• Title/Summary/Keyword: $Z_2$

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Cu and Zn Ions Adsorption Properties at Various pH with a Synthetic Zeolite (합성 제올라이트를 이용한 pH에 따른 Cu와 Zn 이온의 흡착특성)

  • Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.805-813
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    • 2012
  • The removal property of Cu and Zn ions by chemical precipitation and adsorption using zeolite(Z-C1) prepared from coal fly ash(CFA) were evaluated in this study. Adsorption kinetic and equilibrium mechanisms described to analyze parameters and correlation factors with Lagergen $1^{st}$ and $2^{nd}$ order model and Langmuir and Freundlich model. Analysis of adsorption kinetics data revealed that the pseudo $2^{nd}$ order kinetics mechanism was predominant. The equilibrium data in pH 3 - 5 were able to be fitted well to a Langmuir model, by which the maximum adsorption capacities($q_{max}$) were determined at 124.9 - 140.1 mg $Cu^{2+}/g$ and 153.2 - 166.9 mg $Zn^{2+}/g$, respectively. We found that Z-C1 has a potential application as absorbents in metal ion recovery with low pH.

Size measurements of galaxies in the nearby clusters (z<0.2) using the GALAPAGOS

  • Lee, Jae Hyung;Lee, Gwang-Ho;Lee, Myung Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.66.2-66.2
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    • 2014
  • The size evolution of galaxies is one of the fascinating issues in these days. It is known that the size of a galaxy is closely related to other galactic properties, such as the central surface brightness, stellar mass, and redshift. However, we need to measure the sizes of galaxies precisely to understand those relations. We determine the sizes of early-type galaxies in the nearby clusters (z<0.2) using the GALAPAGOS. The GALAPAGOS is a tool which provides surface photometry for multiple sources, which make it fast and convenient to deal with huge image data. We run the GALAPAGOS individually to the Subaru/Suprime-Cam and the HST/ACS images for the same targets. We present and discuss the result of our size measurements for further applications.

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A New Superconductor with the 1212 Structure $(Pb,Sn)Sr_2(Ca,Lu)Cu_2O_z$

  • Lee, Ho-Keun;Jee, Chan-Soo
    • Progress in Superconductivity
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    • v.2 no.1
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    • pp.6-10
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    • 2000
  • New cuprates with the nominal composition $(Pb_{0.75}Sn_{0.25})Sr_2(Ca_{1-x}Lu_x)Cu_2O_z(x=0.4{\sim}1.0)$ have been synthesized. These materials exhibit superconducting properties for 0.4 $\leq$ x $\leq$ 0.7. It is also observed that the superconductivity of the as-prepared sample is enhanced by post-annealing at high temperature followed by quenching. X-ray diffraction analysis reveals that the c lattice parameter decreases as x increases whereas the a lattice parameter is nearly independent of the value of x for both the as-prepared and the post-treated samples. The thermoelectric power measurements indicate that the post-heat-treatments result in an increase in the hole carrier density which account for the observed increase of $T_c$. Bulk superconductivity with a $T_c$ value of 60 K is observed in this system.

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Subaru Weak-lensing Analysis of the Merging Cluster ZwCL 1447.2+2619 at z=0.37

  • Lee, Juheon;Jee, Myungkook J.
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.61.2-61.2
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    • 2018
  • ZwCL 1447.2+2619 is a merging galaxy cluster at z=0.37 with clear substructures in X-ray emission and galaxy distribution. In addition, the system possesses distinct radio relics. In order to constrain the merger scenario, it is necessary to measure both the distribution and mass of the cluster dark matter. We perform weak lensing analysis of ZwCL 1447.2+2619 using Subaru imaging data. We detect clear lensing signal from the cluster after carefully addressing instrumental systematics. In this poster, we present our preliminary results on our mass reconstruction and discuss the comparison with X-ray and radio results.

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Cerebrosides from Longan Arillus

  • Ryu, Ji-Young;Kim, Ju-Sun;Kang, Sam-Sik
    • Archives of Pharmacal Research
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    • v.26 no.2
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    • pp.138-142
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    • 2003
  • From the pulp of Euphoria longana (Longan Arillus), three cerebroside molecular species have been isolated. Six known cerebrosides, soyacerebrosides I and II, 1-Ο-$\beta$-D-glucopyranosyl-(2S,3R,4E,8E)-2-(2 -lignoceroylamino)-4,8-octadecadiene-1,3-diol (long an cerebroside I) and its 8Z isomer (Iongan cerebroside II), momor-cerebroside I, and phytolacca cerebroside, were identified as major components of these cerebroside molecular species. All the cerebrosides were shown to be a mixture of geometrical isomers (8E and 8Z) of sphingosine-type or phytosphingosine-type glucocerebrosides possessing 2-hydroxy fatty acids. The structures of these cerebrosides have been determined on the basis of chemical and spectroscopic evidence.

High redshift clusters in ELAIS N1/N2 fields

  • Hyun, Minhee;Im, Myungshin;Kim, Jae-Woo
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.90.1-90.1
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    • 2012
  • Galaxy clusters, the largest gravitationally bound system, are important means to place constraints on cosmological model and to study the evolution and the formation of galaxies and their large scale distribution. We will report results from our study of galaxy clusters in the European Large Area ISO Survey North1/North2(ELAIS-N1/N2) fields, covering a total of 10.8 $deg^2$. We combine multiple wavelength data from IMS survey, UKIRT Infrared Deep Survey-Deep Extragalactic Survey (UKIDSS-DXS, JK bands), Spitzer Wise-area InfraRed Extragalactic survey (SWIRE, Optical-Infrared bands), and CFHT (u,g,r,i,z bands.) The photometric redshifts are derived from these datasets and are used to search for high redshift galaxy clusters at 0.8 < z < 1.5.

