• Journal of the Korean Vacuum Society
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• v.19 no.1
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• pp.66-71
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• 2010

Spherical shape $Zn_2SiO_4:Mn$ phosphor particles with the mean particle size from submicron to micron sizes were prepared by ultrasonic spray pyrolysis method. A droplet separator was introduced to control the size distribution of the phosphor particles with spherical shape. The $Zn_2SiO_4:Mn$ phosphor particles with 2 mol% doping concentration of manganese have decay time and have photoluminescence intensities comparable with those of the latest commercial product prepared by the solid state reaction method. The size of the phosphor particles was decreased from 1 to 0.2 micrometers as the inorganic salt solution concentration was changed from 0 to 5 M. The phosphor particles prepared from the solutions above 0.5 M have photoluminescence intensities comparable with that of the latest commercial product.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1262-1265
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• 2005

The picture quality of a plasma display panel is very sensitive to the phosphor characteristics such as decay time, surface state, and even longevity of phosphor material in itself. In this work, material characteristics of $Zn_2SiO_4:Mn$, $Y_2O_3-coated$ $Zn_2SiO_4:Mn$, and $YBO_3:Tb$, which are dominant in commercial application, were examined for investigating the aging characteristics of green PDP phosphors. It was found that $Y_2O_3-coated$ $Zn_2SiO_4:Mn$ are easily degraded at high temperature. However, all the samples were very weak after vacuum annealing. The luminescence intensity was decreased by order of one magnitude.

• Proceedings of the Korean Ceranic Society Conference
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• 2000.10a
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• pp.103.1-103
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• 2000

• Proceedings of the Materials Research Society of Korea Conference
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• 2001.11a
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• pp.175-175
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• 2001

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3451-3453
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• 2010

• Proceedings of the Materials Research Society of Korea Conference
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• 1999.05a
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• pp.50-50
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• 1999

• Proceedings of the Materials Research Society of Korea Conference
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• 2002.11a
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• pp.114-114
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• 2002

• Journal of the Korean Magnetics Society
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• v.9 no.3
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• pp.149-153
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• 1999

Frequency and temperature dependence of magnetic loss has been investigated in Mn-Zn ferrites containing the sesistive temary compounds of $SiO_2-CaO-V_2O_5$. The Mn-Zn ferrite with the composition of $MnO:ZnO:Fe_2O_3=36:11:53$(by mol %) are prepared by self-propagating high-temperature synthesis. From the results of frequency dependence of core loss, it has been found that the hysteresis loss is dominant at low frequency and the eddy current loss becomes more dominant as the frequency increases. With the addition of resistive compound, the frequency dependence of core loss, it has been found that the hysteresis loss is dominant at low frequency and the eddy current loss becomes more dominant as the frequency increases. With the addition of resistive compound, the frequency region where the hysteresis loss is dominant becomes wide. The core-loss minimum occurs at about 4$0^{\circ}C$ in the specimens with the additive because of the reduction in eddy current loss.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.565-569
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• 2009

Nano-sized green and blue phosphor powders were synthesized by liquid phase method to confirm the size and morphology. By using that process, the particle sizes of green and blue phosphor particles were 80 nm and 60 nm, respectively. The characteristic comparison of $Zn_2SiO_4$ : Mn and BAM : Eu was carried out and as a result, $Zn_2SiO_4$ : Mn powders showed an higher PL performance compared to BAM : Eu.

• Journal of the Korean Chemical Society
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• v.43 no.6
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• pp.636-643
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• 1999

Green-emission intensity of a $Zn_{2-x}Mn_xSiO_4$ phosphor, which is a potential candidate as a green component in PDP device, significantly increases provided that the compound is additionally heat treated at 900$^{\circ}C$ after solid state reaction at 1300$^{\circ}C$. In order to verify origin of such an intensity enhancement after the additional heat treatment in association with the electronic and local structural change at around Mn ions, the Mn K-edge X-ray absorption spectra were recorded. From the analyses of the preedge peak corresponding to $1s{\rightarrow}3d$ bound state transition and XANES spectrum, it is known that most Mn ions are in +2 oxidation state and substitute Zn ion site regardless of the thermal treatment. In addition, EXAFS analyses revealed that Mn ions formed $MnO_4$ tetrahedra with the Mn-O bond length shortened by 0.01${\AA}$ and with reduced Debye-Waller factor in the thermally treated sample.