostatic and polar interaction between dye molecules and the anionic film surface. The UV irradiation seems to be a viable polymer surface modification technology, which has advantages such as no vacuum requirement and continuous process unlike plasma treatment.

RI PHOTOMETRY OF 32 CYGNI

  • Jeong, Jang-Hae;Kim, Yong-Gi;Nha, Il-Seong
    • Journal of Astronomy and Space Sciences
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    • 제9권2호
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    • pp.135-142
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    • 1992
  • Surface activity of the late-type supergiant component of $\zeta$ Aurtype eclipsing binary 32 Cyg has been searched in R and I passbands for 53 nights in the 1991 season. Atmospheric extinctions in these wavelength regions are made and a linear relation between the two coefficients has been found. All the data are standardized and determined the magnitudes and colors of 32 Cyg. R, I and color curves of 32 Cyg at the outside eclipse phase are presented.

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Biflorin Ameliorates Memory Impairments Induced by Cholinergic Blockade in Mice

  • Jeon, Se Jin;Kim, Boseong;Ryu, Byeol;Kim, Eunji;Lee, Sunhee;Jang, Dae Sik;Ryu, Jong Hoon
    • Biomolecules & Therapeutics
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    • 제25권3호
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    • pp.249-258
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    • 2017
  • To examine the effect of biflorin, a component of Syzygium aromaticum, on memory deficit, we introduced a scopolamine-induced cognitive deficit mouse model. A single administration of biflorin increased latency time in the passive avoidance task, ameliorated alternation behavior in the Y-maze, and increased exploration time in the Morris water maze task, indicating the improvement of cognitive behaviors against cholinergic dysfunction. The biflorin-induced reverse of latency in the scopolamine-treated group was attenuated by MK-801, an NMDA receptor antagonist. Biflorin also enhanced cognitive function in a naïve mouse model. To understand the mechanism of biflorin for memory amelioration, we performed Western blot. Biflorin increased the activation of protein kinase C-${\zeta}$ and its downstream signaling molecules in the hippocampus. These results suggest that biflorin ameliorates drug-induced memory impairment by modulation of protein kinase C-${\zeta}$ signaling in mice, implying that biflorin could function as a possible therapeutic agent for the treatment of cognitive problems.

앰포테릭섬유/산성염료계의 계면동전압 측정치에 대한 PCA (Principle Component Analysis on Electrokinetic Measurements for Amphoteric Fibers/Acid Dye System)

  • 박병기
    • 품질경영학회지
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    • 제13권1호
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    • pp.26-30
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    • 1985
  • In the light of the properties of colloids, in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Nylon, wool and silk, the typical amphoteric fibers were dyed with Acid dye and various combinations were prepared by combining pH, temperature and dye concentration, in order to generate flowing electric potential which were measured by microviolt meter and specific conductivity meter. The results were transformed to Zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers, and these data were statistically analysed by principle component analysis.

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충전제-탄성체 상호작용 4. 플라즈마 처리가 카본블랙 표면 특성에 미치는 영향 (Filler-Elastomer Interactions : 4. Effect of Plasma Treatment on Surface Properties of Carbon Blacks)

  • 김정순;최경은;박수진
    • Elastomers and Composites
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    • 제36권2호
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    • pp.94-101
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    • 2001
  • 본 연구에서는 RF-plasma를 사용하여 카본블랙을 $N_2$ 분위기에서 표면처리 하였을 때 카본블랙의 표면 산도 및 염기도와 이온 흡착 특성, 그리고 표면 자유에너지를 통한 물리-화학적변화를 관찰하였다. 그 결과 카본블랙을 플라즈마 표면처리 하였을 경우 표면 자유에너지의 비극성 요소 (${\gamma}s^L$)가 크게 증가함을 고찰하였다. 또한 표면 산도 및 표면 염기도와 이온 교환특성, 제타 전위, 그리고 이온 이동도의 향상 등에 의한 표면 관능기의 발달로 표면처리 시간이 증가됨에 따라 극성요소 (${\gamma}s^{sp}$)인 전자 받게 (${\gamma}s^+$)와 전자 주게 (${\gamma}s^-$) 인자도 증가하는 것을 볼 수 있었다.

