• Title/Summary/Keyword: $k_La$

Search Result 3,693, Processing Time 0.03 seconds

Structure and Oxidation Behavior of the $LaCrO_3$-dispersed Cr alloys ($LaCrO_3$가 분산된 Cr 합금의 구조 및 산화거동)

  • Jeon, Kwang-Sun;Song, Rak-Hyun;Shin, Dong-Ryul;Jo, J.
    • Proceedings of the KIEE Conference
    • /
    • 1998.07d
    • /
    • pp.1303-1305
    • /
    • 1998
  • In order to reduce or avoid oxidation problem at operation the interconnects in SOFCs have so far mostly been made of ceramic material. It has high chemical stability both under cathode and anode condition, relatively thermal expansion coefficient that matchs that of electrolyte material YSZ. But this material shown rather weak in the low oxygen atmosphere and thermal shock, and it has lower mechanical strength than alloys. To avoid these problems one may consider to use metals or alloys as materials for interconnects. Metallic interconnects are advantageous because of their high thermal and electronic conductivities. But it has some problems, Those are high thermal expansion and oxidation at high temperature in air. To solve these problems in the interconnection material in this study, $LaCrO_3$-dispersed Cr alloys for metallic interconnector of SOFC have been investigated as a fuction of $LaCrO_3$ content in the range of 5 to 25 vol.%. The Cr alloy were prepared by mixing Cr and $LaCrO_3$ powders in high-energy ball mill for 48h and by sintering under Ar atmosphere with 5vol.% $H_2$ for 10h at $1500^{\circ}C$. The alloys had a relative density of 95% and above. The Cr alloys in composed of two kind of small $LaCrO_3$ and large Cr particles. As the $LaCrO_3$ content increased, the Cr particle size decreased but the $LaCrO_3$ particle size remained contant. Also the oxidation tests show that the $LaCrO_3$-dispersed Cr is very resistant to oxidation in air. These results means that $LaCrO_3$-dispersed Cr is a useful material for metallic interconnect of planar SOFC.

  • PDF

Rhizoma Rehmanniae induced Apoptosis in Human Cervical Carcinoma HeLa Cells (생지황(生地黃)이 자궁경부암세포(子宮經部癌細胞)(HeLa cell)에 미치는 영향(影響))

  • Kim, Joo-Yeon;Jo, Ok-Hyon;Choe, Chang-Min;Cho, Han-Baek
    • The Journal of Korean Obstetrics and Gynecology
    • /
    • v.19 no.1
    • /
    • pp.69-80
    • /
    • 2006
  • Purpose : This study is to evaluate the synergistic cytotoxicity of Rhizoma Rehmanniae(RR), in adriamycin-treated HeLa human cervical carcinoma cells. Methods : We culture HeLa cell which is human metrocarcinoma cell in D-MEM included 10% fetal bovine serum(Hyclone Laboratories) below $37^{\circ}C$, 5% $CO_2$. Then we observed apoptosis of log phage cell which is changed cultivation liquid 24 Hours periodically. Results : The combination of RR and adriamycin synergistically augmented the cytotoxicity of HeLa cells. The apoptotic cell death was accompanied by the activation of caspase-3 and -8 as well as cleavage of poly(ADP- ribose) polymerase (PARP) in HeLa cells. The co-treatment of RR with adriamycin didn't have any effect on either the expression of Bcl-2 or that of Bax. Interestingly, a synergistic increase in apoptosis by the combination of two drugs was accompanied by the enhancement of Pas and Fas ligand (FasL) expression in HeLa cells. Taken together, the combination of RR and adriamycin significantly augmented the apoptotic cytotoxicity of Fas-positive cells, such as HeLa cells. The pathway is not involved in mitochondria-dependent pathway. Conclusion : RR induces apoptosis in HeLa cells via p38 MAPK activation.

  • PDF

Cell Properties for SOFC Using Synthesized Powder of Electrolyte LSGM System and Cathode LSM System (LSGM 전해질과 LSM 양극의 합성분말을 이용한 SOFC 단위전지의 특성)

  • Lee, Mi-Jai;Nam, Jeong-Hee;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.4
    • /
    • pp.359-366
    • /
    • 2002
  • The purpose of this study is to investigate the properties of LSGM electrolyte and LSM cathode. The unit cell based on the optimum conditions and processing for high performance was fabricated and measured. The single phase of $LaGaO_3$ was obtained on sintering at $1500^{\circ}$ for 6h with composition of $(La_{0.85}Sr_{0.15})(Ga_{0.8}Mg_{0.2})O_{3-\delta}와 (La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$ and $(La_{0.85}Sr_{0.15})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$. The grain size of the sintered body was about $10∼30{\mu}m$ and electrical conductivity was 0.13 S/cm measured at $800^{\circ}$. The single phase of $LaMnO_3$ structure in $(La1-xSrx)MnO_3$ system was obtained at x=0∼0.2 and the particle size of the synthesized powder was about 40 nm. The unit cell was prepared by firing at $1200^{\circ}$ for 1h with $(La_{0.9}Sr_{0.1})MnO_3$ cathode and 0.9NiO-0.1YSZ anode screen-printed on surfaces of $(La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$ electrolyte. The grain size of the electrode was close to $1{\mu}m$ and the electrode had porous structure. The maximum power density of unit cell showed $0.3W/cm^2$ at $800^{\circ}$.