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Ionized gas outflows in z~2 WISE-selected Hot Dust Obscured Galaxies

  • Jun, Hyunsung
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.2
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    • pp.55.2-55.2
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    • 2018
  • The Wide-field Infrared Survey Explorer (WISE) mission enabled efficient selection of Active Galactic Nuclei (AGN) with high luminosities and large obscuration. According to the merger driven AGN powering scenarios, luminous and obscured AGN are in a stage where they go through feeding of gas accretion into the central black hole, and feedback to the host galaxy through outflows. We report the rest-frame UV-optical spectra of Hot Dust Obscured Galaxies (Hot DOGs) at z~2, WISE color-selected to be extremely reddened AGN. Most of the targets show blueshifted and broadened [OIII] line profiles indicative of ionized gas outflows. We present the occurrence and strength of the outflows, and discuss the impact of luminous, obscured AGN activity on their hosts.

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A STUDY ON THE ADAPTATION OF DENTIN BONDING AGENTS TO TOOTH STRUCTURE (치질에 대한 상아질 접착제의 접합도에 관한 연구)

  • Park, Sung-Taek;Cho, Young-Gon;Hwang, Ho-Keel
    • Restorative Dentistry and Endodontics
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    • v.20 no.2
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    • pp.732-743
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    • 1995
  • The purpose of this study was to evaluate the adaptation of light cured dentin bonding agents to tooth structure by measuring contraction gaps on interfaces between cavity wall and composite resin under SEM study. In this study, class V cavities with cementum margin were prepared on the buccal surfaces of 15 extracted human premolar teeth and teeth were randomly assigned 3 groups of 5 teeth each. The cavities were filled with three dentin bonding agents and two composite resins were investigated for this study: three dentin bonding agents; Scotchbond 2, Scotchbond Multi-Purpose. All-Bond 2, two composite resins; Silux Pius, Z-100. Group 1 : Scotchbond 2 + Silux Plus Group 2 : Scotchbond Multi~Purpose + Z-100 Group 3 : All-Bond 2 + Z-100 The restored teeth were stored in 100% relative humidity at $37^{\circ}C$ for 7 days. And then, the roots of the teeth were removed with the tapered fissure bur and the remaining crowns were sectioned occlusogingivally through the center of restorations. Adaptation at tooth-restoration interface was assesed occlusally, gingivally, and axially by scanning electron microscope. The results were as follows : 1. In Group 1, the adaptation to dentinal wall of Scotchbond 2 was poor, but the adaptation to enamel wall of Scotchbond 2 was excellent. 2. In Group 2, the adaptation to occlusal was axial wall and gingival wall of Scotchbond Multi-Purpose was excellent. Especially in axially wall, the dentin bonding agents infiltrated into dentinal tubules and there was excellent adaptation to dentinal wall. 3. In Group 3, the adaptation to occlusal wall and axial wall of All-Bond 2 was excellent. But in gingival wall, there was gap formation between composite resin and dentin bonding agent.

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A Study of the Structure and Thermal Property of $Cu^{2+}\;and\;NH_{4}{^+}$ Ion-Exchanged Zeolite A

  • Park, Jong-Yul;Kang, Mi-Sook;Choi, Sang-Gu;Kim, Yang;Kim, Un-Sik
    • Bulletin of the Korean Chemical Society
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    • v.15 no.5
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    • pp.341-346
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    • 1994
  • The frameworks of $(Cu(NH_3)_3OH^+)_x(NH_4^+)_{12-x}-A{\cdot} zH_2O$ which were prepared by the ion-exchange of zeolite A with ammoniac cupric nitrate solution are more stable than those of $Cu_xNa_{12-2x} -A$ obtained by the ion exchange with aqueous cupric nitrate solution are more stable than those of $Cu_xNa_{12-2x} -A$ obtained by the ion exchange with aqueous cupric nitrate solution. An energetic calculation was made on the relatively stable $(CuOH^+)_2(NH_4^+)_{10}-A{\cdot} 2H_2O$ prepared by the partial evacuation of $(Cu(NH_3)_3OH^+)_2(NH_4^+)_{10}-A{\cdot} zH_2O$. The mean stabilization energies of water, OH-, and $NH_4^+$ ions are -30.23 kcal/mol, -60.24 kcal/mol, and -16.65 kcal/mol, respectively. The results of calculation were discussed in terms of framework stability. The $(Cu(NH_3)_3OH^+)_2(NH_4^+)_{10}-A{\cdot} zH_2O$ zeolite shows two step deammoniation reactions. The first deammoniation around 210 $^{\circ}$C (third DSC peak) was attributed to the decomposition of $[Cu(NH_3)_3OH^+]$ ion and the second one around 380 $^{\circ}$C (fourth DSC peak) was ascribed to the decomposition of $NH_4^+$ ion. The activation energies of the first and second deammoniation reactions were 99.75 kJ/mol and 176.57 kJ/mol, respectively.