• Title/Summary/Keyword: $sc-CO_2$

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A Study on the Slope Analysis of Weathered Limestone Soils during Rainfalls (강우 시 석회암 풍화토 사면의 안정해석에 관한 연구)

  • Kim Jong-Ryeol;Kang Seung-Goo;Kang Hee-Bog;Park Seung-Kyun;Park Chol-Won
    • The Journal of Engineering Geology
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    • v.15 no.1
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    • pp.9-17
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    • 2005
  • A set of soil samples were picked up from a failed slope formed by rainfall in limestone zone in Jangseong-gun, Jeonnam, Korea, to find out its physical and mechanical characteristics for this study, and variation of safety factor depending on slope inclination was defined by analysing slope stability affected by rainfall. Decomposed limestone soil in the research area is composed of quartz, orthoclase, gibbsite, geothite, etc., with specific gravity of 2.73, and this soil is included in SC by unified soil classification system. Calcium ingredient decreased remarkably during weathering at its mother rock. Coefficient of permeability is 2.56×10/sup -4/ cm/ sec, similar to its value of silty clay. Cohesion decreases remarkably from 3.0 t/ ㎡ to 0.72 t/ ㎡, and Φ value of internal friction angle tends to decrease as it turns to be saturated soil from partial saturated soil in the shear test. To analyze slope stability affected by rainfall, it is reasonable to seek seepage depth with reference to rainfall* intensity. In the slope stability analysis, when the seepage depth is the larger, its safety factor is the less, which makes the slope unstable. Comparing with minimum safety factor, 1.5 of cut slope in consideration of the seep-age line, safety factor is found to be satisfactory only when inclination of cut slope of decomposed limestone soil is more than 1:1.2 slope at least considering rainfall. It is also found that decrease of cohesion has great effect on decline of safety factor of slope while partial saturated soil turns to be saturated soil.

Prediction of Phase Behavior of ε-caprolactam Derivatives and Carbon Dioxide using a Group Contribution Method (그룹 기여 방법을 이용한 ε-caprolactam 유도체와 이산화탄소의 상거동 예측에 관한 연구)

  • Kwon, Soyoung;Bae, Won;Lee, Kyoungwon;Kim, Hwayong
    • Clean Technology
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    • v.11 no.3
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    • pp.117-122
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    • 2005
  • N-vinyl caprolactam (NVCL), a kind of N-vinyl amide monomer, must be dissolved in continuous phase ($scCO_2$) for dispersion polymerization in supercritical carbon dioxide. Phase behavior of $CO_2$+NVCL is very important and necessary for determining initial polymerization condition and for monomer extraction from final polymer. There is the limitation of experimental method for obtaining pure properties of the monomer because of the possibility of polymerization. And N-methyl caprolactam (NMCL) is the useful solvent for the gas treating process. In the viewpoint of molecular thermodynamics, NVCL and NMCL have same functional group i.e. ${\varepsilon}$-caprolactam. In the case of NVCL, hydrogen of amide group is substituted with vinyl group and for NMCL, hydrogen of amide group is substituted with methyl group. We suggested modified group contribution method for this ${\varepsilon}$-caprolactam derivatives. This new group contribution parameter was applied to correlate $CO_2$ + N-vinyl caprolactam or N-methyl caprolactam system.

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New Liquid Crystal-Embedded PVdF-co-HFP-Based Polymer Electrolytes for Dye-Sensitized Solar Cell Applications

  • Vijayakumar, G.;Lee, Meyoung-Jin;Song, Myung-Kwan;Jin, Sung-Ho;Lee, Jae-Wook;Lee, Chan-Woo;Gal, Yeong-Soon;Shim, Hyo-Jin;Kang, Yong-Ku;Lee, Gi-Won;Kim, Kyung-Kon;Park, Nam-Gyu;Kim, Suhk-Mann
    • Macromolecular Research
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    • v.17 no.12
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    • pp.963-968
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    • 2009
  • Liquid crystal (LC; E7 and/or ML-0249)-embedded, poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-co-HFP)-based, polymer electrolytes were prepared for use in dye-sensitized solar cells (DSSCs). The electrolytes contained 1-methyl-3-propylimidazolium iodide (PMII), tetrabutylammonium iodide (TBAI), and iodine ($I_2$), which participate in the $I_3^-/I^-$ redox couple. The incorporation of photochemically stable PVdF-co-HFP in the DSSCs created a stable polymer electrolyte that resisted leakage and volatilization. DSSCs, with liquid crystal(LC)-embedded PVdF-co-HFP-based polymer electrolytes between the amphiphilic ruthenium dye N719 absorbed to the nanocrystalline $TiO_2$ photoanode and the Pt counter electrode, were fabricated. These DSSCs displayed enhanced redox couple reduction and reduced charge recombination in comparison to that fabricated from the conventional PVdF-co-HFP-based polymer electrolyte. The behavior of the polymer electrolyte was improved by the addition of optimized amounts of plasticizers, such as ethylene carbonate (EC) and propylene carbonate (PC). The significantly increased short-circuit current density ($J_{sc}$, $14.60\;mA/cm^2$) and open-circuit voltage ($V_{oc}$, 0.68 V) of these DSSCs led to a high power conversion efficiency (PCE) of 6.42% and a fill factor of 0.65 under a standard light intensity of $100\;mW/cm^2$ irradiation of AM 1.5 sunlight. A DSSC fabricated by using E7-embedded PVdF-co-HFP-based polymer electrolyte exhibited a maximum incident photon-to-current conversion efficiency (IPCE) of 50%.

