• Title/Summary/Keyword: $Z_2$

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Coordination Modes and Properties of Ag(I) Complex with N,N,N',N',N''-Pentamethyldiethylenetriamine

  • Chun, In-Sung;Kwon, Jung-Ah;Bae, Myung-Nam;Lee, Sim-Seong;Jung, Ok-Sang
    • Bulletin of the Korean Chemical Society
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    • v.27 no.7
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    • pp.1005-1008
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    • 2006
  • The reaction of $AgClO_{4}$ with acyclic potential tridentate N,N,N',N',N''-pentamethyldiethylenetriamine (pmdeta) has given colorless crystals suitable for X-ray crystallography. The crystal structure ($P2_{1}$/n, a = 14.413(1) $\AA$, b = 25.270(2) $\AA$, c = 16.130(1) $\AA$, b = $103.012(1){^{\circ}}$, V = 5723.7(8) A$\AA^{3}$, Z = 4, R = 0.0349) has been solved and refined. Three silver(I) ions connect four pmdeta ligands to produce discrete complex of $[Ag_3(pmdeta)_4](ClO_4)_3$. A pmdeta ligand is bridged to three silver(I) ions, and three other pmdeta ligands are chelated to each silver(I) center in a tridentate mode. Thus, the product is a rare tri-nuclear silver(I) complex with two different chemical environments. $^{13}C$ NMR and $MAS\;^{13}$C NMR indicate that the tri-nuclear silver(I) complex is not rigid in solution. The contact angles and thermal analyses of the complex are measured and discussed.

Theoretical Investigation on the Structure, Detonation Performance and Pyrolysis Mechanism of 4,6,8-Trinitro-4,5,7,8-tetrahydro -6H-furazano[3,4-f]-1,3,5-triazepine

  • Li, Xiao-Hong;Zhang, Rui-Zhou;Zhang, Xian-Zhou
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1479-1484
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    • 2014
  • Based on the full optimized molecular geometric structures at B3LYP/cc-pvtz method, a new designed compound, 4,6,8-trinitro-4,5,7,8-tetrahydro-6H-furazano[3,4-f ]-1,3,5-triazepine was investigated in order to look for high energy density compounds (HEDCs). The analysis of the molecular structure indicates that the seven-membered ring adopts chair conformation and there exist intramolecular hydrogen bond interactions. IR spectrum and heat of formation (HOF) were predicted. The detonation velocity and pressure were evaluated by using Kamlet-Jacobs equations based on the theoretical density and condensed HOF. The bond dissociation energies and bond orders for the weakest bonds were analyzed to investigate the thermal stability of the title compound. The results show that $N_1-N_6$ bond is the trigger bond. The crystal structure obtained by molecular mechanics belongs to $Pna2_1$ space group, with lattice parameters Z = 4, a = 15.3023 ${\AA}$, b = 5.7882 ${\AA}$, c = 11.0471 ${\AA}$, ${\rho}=2.06gcm^{-3}$. In addition, the analysis of frontier molecular orbital shows the title compound has good stability and high chemical hardness.

How to utilize vegetation survey using drone image and image analysis software

  • Han, Yong-Gu;Jung, Se-Hoon;Kwon, Ohseok
    • Journal of Ecology and Environment
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    • v.41 no.4
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    • pp.114-119
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    • 2017
  • This study tried to analyze error range and resolution of drone images using a rotary wing by comparing them with field measurement results and to analyze stands patterns in actual vegetation map preparation by comparing drone images with aerial images provided by National Geographic Information Institute of Korea. A total of 11 ground control points (GCPs) were selected in the area, and coordinates of the points were identified. In the analysis of aerial images taken by a drone, error per pixel was analyzed to be 0.284 cm. Also, digital elevation model (DEM), digital surface model (DSM), and orthomosaic image were abstracted. When drone images were comparatively analyzed with coordinates of ground control points (GCPs), root mean square error (RMSE) was analyzed as 2.36, 1.37, and 5.15 m in the direction of X, Y, and Z. Because of this error, there were some differences in locations between images edited after field measurement and images edited without field measurement. Also, drone images taken in the stream and the forest and 51 and 25 cm resolution aerial images provided by the National Geographic Information Institute of Korea were compared to identify stands patterns. To have a standard to classify polygons according to each aerial image, image analysis software (eCognition) was used. As a result, it was analyzed that drone images made more precise polygons than 51 and 25 cm resolution images provided by the National Geographic Information Institute of Korea. Therefore, if we utilize drones appropriately according to characteristics of subject, we can have advantages in vegetation change survey and general monitoring survey as it can acquire detailed information and can take images continuously.