Variations in the Properties of LSGM System Electrolyte with Sr and Mg Addition and Sintering Conditions (Sr과 Mg 첨가량 및 소결조건에 따른 LSGM계 전해질의 특성 변화)

  • Lee, Mi-Jai;Park, Sang-Sun;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.4
    • /
    • pp.352-358
    • /
    • 2002
  • The variations of the properties of Sr and Mg added $LaGaO_3$ system electrolyte with the amount of the additive and the sintering condition were studied. Main phase was (La$_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$ phase for each compositions and the single phases $(La_{0.85}Sr_{0.15})(Ga_{0.85}Mg_{0.15})O_{3-\delta},(La_{0.85}Sr_{0.15})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$ and $(La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O{3-\delta}$ were obtained with the decrease in the sintering temperature and Mg addition. Thermal expansion coefficient of the $(La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$ decreased with the increase in the sintering temperature. Electric conductivity of electrolyte sintered at $1500^{circ}C$ for 1h was 0.14 S/cm at $800^{circ}C$ with 1 mA.

Effect of Annealing Atmosphere on the La2O3 Nanocrystallite Based Charge Trap Memory

  • Tang, Zhenjie;Zhao, Dongqiu;Hu, Huiping;Li, Rong;Yin, Jiang
    • Transactions on Electrical and Electronic Materials
    • /
    • v.15 no.2
    • /
    • pp.73-76
    • /
    • 2014
  • $Pt/Al_2O_3/La_2Si_5O_x/SiO_2/Si$ charge trap memory capacitors were prepared, in which the $La_2Si_5O_x$ film was used as the charge trapping layer, and the effects of post annealing atmospheres ($NH_3$ and $N_2$) on their memory characteristics were investigated. $La_2O_3$ nanocrystallites, as the storage nodes, precipitated from the amorphous $La_2Si_5O_x$ film during rapid thermal annealing. The $NH_3$ annealed memory capacitor showed higher charge storage performances than either the capacitor without annealing or the capacitor annealed in $N_2$. The memory characteristics were enhanced because more nitrogen was incorporated at the $La_2Si_5O_x/SiO_2$ interface and interfacial reaction was suppressed after the $NH_3$ annealing treatment.

Lanthanum Oxide-catalyzed Transesterification of Dimethyl Carbonate with Glycerol: Effect of Surfactant

  • Lim, Seung Rok;Lee, Sang Deuk;Kim, Hoon Sik;Simanjuntak, Fidelis Stefanus Hubertson;Lee, Hyunjoo
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.11
    • /
    • pp.3163-3168
    • /
    • 2014
  • Three kinds of lanthanum oxides ($La_2CO_3$) were synthesized from different methods and used as a catalyst in the transesterification of dimethyl carbonate (DMC) with glycerol for the synthesis of glycerol carbonate (GLC). Lanthanum oxide synthesized using a surfactant (S-La) showed a much higher GLC yield of 89.9% compared to other lanthanum oxides synthesized by calcination (C-La) and precipitation (P-La) at the reaction conditions of $90^{\circ}C$, DMC/glycerol = 2, and catalyst/glycerol = 5 wt %. The best catalyst was obtained when the surfactant/La weight ratio was 12. XRD study revealed that S-La has large amount of monoclinic and hexagonal $La_2O_2CO_3$ phases, which are assumed as active sites of the catalyst for the reaction.

Electrochemical Characterization of Electrospun LaCoO3 Perovskite Nanofibers Prepared at Different Temperature for Oxygen Reduction and Evolution in Alkaline Solution (다양한 온도에서 합성한 전기방사 LaCoO3 페롭스카이트 나노섬유의 알칼리용액에서 산소환원 및 발생반응에 대한 전기화학 특성)

  • Lopez, Kareen J.;Sun, Ho-Jung;Park, Gyungse;Eom, Seungwook;Shim, Joongpyo
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.26 no.2
    • /
    • pp.148-155
    • /
    • 2015
  • Electrospun $LaCoO_3$ perovskite nanofibers were produced for the air electrode in Zn-air rechargeable batteries using electrospinning technique with sequential calcination. The final calcination temperature was varied from 500 to $800^{\circ}C$ in order to determine its effect on the physical and electrochemical properties of the prepared $LaCoO_3$ perovskite nanofibers. The surface area of the electrospun $LaCoO_3$ perovskite nanofibers were observed to decrease with increasing final calcination temperature. Electrospun $LaCoO_3$ perovskite nanofibers calcined with final calcination temperature of $700^{\circ}C$ had the best electrocatalytic activity among the prepared perovskite nanofibers.

