• Title/Summary/Keyword: $Z_2$

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NON-TRIVIALITY OF TWO HOMOTOPY ELEMENTS IN π*S

  • Liu Xiugui
    • Journal of the Korean Mathematical Society
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    • v.43 no.4
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    • pp.783-801
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    • 2006
  • Let A be the mod p Steenrod algebra for p an arbitrary odd prime and S the sphere spectrum localized at p. In this paper, some useful propositions about the May spectral sequence are first given, and then, two new nontrivial homotopy elements ${\alpha}_1{\jmath}{\xi}_n\;(p{\geq}5,n\;{\geq}\;3)\;and\;{\gamma}_s{\alpha}_1{\jmath}{\xi}_n\;(p\;{\geq}\;7,\;n\;{\geq}\;4)$ are detected in the stable homotopy groups of spheres, where ${\xi}_n\;{\in}\;{\pi}_{p^nq+pq-2}M$ is obtained in [2]. The new ones are of degree 2(p - 1)($p^n+p+1$) - 4 and 2(p - 1)($p^n+sp^2$ + sp + (s - 1)) - 7 and are represented up to nonzero scalar by $b_0h_0h_n,\;b_0h_0h_n\tilde{\gamma}_s\;{\neq}\;0\;{\in}\;Ext^{*,*}_A^(Z_p,\;Z_p)$ in the Adams spectral sequence respectively, where $3\;{\leq}\;s\;<\;p-2$.

A CLASS OF ARITHMETIC FUNCTIONS ON PSL2(ℤ), II

  • Spiegelhalter, Paul;Zaharescu, Alexandru
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.2
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    • pp.443-455
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    • 2014
  • Atanassov introduced the irrational factor function and the strong restrictive factor function, which he defined as $I(n)=\displaystyle\prod_{p^{\alpha}||n}^{}p^{1/{\alpha}}$ and $R(n)=\displaystyle\prod_{p^{\alpha}||n}^{}p^{{\alpha}-1}$ in [2] and [3]. Various properties of these functions have been investigated by Alkan, Ledoan, Panaitopol, and the authors. In the prequel, we expanded these functions to a class of elements of $PSL_2(\mathbb{Z})$, and studied some of the properties of these maps. In the present paper we generalize the previous work by introducing real moments and considering a larger class of maps. This allows us to explore new properties of these arithmetic functions.

Preparation and Nonlinear Optical Properties of CuCl-doped Nonlinear Optical Glasses : III. Bimodal Distribution of CuCl Nanocrystals and Temperature Dependent Optical Absorption Spectra (CuCl 미립자가 분산된 비선형 광학유리의 제조와 비선형 광특성: III. CuCl 반도체 미립자의 Bimodal 분포 특성과 온도에 따른 광흡수도)

  • 윤영권;한원택
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.436-442
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    • 1997
  • The bimodal distribution of CuCl nano-crystals precipitated in alumino-borosilicate glass matrix (30SiO2-45B2O3-7.5Al2O3-7.5Na2O-7.5CaO-2.5GeO2(mole %)) was investigated by TEM and the temperature dependent optical spectroscopy. Two types of CuCl particles with different size were observed by TEM and it was confirmed by the splitting of Z3 absorption peak at low temperature and the occurrence of deflection point in the optical spectra with temperature.

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Development of an Isolable Active Ester, Diethyl Thiophosphoryl [(Z)-(2-Aminothiazol-4-yl)-2-(Methoxyimino)acetate (DAMA) for the Synthesis of Cefotaxime

  • Yoon, Man-Young;Lee, Hee-Bong;Shin, Hyun-Ik
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.407-410
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    • 2011
  • An isolable activated ester, diethyl thiophosphoryl [(Z)-(2-aminothiazol-4-yl)-2-(methoxyimino)acetate (9a, DAMA) was prepared in high purity, which was at least stable for 7 d at $25^{\circ}C$ and 6 months at $5^{\circ}C$. Its reaction with 7-ACA (4) in the presence of tributylamine in i-PrOH provided cefotaxime (1) of high purity in good yield. Preparation of DAMA and its reaction with 7-ACA (4) to 1 was performed in one-pot manner, respectively with minimal unit operations of stirring and filtration.

Isolation and Structure of $[Ph_3P(OH)]^+[ $N_3$]^-$ ($[Ph_3P(OH)]^+[ $N_3$^-$의 분리 및 구조)

  • Beom Jun Lee;Won Seok Han;Soon Won Lee
    • Korean Journal of Crystallography
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    • v.12 no.3
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    • pp.141-144
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    • 2001
  • From the reaction of Na[Ga(N₃)₄] with PPh₃, an ionic compound [Ph₃P(OH)]/sup +/[N₃]/sup -/ (1) was isolated. Compound 1 was characterized by spectroscopy (¹H-NMR, /sup 13C{¹H}-NMR, and IR) and X-ray diffraction. Crystallographic data for 1 : orthorhombic space group P2₁2₁2₁, a = 10.491 (4) Å, b=11.603(5)Å, c=13.149(5)Å, Z=4, R(wR₂)=0.0547(0.0978).