Clinical Impact of Overexpression of FOXP3 and WT1 on Disease Outcome in Egyptian Acute Myeloid Leukemia Patients

  • Assem, Magda M;Osman, Ahmed;Kandeel, Eman Z;Elshimy, Reham AA;Nassar, Hanan R;Ali, Radwa E
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.10
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    • pp.4699-4711
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    • 2016
  • Background: In the last decade, it has become clear that change of gene expression may alter the hematopoietic cell quiescent state and consequently play a major role in leukemogenesis. WT1 is known to be a player in acute myeloid leukemia (AML) and FOXP3 has a crucial role in regulating the immune response. Objectives: To evaluate the impact of overexpression of WT1and FOXP3 genes on clinical course in adult and pediatric AML patients in Egypt. Patients and methods: Bone marrow and peripheral blood samples were obtained from 97 de novo non M3 AML patients (63 adult and 34 pediatric). Real-time quantitative PCR was used to detect overexpression WT1 and FOXP3 genes. Patient follow up ranged from 0.2 to 39.0 months with a median of 5 months. Results: In the pediatric group; WT1 was significantly expressed with a high total leukocyte count median 50X109/L (p=0.018). In the adult group, WT1 had an adverse impact on complete remission induction, disease-free survival and overall survival (p=0.02, p=0.035, p=0.019 respectively). FOXP3 overexpression was associated with FAB subtypes AML M0 +M1 vs. M2, M4+M5 (p =0.039) and the presence of hepatomegaly (p=0.005). Conclusions: WT1 and FOXP3 overexpression has an adverse impact on clinical presentation, treatment response and survival of pediatric and adult Egyptian AML patients.

A Super-Wideband Dipole Antenna With a Self-Complementary Structure (자기상보 구조를 갖는 초광대역 다이폴 안테나)

  • Park, Won Bin;Kwon, Oh Heon;Lee, Sungwoo;Lee, Jong Min;Park, Young Mi;Hwang, Keum Cheol
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.41 no.11
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    • pp.1414-1416
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    • 2016
  • In this paper, a SWB (Super-WideBand) dipole antenna with self-complementary structure is proposed for signal intelligence. The proposed antenna consists of a self-complementary dipole antenna and a tapered balun for balanced feeding. The measured -10 dB reflection bandwidth of the proposed antenna is more than 28:1 (0.73-20 GHz) and 3 dB axial ratio bandwidth is 3.25:1 (1.91-6.22 GHz) with RHCP (Right Hand Circular Polarization) at +z direction. The measured radiation patterns are omni-directional in lower frequency band and bi-directional in higher frequency band. The measured peak gain within -10 dB reflection bandwidth varies from 2.83 dBi to 7.66 dBi.

