• Title/Summary/Keyword: $pH_u$

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Poly(2-ethyl-2-oxazoline)/poly(acrylic acid) 계의 수소결합 특성 및 이용

  • Kim, Jin-Hui;Jang, U-Jin;Gu, Yun-Mo
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.644-647
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    • 2000
  • The properties of hydrogen bonding between poly(2-ethyl-2-oxazoline)[PEOx] and poly(acrylic acid)[PAA] were investigated. PEOx and PAA formed stable complex and precipitated due to hydrogen bonding between hydrogen of PAA and oxygen of PEOx in acidic condition(below pH 4.3). Optimum reaction ratio of PEOx and PAA was determined as mass ratio of 1:1.5 for applications in aqueous two phase system. The mixtures of the polymers formed aqueous two phase system with dextran solution after the breakage of hydrogen bondings. This properties can be used for the recovery of valuable products.

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Adsorption and Separation of U (VI), Co (II), and Dy (III) Metal Ions on Crown Synthetic Resin

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.10 no.1
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    • pp.43-50
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    • 2017
  • Synthetic resins were combined 1-aza-12-crown-4 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 8%, and 16% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on metal ion adsorption for resin adsorbent, the metal ions showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in ethanol solvent was the order of uranium ($UO_2{^{2+}}$) > cobalt ($Co^{2+}$) > dysprosium ($Dy^{3+}$) ion, adsorbability of the metal ion was the crosslink in order of 1%, 2%, 8%, and 16% and it was increased with the lower dielectric constant. In addition, theses metal ions could be separated in the column with 1% crosslink resin by using nitric acid (pH 2.0) as an eluent.

Viscosity and Sensory Characteristics of Cow-soy Milk (콩우유와 우유 혼합유의 점도 및 관능적 특성에의 영향인자 영향)

  • Jeong, Nam-Yong;Kim, U-Jeong;Kim, Dong-Won
    • The Korean Journal of Food And Nutrition
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    • v.7 no.4
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    • pp.353-360
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    • 1994
  • Effect of pH, calcium, sucrose, heating and mixing ratio of soy and cow milk was studied on the viscosity and the sensory characteristics of cow-soy milk. The viscosity of soymilk was significantly affected by pH with showing maximum at 6.0 and the pH effect was decreased as the ratio of cow talk increased. A addition of sucrose or calcium affected little on the viscosity and a negative linear relationship was found be tween viscosity and an increase in cow milk ratio. Sensory characteristics of grassy and beany odor and taste of soymilk were rapidly decreased and nutty flavor and total acceptability were increased during initial 30 min of boiling. A further increase in boiling affected little on tastes and odors of soymilk. The beany odor and taste linearly decreased and milk flavor Increased as the ratio of cow milk increased. The total acceptability of 50 : 50 was found to be maximum for cow and soy mixed milks.

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Media Optimization for the Production of Aminopeptidase M Inhibitors MR-387A and B by Streptomyces sp. SL-387 (Streptomyces sp. SL-387에 의한 Aminopeptidase M 저해제 MR-387A 및 B의 생산 배지 최적화)

  • Chung, Myung-Chul;Chun, Hyo-Kon;Lee, Ho-Jae;Lee, Choong-Hwan;Kim, Su-Il;Kho, Yung-Hee
    • Applied Biological Chemistry
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    • v.38 no.2
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    • pp.100-105
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    • 1995
  • Media optimization for the production of MR-387A and B, novel aminopeptidase M inhibitors by Streptomyces sp. SL-387 isolated from a soil was studied. Optimized medium was consisted of 1% glucose, 3% soybean meal, 0.2% yeast extract, 0.1% beef extract, 0.3% NaCl, 0.01% $K_2HPO_4$, 0.3% $CaCO_3$, 0.001% $MnCl_2{\cdot}4H_2O$, 0.001% $ZnCl_2{\cdot}7H_2O$, and 0.0005% $MgSO_4{\cdot}7H_2O$, and adjusted to pH 7.0 before autoclaving. When the optimized medium was used as a fermentation medium, maximum productivity of MR-387 was reached at 120 hours of fermentation, and total productivity was 909.1 U/ml.

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Element Mobility during the Weathering of Granitic Gneiss in the Yoogoo Area, Korea. (유구지역 화강암질 편마암의 풍화작용에 따른 원소의 거동)