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Generalized Scattering Matrix of Multi-port($2{\times}2$port, 1port) Rectangular Waveguide Using $TE^z_{mn}$ Mode Matching Method ($TE^z_{mn}$ 모드정합법을 이용한 다중포트($2{\times}2$포트, 1포트) 직사각형 도파관의 일반화 산란행렬 추출)

  • Lee, J.K.;Mun, S.Y.;Park, K.U.;Heo, Y.K.;Cho, Y.K.
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2003.11a
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    • pp.79-83
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    • 2003
  • Multi-port($2{\times}2$port, 1port) rectangular waveguide discontinuity problem has been analyzed by use of $TE^x_{mn}$ (mono)mode matching method. Matrix size can be reduced significantly in comparison with $TE_{mn}&TM_{mn}$(full-wave)mode matching method. the present results is compared with those by CST MicroWave Studio to validate the presint method.

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A BORSUK-ULAM TYPE THEOREM OVER ITERATED SUSPENSIONS OF REAL PROJECTIVE SPACES

  • Tanaka, Ryuichi
    • Journal of the Korean Mathematical Society
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    • v.49 no.2
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    • pp.251-263
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    • 2012
  • A CW complex B is said to be I-trivial if there does not exist a $\mathbb{Z}_2$-map from $S^{i-1}$ to S(${\alpha}$) for any vector bundle ${\alpha}$ over B a any integer i with i > dim ${\alpha}$. In this paper, we consider the question of determining whether $\Sigma^k\mathbb{R}P^n$ is I-trivial or not, and to this question we give complete answers when k $\neq$ 1, 3, 8 and partial answers when k = 1, 3, 8. A CW complex B is I-trivial if it is "W-trivial", that is, if for every vector bundle over B, all the Stiefel-Whitney classes vanish. We find, as a result, that $\Sigma^k\mathbb{R}P^n$ is a counterexample to the converse of th statement when k = 2, 4 or 8 and n $\geq$ 2k.

PHOTOISOMERIZATION STUDIES OF SUBSTITUTED DIPHENYLBUTADIENES: ROLE OF POLARIZED EXCITED STATES IN THE PHOTOPROCESSES OF $\alpha,\omega$-DIPHENYLPOLYENES

  • Singh, A.K.;Krishna, T.S.R.
    • Journal of Photoscience
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    • v.5 no.2
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    • pp.47-51
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    • 1998
  • Direct irradiation of 1Z,3E-1-cyano-1,4-diphenylbutadiene (2) and 1Z,3E-1-cyano-3-methyl-1,4-diphenylbutadiene (3) in organic solvents viz. n-hexane, methanol and acetonitrile results in preferential isomerization of the double bond substituted with cyano group via one-photon-one-bond isomerization process. The quantum efficiency of the isomerization of 3 is more than 2 in all the three solvents. Photoproducts of 2 and 3 (viz. 2a, 2b, 3a, 3b) also exhibited similar photoisomerization trends. The results are discussed in terms of the effects of substituents on the potential energy surface of the excited singlet states of $\alpha$,$\omega$-diphenylpolyenes, and the role of zwitterionic dipolar species in the photoisomerization process of linearly conjugated C=C polyenes is highlighted.

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계산과학을 통한 MoSe2 물분해 광촉매 성질 연구

  • Gang, Seong-U
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.273-276
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    • 2016
  • 최근 single-layer $MoSe_2$와 같은 2차원의 TMD 화합물들이 물분해 광촉매로서 각광받고 있다. TMD 화합물 중 single-layer $MoSe_2$는 수소 발생 반응을 일으킬 수 있으나 산소 발생 반응은 일으킬 수 없어 산화 반응을 진행시킬 추가적인 전극이 필요하다. 이 연구에서는 strain과 doping을 통해 valence band를 아래로 이동시켜 $MoSe_2$를 더 좋은 물분해 광촉매로 변화시키는 방법을 모색하였다. 먼저 Armchair, zigzag, biaxial isotropic, z-axis direction으로 strain을 걸어줄 때 전자구조의 변화를 관찰하였다. z-axis 방향으로 -2.5% strain을 걸어주었을 때 VBM이 0.07eV만큼 감소하였다. 또한 Mo를 Nb로 치환하고 Se를 P, As로 치환한 다음 전자구조를 관찰하였다. Nb와 doping의 경우 VBM이 감소함을 확인하였으며 As doping의 경우 산화반응이 일어날 수 있고 산화력과 환원력이 비슷해짐을 알아내었다. 또한 산화반응과 환원반응이 일어나는 위치가 분리됨을 확인하였다.

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Preparation and Characterization of $Ag/TiO_{2-x}N_x$ Nanoparticles

  • Liu, Z.Q.;Li, Z.H.;Zhou, Y.P.;Ge, C.C.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.436-437
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    • 2006
  • The $Ag/TiO_{2-x}N_x$ nanoparticles were synthesized by photochemical deposition in a $TiO_{2-X}N_X$ suspension system. The prepared products were characterized by means of XRD, Uv-vis and photoluminescence spectra (PL). Its photocatalytic activity was investigated by the decomposition of methylene blue (MB) solution under illumination of visible and ultraviolet light, respectively. Compared to $TiO_{2-x}N_x$, the photocatalytic activity of the as-prepared $Ag/TiO_{2-x}N_x$ is obviously enhanced due to the decreasing recombination of a photoexcitated electron-hole pairs. The Mechanism in which photocatalytic activity is enhanced has been discussed in detail.

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