Evaluation method of motion seasickness by ship motions during underway in irregular waves (선박운항 중 선체동요에 의한 뱃멀미 평가방법)

  • Choi, Chan-Moon;Lee, Chang-Heon;Kim, Byung-Yeob;Ahn, Jang-Young;Kim, Seok-Jong;Shigehiro, Ritsuo
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.51 no.1
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    • pp.71-78
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    • 2015
  • In order to deduce an objective evaluation method of motion seasickness incidence (MSI) by ship motions during underway in irregular waves and to present the fundamental data of passenger comfort on the yacht and the passenger ship according to the result, the MSI of the trainees by the questionnaires was analysed and compared with the rate of variation of salivary ${\alpha}$-amylase activity (VSAA) on the training ship "A-ra ho" of Jeju national university. Relationship between rate of variation (x) by salivary ${\alpha}$-amylase activity and motion seasickness incidence (y) was described by the equation, MSI(%) = 0.6073 x + 12.189 including the correlation coefficient ($R^2=0.9853$). The result obtained through the rate of variation of salivary ${\alpha}$-amylase activity which was the quantitative evaluation method for ship motions causing seasickness was most affected by z-vertical acceleration and occurred within the frequency range 0.1 to 0.3Hz centered on 0.2Hz, and the simulation result based on this finding showed the motion seasickness rate at approximately 4% lower than the rate obtained through the survey.

Effects of Varying Levels of Fungal (Arachniotus sp.) Treated Wheat Straw as an Ingredient of Total Mixed Ration on Growth Performance and Nutrient Digestibility in Nili Ravi Buffalo Calves

  • Shahzad, F.;Abdullah, M.;Chaudhry, A.S.;Bhatti, J.A.;Jabbar, M.A.;Ahmed, F.;Mehmood, T.;Asim, M.;Ahmed, S.;Kamran, Z.;Irshad, I.;Tahir, M.N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.3
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    • pp.359-364
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    • 2016
  • The study was carried out to explore the effects of replacing wheat straw with fungal treated wheat straw as an ingredient of total mixed ration (TMR) on the growth performance and nutrient digestibility in Nili Ravi buffalo male calves. Fungal treated wheat straw was prepared using Arachniotus sp. Four TMRs were formulated where wheat straw was replaced with 0 (TMR1), 33 (TMR2), 67 (TMR3), and 100% (TMR4) fungal treated wheat straw in TMR. All TMRs were iso-caloric and iso-nitrogenous. The experimental TMRs were randomly assigned to four groups of male calves (n = 6) according to completely randomized design and the experiment continued for four months. The calves fed TMR2 exhibited a significant improve in dry matter intake, average daily weight gain, feed conversion ratio and feed economics compared to other groups. The same group also showed higher digestibility of dry matter, crude protein, neutral-, and acid detergent fibers than those fed on other TMRs. It is concluded that TMR with 33% fungal-treated wheat straw replacement has a potential to give an enhanced growth performance and nutrient digestibility in male Nili Ravi buffalo calves.

Regional bond strength of dentin bonding systems to pulp chamber dentin (치수강 상아질에 대한 상아질 접착제의 결합 강도에 관한 연구)

  • Lee, Sang-Hyuk;Choi, Gi-Woon;Choi, Kyoung-Kyu
    • Restorative Dentistry and Endodontics
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    • v.29 no.1
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    • pp.13-22
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    • 2004
  • 본 연구는 치수강 상아질 부위 및 상아질 접착제 종류에 따른 결합 강도를 측정하고 이들 사이의 상관관계를 구명하고자 시행되었다 45개의 대구치를 포매 후, 대조군에서는 교합면 법랑질 제거 후 #600 SiC paper까지 순차연마하여 상아질을 노출시켰고, 실험군에서는 치수강 개방 후 1시간동안 NaOCl에 보관 후 axial wall과 pulpal floor를 노출시켰다. 노출된 상아질 면에 상아질 접착제를 적용한 후 Z-100을 충전한 다음 40초간 광중합하였다. 사용된 상아질 접착제는 Scotchbond Multi-Purpose와 Single Bond, Clearfil SE Bond였다. $37^{\circ}C$ 증류수에 24시간 보관 후, 저속 diamond saw를 이용하여 0.7mm 두께로 수직절단하고 고속 diamond point(#104)로 단면적 $1{mm}^2$가 되도록 시편을 제작하고, Universal testing machine에서 미세인장 결합강도를 측정하였다. 1. 모든 상아질 접착제의 미세인장강도는 대조군, axial wall군, pulpal floor군 순으로 감소하는 경향을 보였다. 2. 대조군에서 SM과 BB는 SE에 비해 유의성 있게 높은 결합강도를 나타내었다(p<0.05). 3. SM과 SB는 대조군에 비해 axial wall군과 pulpal floor군에서 유의성있게 낮은 결합강도를 보였으나, SE에서는 pulpal floor군만이 유의성 있게 낮은 결합강도를 보였다(p<0.05). 4. Axial wall군과 pulpal floor군에서는 상아질 접착제의 종류에 따른 유의차를 보이지 않았다. 5. 전자현미경 소견에서는 대조군에 비해 axial wall군과 pulpal floor군이 더 부드러운 접착 계면을 나타내었다. 혼성층의 두께는 결합강도의 감소와는 관련이 없었다.