  • 이석훈;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.14 no.1
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    • pp.39-51
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    • 2001
  • 공주군 유구면 일대의 화강암질 편마암의 풍화작용에 따른 원소의 거동과 pH와 이차광물과의 관계를 XRF, ICP-AES, ICP-MS를 이용한 원소분석결과를 통하여 검토하였다. 이 지역의 암석은 pH6 내외의 산성환경, 침철석, 아나타제와 같은 다양한 이차광물을 생성하면서 심각한 화학조성의 변화를 초래했다. 주원소의 화학조성을 이용한 풍화지수는 토양층에서 79~88로 모암 중의 사장석이 용해되고 흑운모가 변질되어 캐올리광물의 생성이 활발한 방향으로 풍화작용이 진행되었다. 지표층으로 가면서 Al에 대한 주 원소의 거동은 Si, Ca, Na, K, P가 감소하고 Fe, Ti, Mn이 증가하는 경향을 보이며 pH가 낮은 풍화단면에서 주 원소의 변화량이 더 크다. 이 풍화대에서 Mg은 거의 일정하다. Li, As 모든 전이원소는 pH가 감소함에 따라 증가하며 특히 이들 원소는 Fe의 함량과 비례해서 증가해 침철석과 공침하였거나 표면에 흡착되어 있는 것으로 보인다. Ga은 Fe와 비례하기는 하지만 변화량은 전 풍화단면에서 일정하다. Zr, Mo, Sn, Cd은 pH에 변화에 상관없이 일정한 반면에 Rb, Sr, Ba, Y, Pb, Th, U 등은 감소하는 경향을 보인다. 특히 Rb 과 Sr은 Ca에 비례해서 감소한다. 희토류원소는 전 풍화단면에서 감소하는 경향을 보이는데 $Al_2$$O_3$에 대한 상대적인 변화량을 보면 경희토류원소는 사프롤라이트(saprolite)하부와 상부에서 부화되어 있고 중부 사프롤라이트와 토양층에서 감소하는 반면에 중희토류원소는 사프롤라이트 하부와 상부에서 감소하고 중부사프롤라이트 및 토양층에서 부화되는 경향을 보인다. 전반적으로 희토류원소의 원자번호가 클수록 손실율이 커진다. 이 풍화단면에서 원소의 거동은 각 풍화층의 pH와 생성된 이차광물의 조성에 지배를 받았다.

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lsolation of A Moderately Alkaline Pullulanase-Producing Bacillus sp. S-1 and Enzyme Characterization (알칼리성 플루라나제를 생산하는 세균 Bacillus sp. S-1의 분리와 효소특성에 관한 연구)

  • Lee, Moon-Jo;Shim, Jae-Kyoung;Park, Jin-Woo;Kim, Dong-Soo;Kim, Cheorl-Ho
    • Journal of Life Science
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    • v.7 no.2
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    • pp.95-106
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    • 1997
  • The moderately alkalophilic bacterium, identified as Bacillus sp. S-1 , was isolated from soils and effectively secrete extracellular pullulanase. The isolate was moderately alkalophilic since enzyme production occurred at pHs from 6.0 to 10.0. Extracellular crude enzymes of the isolate gave maltotriose as the major product from soluble starch and pullulan hydrolysis. Compared to other alkalophilic microbes, this isolate secreted extremely high concentration(7.0 units/ml) of pullulanase. The purified pullulanase was moderately alkalophilic and thermoactive; optimal activity was detected at pH 8.0-10.0 and between 50-60$^{\circ}$C. Even at pH 12.0, 10% of S-1 pulluanase activity remained and the strain had broad pH ranges and moderate thermo-stability for their enzyme activities. These results indicate that the new isolate have potential as producer of pullulanase for use in the starch industry.

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A Simple Method for the Monitoring of Photo-induced Alignment of the Azobenzene Molecules in a Poly(malonic ester)

  • Shin, H.D.;Hwang, U.J.;Oh, C.H.;Song, S.H.;Kim, P.S.;Han, Y.K.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.1
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    • pp.1-4
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    • 2002
  • A simple method for real-time monitoring the molecular orientation in a polymeric film was suggested. This method was examined in the polarization holograms by two recording beams on a poly(malonic ester) containing disperse red 1. The spatial distributions of the photo-induced alignment were measured and analyzed at various polarization states of two recording beams. As the result, the directions of molecular alignments could be identified easily by our method.

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Effect of Nutrients on the Production of Extracellular Enzymes for Decolorization of Reactive Blue 19 and Reactive Black 5

  • Lee Yu-Ri;Park Chul-Hwan;Lee Byung-Hwan;Han Eun-Jung;Kim Tak-Hyun;Lee Jin-Won;Kim Sang-Yong
    • Journal of Microbiology and Biotechnology
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    • v.16 no.2
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    • pp.226-231
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    • 2006
  • Several white-rot fungi are able to produce extracellular lignin-degrading enzymes such as manganese peroxidase (MnP), lignin peroxidase (LiP), and laccase. In order to enhance the production of laccase and MnP using Trametes versicolor KCTC 16781 in suspension culture, the effects of major medium ingredients, such as carbon and nitrogen sources, on the production of the enzymes were investigated. The decolorization mechanism in terms of biodegradation and biosorption was also investigated. Among the carbon sources used, glucose showed the highest potential for the production of laccase and MnP. Ammonium tartrate was a good nitrogen source for the enzyme production. No significant difference in the laccase production was observed, when glucose concentration was varied between 5 g/l and 30 g/l. As the concentration of nitrogen source increased, a lower MnP activity was observed. The optimal C/N ratio was 25 for the production of laccase and MnP. When the concentrations of glucose and ammonium tartrate were simultaneously increased, the laccase and MnP activities increased dramatically. The maximum laccase and MnP activities were 33.7 U/ml at 72 h and 475 U/ml at 96 h, respectively, in the optimal condition. In this condition, over 90% decolorization efficiency was observed.