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벤조페논을 함유한 폴리비닐아세테이트 필름의 자외선 조사에 의한 가교 (UV-induced Crosslinking of Poly(vinyl acetate) Films Containing Benzophenone)

  • 심영재;서은교;최경준;윤성종;장진호
    • 한국염색가공학회지
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    • 제21권4호
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    • pp.33-38
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    • 2009
  • Poly(vinyl acetate) films containing benzophenone were photocrosslinked by continuous UV irradiation.UV irradiation of PVAc film containing 5% benzophenone induced bulk crosslinking of the polymer indicated by 84.1% of gel fraction after ethyl acetate extraction. The crosslinking was attributed to the recombination of tertiary polymer radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of benzophenone. Also the UV irradiation resulted in scission of ester linkage and photooxidation of PVAc surface, which was verified by ATR and zeta potential analysis, implying that the PVAc surface became more polar and hydrophilic. The zeta potential proportionally increased from +4.5mV to -26.8 mV with increasing UV irradiation. Also the surface energy of the PVAc film increased with higher UV irradiation upto 56.5 $mJ/m^2$ by the enhanced Lewis acid/base component with larger contribution of Lewis acid parameter. Accordingly the crosslinked PVAc showed higher thermal stability with increasing UV energy.

The Interaction Between Accretion from the Interstellar Medium and Accretion from the Evolved Binary Component in Barium Stars

  • Jeong, Yeuncheol;Yushchenko, Alexander V.;Doikov, Dmytry N.
    • Journal of Astronomy and Space Sciences
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    • 제35권1호
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    • pp.1-6
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    • 2018
  • The reanalysis of the previously published abundance pattern of mild barium star HD202109 (${\zeta}$ Cyg) and the chemical compositions of 129 thin disk barium stars facilitated the search for possible correlations of different stellar parameters with second ionization potentials of chemical elements. Results show that three valuable correlations exist in the atmospheres of barium stars. The first is the relationship between relative abundances and second ionization potentials. The second is the age dependence of mean correlation coefficients of relative abundances vs. second ionization potentials, and the third one is the changes in correlation coefficients of relative abundances vs. second ionization potentials as a function of stellar spatial velocities and overabundances of s-process elements. These findings demonstrate the possibility of hydrogen and helium accretion from the interstellar medium on the atmospheres of barium stars.

미녹시딜과 다이아미노피리미딘옥사이드 성분을 함유하는 니오좀 제형의 물성 및 피부투과 (Physical Properties and Skin Penetration of Niosome Formulations Containing Minoxidil and Diaminopyrimidine Oxide)

  • 김보경;김원형;윤경섭
    • 대한화장품학회지
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    • 제49권2호
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    • pp.127-139
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    • 2023
  • 본 연구에서는 의약품 원료로 잘 알려진 minoxidil과 화장품 원료인 diaminopyrimidine oxide (DAO) 활성성분으로 사용하여 니오좀(niosome)의 물성평가와 더불어 인공피부에 대한 경피투과율을 비교하였다. 나노입자의 니오좀을 제조하기 위해 고압유화(high pressure homogenization) 방법을 이용하였으며 제타사이저(zetasizer)로 물성평가를 진행하였다. 활성성분을 포함한 니오좀의 입자크기는 HLB에 따라 평균 99 ~ 123 nm, 제타전위(zeta potential)는 -60 ~ -81 mV의 범위로 측정되었다. DSC (differential scanning colorimetry)를 통해 결정성 성분인 minoxidil이 니오좀 내에 무결정 상태로 균일하게 용해되어 있음을 확인하였다. 경피투과량을 확인 및 비교하기 위해 in vitro Franz diffusion cell 방법으로 측정하였으며, 니오좀 제형이 대조군인겔 제형보다 minoxidil의 경우 3.4배, DAO의 경우 11.1배 높은 투과율을 보였다. 또한 minoxidil과 DAO 니오좀의 경피투과 비교 시 유사한 경향을 보였으며, 상대적으로 DAO의 투과량이 많았다. HLB 값을 달리한 니오좀 제형을 Cryo-TEM을 이용하여 형상을 관찰하였으며, 모두 소포체가 형성되었으며 SUV (small unilamella vesicle)와 LUV (large unilamella vesicle)의 중간 형태임을 확인하였다. 본 연구를 통하여 탈모에 효과적인 약물인 minoxidil과 화장품 원료인 DAO 성분을 니오좀 제형에 캡슐화시킴으로써 효과적으로 피부에의 전달을 기대할 수 있다.