Construction of the Detection System of Endocrine Disrupters using Yeast Two-Hybrid System with Human Estrogen Receptor ligand Binding Domain and Co-activators (Human Estrogen Receptor Ligand Binding Domain (hER LBD)과 Co-activator로 구성된 효모 Two-Hybrid System을 이용한 내분비계장애물질 검출계의 구축)

  • 이행석;조은민;류재천
    • Environmental Mutagens and Carcinogens
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    • v.22 no.3
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    • pp.175-182
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    • 2002
  • Endocrine disruptors (EDs) are the chemicals that affect endocrine systems through activation or inhibition of steroid hormone response. It is necessary to have a good system to evaluate rapidly and accurately endocrine-disrupting activities of suspected chemicals and their degradation products. The key targets of EDs are nuclear hormone receptors, which bind to steroid hormones and regulate their gene transcription. We constructed a co-expression system of Gal4p DNA binding domain (DBD)- ligand binding domain of human estrogen receptor $\alpha$ or $\beta$, and Gal4p transactivation domain (TAD)-co-activator AIB-1, SRC-1 or TIF-2 in Saccharomyces cerevisiae with a chromosome-integrated lacZ reporter gene under the control of CYC1 promoter and Gal4p binding site (GAL4 upstream activating sequence, GAL4$_{UAS}$). Expression of this reporter gene was dependent on the presence of estrogen or EDs in the culture medium. We found that the two-hybrid system with combination of the hER$\beta$ LBD and co-activator SRC-1 was most effective in the xenoestrogen-dependent induction of reporter activity. The extent of transcriptional activation by those chemicals correlated with their estrogenic activities measured by other assay systems, indicating that this assay system is efficient and reliable for measuring estrogenic activity. The data in this research demonstrated that the yeast detection system using steroid hormone receptor and co-activator is a useful tool for identifying chemicals that interact with steroid receptors.s.

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Analysis of a T-Shaped UWB Printed Monopole Antenna Using Surface Currents (표면 전류 분포를 이용한 T자형 UWB 평면형 모노폴 안테나 해석)

  • Lee Dong-Hyun;Park Wee-Sang
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.16 no.9 s.100
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    • pp.883-892
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    • 2005
  • We propose a T-shaped UWB printed monopole antenna and investigate the effect of the surface currents of the radiator and ground plane. The measured impedance bandwidth of the antenna covers the range of 3.1 to 11 GHz for a VSWR$\le$2, which satisfies the requirement of the UWB operation. From the analysis of the surface currents, the proposed antenna can be treated as two asymmetric dipoles with the included angle of 90 degrees which lie along z-direction symmetrically. It is observed that the effect of the surface currents on the radiation patterns is similar to that of the corresponding dipole. The length and width of the found plane correspond the radius and length of the dipole respectively. This approach is also valid to general printed monopole antennas. Finally, we included an antenna example having resonance at a lower frequency by tapering the edges of the ground plane and another example having a bandstop characteristic by inserting an inverted-U slot on the radiator, and explain those antennas using the surface currents.