Investigation on the Comparison of Exhaust Emission Characteristics of Passenger Cars using LPG and Diesel Fuel in Variation of Driving Mode and Ambient Conditions (주행모드 및 조건변화에 따른 LPG와 디젤승용차량 배출특성 비교에 관한 연구)

  • Kim, Hyung Jun;Lee, Jongtae;Seo, Youngho;Hong, You Deug
    • Journal of ILASS-Korea
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    • v.22 no.4
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    • pp.185-189
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    • 2017
  • In Korea, sales of passenger cars using diesel and LPG fuels were continuously increased in recent years. From now on 2030, the registrated vehicles will close in about twenty five million in Korea. From these reason, Investigation on the comparison of exhaust emission characteristics of passenger cars using LPG and Diesel fuel in variation of driving mode and ambient conditions were conducted in this study. Exhaust emission characteristics of test vehicles were measured and analyzed by using chassis dynamometer and emission analyzer. Also, test vehicles were selected on the diesel vehicle with 1.7L engine and LPG vehicle with 2.0L engine. In order to study on emission characteristics according to driving cycles, CVS-75, NEDC, US06, SC03, Cold-FTP and HWFET were applied and the test conditions were set up the cases of A/C on and hot start. From these results, it is revealed that the NOx emission of diesel vehicle was higher than that of LPG vehicle and the case of CO emission shows the opposite patterns. In the HC emission, the emission increasing patterns not showed but the NOx emission of diesel vehicle and CO emission of LPG vehicle were showed the variation patterns according to the various driving modes.

EFFECT OF CURING METHODS OF RESIN CEMENTS ON BOND STRENGTH AND ADHESIVE INTERFACE OF POST (레진시멘트의 중합방법이 포스트의 결합강도와 접착계면에 미치는 영향)

  • Kim, Mun-Hang;Kim, Hae-Jung;Cho, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.34 no.2
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    • pp.103-112
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    • 2009
  • The purpose of this study was to compare the effect of curing methods of adhesive resins and resin cements in the root canal. Crown portions of 32 single-rooted mandibular premolars were removed. Routine endodontic treatment was done, and 9 mm deep post spaces were prepared within root canals. No.3 FRC Postec posts (Ivoclar-Vivadent AG, Liechtensteih) were cemented in the post spaces by self-(SC) or light-curing (LC) using two dual-cured adhesives (Adper Scotchbond multi-purpose plus and Exite DSC )and resin cements (RelyX ARC and Variolink II). They were assigned to 4 groups (n=8): R-SC, R-LC, V-SC, V-LC group. After stored in distilled water for 24 hours, each root was transversally sectioned with 1.5 mm thick and made three slices. The specimens were subjected to push-out test in a universal testing machine (EZ Test, Shimadzu Co., Japan) with a crosshead speed of 1 mm/min. The data were analyzed with repeated ANOVA and one-way ANOVA. Also the interface of post-resin cement and resin cement-canal wall of each group was observed under FE-SEM. When fiber posts were cemented into the root canal using total-etch adhesives, the bond strength and adaptation between post and root canal dentin was affected by curing method. Self-cure of adhesives and resin cements showed higher bond strength and closer adaptation than light-cure of them.

Study on the in vitro and in vivo anti-obesity effects of a combination of Syzygium aromaticum L. and Sorbus commixta Hedl. (정향과 마가목 복합물의 in vitro와 in vivo 항비만 효과 연구)

  • Ji Heon Yu;Hui Yeon An;Seong-Soo Roh;Mi-Rae Shin
    • Journal of Nutrition and Health
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    • v.57 no.2
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    • pp.196-210
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    • 2024
  • Purpose: This study investigated the anti-obesity effects of a combination of Syzygium aromaticum L. and Sorbus commixta Hedl. (SS) in vitro and in vivo. Methods: The extracts of Syzygium aromaticum extract (SA) and Sorbus commixta extract (SC) were prepared individually using distilled water. They were mixed in a 1:2 ratio for use in the experiment. To assess the anti-obesity potential of SS in vitro, we examined cell proliferation, cellular triglyceride (TG), and total cholesterol (TC) levels, as well as lipogenesis and β-oxidation in 3T3-L1 cells. To confirm its anti-obesity potential in vivo, C57BL/6J mice were fed a 60% high-fat diet (HFD) to induce obesity. SA alone, SC alone, and their combination compound, SS (at a dosage of 200 mg/kg) were orally administered for 6 weeks. Thereafter, to conduct a comparative evaluation, serum analysis, western blotting of liver tissues, and histopathological analysis were performed. Results: Both SS200 and SS400 significantly inhibited the cellular TG and TC contents in the 3T3-L1 cells. Furthermore, treatment of the cells with SS (at a dose 200 and 400 ㎍/mL) also led to a noticeable regulation of key lipogenic and β-oxidation factors. Treatment of obese mice with SS resulted in a greater reduction in serum leptin and TG levels compared to treatment with the individual compounds (SA and SC). Furthermore, activation of AMP-activated protein kinase α by SS treatment resulted in the suppression of sterol regulatory element-binding proteins (SREBP)-1, leading to the inhibition of acetyl-CoA carboxylase (ACC) expression. Conclusion: Our results suggest that SS may have the potential to prevent obesity through a reduction in the TG and TC levels and regulation of lipogenesis and β-oxidation.

