• Title/Summary/Keyword: $pH_u$

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Molybdenum release from high burnup spent nuclear fuel at alkaline and hyperalkaline pH

  • Sonia Garcia-Gomez;Javier Gimenez;Ignasi Casas;Jordi Llorca;Joan De Pablo;Albert Martinez-Torrents;Frederic Clarens;Jakub Kokinda;Luis Iglesias;Daniel Serrano-Purroy
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.34-41
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    • 2024
  • This work presents experimental data and modelling of the release of Mo from high-burnup spent nuclear fuel (63 MWd/kgU) at two different pH values, 8.4 and 13.2 in air. The release of Mo from SF to the solution is around two orders of magnitude higher at pH = 13.2 than at pH = 8.4. The high Mo release at high pH would indicate that Mo would not be congruently released with uranium and would have an important contribution to the Instant Release Fraction, with a value of 5.3%. Parallel experiments with pure non irradiated Mo(s) and XPS determinations indicated that the faster dissolution at pH = 13.2 could be the consequence of the higher releases from metallic Mo in the fuel through a surface complexation mechanism promoted by the OH- and the oxidation of the metal to Mo(VI) via the formation of intermediate Mo(IV) and Mo(V) species.

Effects of Fire on Vegetation and Soil Nutrients in Mt. Chiak (치악산의 식생과 토양에 미친 산불의 영향)

  • 박봉규;김종희
    • Journal of Plant Biology
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    • v.24 no.1
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    • pp.31-45
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    • 1981
  • The purpose of this study aimed to study effects of fire on vegetation and soil properties after the first growing season in Mt. Chiak. 1. With the basis of importance value of species in each stand, status of species was assessed for three categories; Increaser species, Decreaser species, and Neutral species. 2. Biomass was 2.2 times higher on burned area than unburned. This indicates that biomass was remarkably increased after fire. 3. To evaluate similarity, coefficients of similarity among communities were obtained, and correlation coefficients were also estimated. These indices showed that burned and unburned community were markedly different.. $B_1$-stand and $B_1$-stand appeared most similar to each other among stands. 4. Species diversity was greater in burned than unburned stands. 5. Soil pH value and organic matter content in burned area were significantly higher than those in unburned area. However, soil water content was lower in burned area. There was no effect of burning on soil pH value and water content at 15~20 cm depth of soil. 6. All chemical compositions except sodium were much higher in soil surface. The decreases in sodium levels at surface were probably resulted from the rapid leaching due to the increased solubility and decreased capacity for adsorption of sodium in comparison with potassium or calcium. Among chemical compositions of soil amount of nitrogen showed least difference between the burneb and unburned surfaces soil.

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Studies on the New Analytical Methods for Separation and Recovery of Rare Earth Metals (I) : Adsorption Characteristics of U(VI) Ion by New Synthetic Resins with Macrocyclic Compounds (희토류금속 분리 및 회수를 위한 분석화학적 연구 (제1보) : 우라늄(VI)의 분리회수를 위한 선택이온교환수지 합성과 우라늄(VI) 금속이온의 흡착특성)

  • Jung Oh Jin;Hak Jin Jung;Joon Tea Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.358-370
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    • 1988
  • Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, 4%, and 10%-crosslinking and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium, rare earths and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and have good resistance to heat at $280^{\circ}C$. The $UO_2^{+2}$ aqueous solution are not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was twenty minutes and adsorptive power decreased in proportion to crosslinking size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations is in the order of $UO_2^{2+},\;Cu^{2+}\;and\;Nd^{3+}$.

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Single Nucleotide Polymorphism in the Promoter Region of H1 Histone Family Member N, Testis-specific (H1FNT) and Its Association Study with Male Infertility

  • Yang, Seung-Hee;Lee, Jin-U;Lee, Su-Man
    • Genomics & Informatics
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    • v.8 no.4
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    • pp.201-205
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    • 2010
  • The H1 histone family, member N, testis-specific (H1FNT) is exclusively expressed in the testis, and had its possible role for sperm chromatin formation. The purpose of this study is to investigate any genetic association of H1FNT gene with male infertility, especially at the promoter region. We examined the promoter single nucleotide polymorphisms (SNP) of H1FNT gene which is located within transcription factor binding site for its association with male infertility. The statistical analysis showed that the -1129A>T polymorphism was present at a statistically significance in male infertility (p=0.0059 and 0.0349 for hetero and risk type, respectively). The dual-luciferase promoter assay was performed to examine the polymorphic effect of this promoter SNP by the cloning of promoter region (1700bp fragment) into pGL3-basic vector. In our plasmid based reporter system, there is no big difference between wild and risk type. In conclusion, H1FNT -1129A>T promoter SNP is statistically significant with male infertility, especially with subfertile (non-azoospermia) group. Further analysis of its functional polymorphic effect in vivo may provide the biological significance of testis-specific histone with spermatogenesis.

Oxidative Stability of Vacuum-Packed Chicken Wings Marinated with Fruit Juices during Frozen Storage

  • Rupasinghe, Rashmi A.;Alahakoon, Amali U.;Alakolanga, Achala W.;Jayasena, Dinesh D.;Jo, Cheorun
    • Food Science of Animal Resources
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    • v.42 no.1
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    • pp.61-72
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    • 2022
  • Antioxidants present in fruits and vegetables have a potential to reduce disease risk, and increase the shelf life of food products by reducing lipid oxidation. The effect of marination with antioxidants-rich fruit juices on quality characteristics of vacuum-packed chicken wings were examined during frozen storage. Chicken wings were mixed separately with marinades containing pineapple juice, June plum juice, and mango juice and kept for 12 h and 24 h. Three best marination conditions were selected based on a sensory evaluation. Antioxidant activity and total phenolic content of fruit juices, and marinade uptake, and marinade loss of marinated chicken wings were determined. In addition, vacuum packed marinated chicken wings were tested for pH, water holding capacity (WHC), 2-thiobarbituric acid reactive substances (TBARS) value and antioxidant activity over a 4-wk frozen storage. The best sensory properties were reported from chicken wings marinated with pineapple juice for 24 h, mango juice for 24 h, and June plum juice for 12 h (p<0.05) compared to other marinade-time combinations. Mango juice showed the highest antioxidant activity (92.2%) and total phenolic content (38.45 ㎍/mL; p<0.05) compared to other fruit juices. The pH and WHC of vacuumpacked chicken wings were slightly decreased over the frozen storage (p<0.05). Moreover, chicken wings marinated with mango juice had the lowest TBARS values and the highest 2,2-diphenyl-1-picryl-hydrazyl-hydrate free radical scavenging activity. In conclusion, mango juice was selected among tested as the most effective marinade for enhancing the oxidative stability of lipid while maintaining the other meat quality traits of vacuum-packed chicken wings.

Nonparametric Estimation of Reliabilityin Strength-Stress Model

  • Jeong, H.S.;Kim, J.J.;Park., B.U.;Lee, H.W.
    • Communications for Statistical Applications and Methods
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    • v.3 no.3
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    • pp.187-194
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    • 1996
  • We treat the problem of estimating reliability R = P[Y < X] in the stress-strength model in which a unit of strength X is subfected to enviromental stress Y./ In this paper several nonparametric approaches to estimation of R are analyzed and compared by simulations.

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