Effects of Laser and Electro Acupuncture Treatment with GB30·GB34 on Change in Arthritis Rat (환도·양릉천 레이저 및 전침이 관절염에 미치는 영향)

  • Kim, Mirae;Lee, Yumi;Choi, Donghee;Youn, Daehwan;Na, Changsu
    • Korean Journal of Acupuncture
    • /
    • v.36 no.4
    • /
    • pp.189-199
    • /
    • 2019
  • Objectives : This study aimed to investigate the effects of electroacupuncture (EA), the laser acupuncture (LA) and the combination therapy (LA+EA) in a collagenase-induced osteoarthritis rat model. Methods : Osteoarthritis rat model was induced by injection of collagenase into left lower articular cavity (50 μl to knee and 10 μl to ankle). In order to assess the anti-osteoarthritic effects of EA, the 650 nm LA and 650 nm LA+EA, the histopathological findings and plantar withdrawal responses were analyzed. Results : All of the treatment methods used in this study were effective in reducing pain. All treatment groups were effective in decreasing inflammatory cytokines of TNF-a and IL-6; the 650 nm LA and 650 nm LA+EA groups significantly reduced IL-1β. Conclusions : 650 nm LA and EA inhibit the production of collagenase-induced inflammatory mediators of osteoarthritis.

LPE growth of $La_{2-x}Sr_{x}CuO_{4}$ single-crystalline films

  • Tanaka, Isao;Tanabe, Hideyoshi;Watauchi, Satoshi;Kojima, Hironao
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.9 no.3
    • /
    • pp.299-302
    • /
    • 1999
  • $La_{2-x}Sr_{x}CuO_{4}$ single-crystalline films were prepared on bulk single crystals of Zn-doped $La_{2-x}Sr_{x}CuO_{4}$ as the substrates by LPE technique using two deferent methods. When prepared using an alumina crucible in normal electrical furnace, the $La_{2-x}Sr_{x}CuO_{4}$ films were contaminated with less than 3 at% aluminum from the alumina crucibles. Aluminum contamination either reduced or completely destroyed the superconductivity of the $La_{2-x}Sr_{x}CuO_{4}$ films, For LPE growth by modified TSFZ method using an infrared heating furnace without crucibles, the $La_{2-x}Sr_{x}CuO_{4}$ films of x=0.11 showed superconducting with $Tc_{onset}=36\;K$, which is 10 K higher than that in the $La_{2-x}Sr_{x}CuO_{4}$ bulk single crystals.

  • PDF

(∈, ∈ ∨qk)-FUZZY IDEALS IN LEFT REGULAR ORDERED $\mathcal{LA}$-SEMIGROUPS

  • Yousafzai, Faisal;Khan, Asghar;Khan, Waqar;Aziz, Tariq
    • Honam Mathematical Journal
    • /
    • v.35 no.4
    • /
    • pp.583-606
    • /
    • 2013
  • We generalize the idea of (${\in}$, ${\in}{\vee}q_k$)-fuzzy ordered semi-group and give the concept of (${\in}$, ${\in}{\vee}q_k$)-fuzzy ordered $\mathcal{LA}$-semigroup. We show that (${\in}$, ${\in}{\vee}q_k$)-fuzzy left (right, two-sided) ideals, (${\in}$, ${\in}{\vee}q_k$)-fuzzy (generalized) bi-ideals, (${\in}$, ${\in}{\vee}q_k$)-fuzzy interior ideals and (${\in}$, ${\in}{\vee}q_k$)-fuzzy (1, 2)-ideals need not to be coincide in an ordered $\mathcal{LA}$-semigroup but on the other hand, we prove that all these (${\in}$, ${\in}{\vee}q_k$)-fuzzy ideals coincide in a left regular class of an ordered $\mathcal{LA}$-semigroup. Further we investigate some useful conditions for an ordered $\mathcal{LA}$-semigroup to become a left regular ordered $\mathcal{LA}$-semigroup and characterize a left regular ordered $\mathcal{LA}$-semigroup in terms of (${\in}$, ${\in}{\vee}q_k$)-fuzzy one-sided ideals. Finally we connect an ideal theory with an (${\in}$, ${\in}{\vee}q_k$)-fuzzy ideal theory by using the notions of duo and (${\in}{\vee}q_k$)-fuzzy duo.