Synthesis and Electrochemical Properties of (La0.6Sr0.4)(Co0.2Fe0.8)O3 cathode for SOFC on pH Control Using Modified Oxalate Method (Modified Oxalate Method 의해 합성한 SOFC용(La0.6Sr0.4)(Co0.2Fe0.8)O3 Cathode의 pH 변화에 따른 특성)

  • Lee, Mi-Jai;Choi, Byung-Hyun;Kim, Sei-Ki;Park, Sang-Sun;Lee, Kyung-Hee
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.288-294
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    • 2007
  • The LSCF cathode far Solid Oxide Fuel Cell was investigated to develop high performance unit cell at intermediate temperature by modified oxalate method with different electrolytes and different pH. The LSCF powders employed La, Sr, Co and Fe oxides, oxalic acid, ethanol and $NH_4OH$ solution were synthesized with pH controlled as 2, 6, 7, 8, 9 and 10 at $80^{\circ}C$ Single crystalline phase was obtained from pH $2{\sim}9$. on the other hand, $La_2O_3$ appeared from pH 10. Very fine powder with particle size of 50 nm was obtained at calcination temperature of $800^{\circ}C$ for 4 hours. LSCF cathode synthesized at pH 7 showed the highest electric conductivity in the temperature range of $600^{\circ}C$ to $900^{\circ}C$ its value was 950 S/cm at $900^{\circ}C$ Under same synthesis conditions, polarization resistance of each LSCF cathode was changed with different calcination temperatures. As-prepared powder presented 2.52, 1.54 and $2.58\;{\Omega}$ at $600^{\circ}C$ with ScSZ, 8Y-YSZ and GDC as its electrolyte respectively after calcination at $800^{\circ}C$ for 4 hours.

Chemical Abundances of 93 Planet Host stars

  • Kang, Won-Seok;Lee, Sang-Gak;Kim, Kang-Min
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.78.1-78.1
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    • 2010
  • We obtained the spectra of 93 Planet host stars and 73 normal field stars in F, G, K type using BOES at BOAO. We measured the equivalent width of Fe and 13 elements lines using the automatic EW measurement program, TAME(Tools for Automatic Measurement of Equivalent-widths) and estimated the abundances by synth and abfind driver of MOOG code. Since the absence of planets in the normal field stars cannot be "completely" proved, this work focused on the chemical abundances and planet properties of planet host stars, which have the massive planets close to the parent star relatively. We carried out an investigation for the difference of abundances between stars with "Hot Jupiter" and normal field stars with no known planets. We examined the chemical composition of 12 elements, such as Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Co, and Ni by EW measurements, and the S abundances were estimated using synthetic spectrum.

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Low Latency Encoding Algorithm for Duo-Binary Turbo Codes with Tail Biting Trellises (이중 입력 터보 코드를 위한 저지연 부호화 알고리즘)

  • Park, Sook-Min;Kwak, Jae-Young;Lee, Kwy-Ro
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.46 no.2
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    • pp.47-51
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    • 2009
  • The low latency encoder for high data rate duo-binary turbo codes with tail biting trellises is considered. Encoder hardware architecture is proposed using inherent encoding property of duo-binary turbo codes. And we showed that half of execution time as well as the energy can be reduced with the proposed architecture.

Geochemical Characteristics of Volcanics from Yangsan, Kyeongnam Province (경남(慶南) 양산지역(梁山地域)에 분포(分布)하는 화산암류(火山岩類)의 지구화학적(地球化學的) 특성연구(特性硏究))

  • Kim, M.Y.;Shin, H.J.;Lee, P.K.;Jang, Y.N.
    • Economic and Environmental Geology
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    • v.21 no.2
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    • pp.139-148
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    • 1988
  • The altered volcanic rocks, ranging from tuffaceous to andesitic rocks are widely distributed around the "caldera" area in the southeastern part of Kyeongsang province. The volcanic activity and tectonic movement are assumed to be followed by the hydrothermal activities in the area. From the mineral assemblage the type of alteration can be divided into two types; propylitic and argillic. The average concentration of gold in hydrothermally altered rocks is somewhat lower (about 20 ppb) than that of fresh rocks (45-25 ppb), but for Ag, vice versa. During the hydrothermal process, the concentration of the trace elements Ag, Hg, Co, As, Hf, Sc, Si, Al increased, and that of Na, Rb, K, Au, Mg, Ca etc. decreased. The high anomalous contents of silver for altered rocks range from 4-7 ppm and 1-3 ppm for relatively fresh rocks.

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