• Title/Summary/Keyword: $Yb^{3+}$

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Thermoelectric Properties of P-type (Ce1-zYbz)0.8Fe4-xCoxSb12 Skutterudites

  • Choi, Deok-Yeong;Cha, Ye-Eun;Kim, Il-Ho
    • Korean Journal of Metals and Materials
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    • v.56 no.11
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    • pp.822-828
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    • 2018
  • P-type Ce/Yb-filled skutterudites were synthesized, and their charge transport and thermoelectric properties were investigated with partial double filling and charge compensation. In the case of $(Ce_{1-z}Yb_z)_{0.8}Fe_4Sb_{12}$ without Co substitution, the marcasite ($FeSb_2$) phase formed alongside the skutterudite phase, but the generation of the marcasite phase was inhibited by increasing Co concentration. The electrical conductivity decreased with increasing temperature, exhibiting degenerate semiconductor behavior. The Hall and Seebeck coefficients were positive, which confirmed that the specimens were p-type semiconductors with holes as the major carriers. The carrier concentration decreased as the concentration of Ce and Co increased, which led to decreased electrical conductivity and increased Seebeck coefficient. The thermal conductivity decreased due to a reduction in electronic thermal conductivity via Co substitution, and due to decreased lattice thermal conductivity via double filling of Ce and Yb. $(Ce_{0.25}Yb_{0.75})_{0.8}Fe_{3.5}Co_{0.5}Sb_{12}$ exhibited the greatest dimensionless figure of merit (ZT = 0.66 at 823 K).

High-power Yb Fiber Laser with 3.0-kW Output (3.0 kW 고출력 발진 단일 모드 Yb 광섬유 레이저)

  • Park, Jong Seon;Park, Eun Ji;Oh, Ye Jin;Jeong, Hoon;Kim, Ji Won;Jung, Yeji;Lee, Kangin;Lee, Yongsoo;Cho, Joonyong
    • Korean Journal of Optics and Photonics
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    • v.32 no.4
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    • pp.147-152
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    • 2021
  • We report high-power continuous-wave operation of a Yb-doped fiber laser at 1070 nm, pumped by high-power laser diodes at 976 nm. Based on theoretical calculation of the stimulated Raman scattering and temperature distribution in the fiber, we construct a bidirectionally pumped Yb-fiberlaser system incorporating a pair of fiber Bragg gratings and a cladding light stripper. The fiber laser yields 3.0 kW of continuous-wave output at 1070 nm in a diffraction-limited beam with M2 ≈ 1.26 for 4.1 kW of incident pump power, corresponding to a slope efficiency of 81.5%. The prospects for further power scaling are discussed.

Electrical Conductivity of Ytterbium Sesquioxide ($Yb_2O_3$) ($Yb_2O_3$의 전기 전도도)

  • 강영환;최재시;윤기현
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.23-26
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    • 1981
  • The electrical conductivity of highly pure polycrystalline $Yb_2O_3$ has been measured from 650 to 105$0^{\circ}C$ under oxygen pressure range of $10^{-5}$ to 102 torr. The conductivity dependence of oxygen pressure in the temperature region from 750 to 105$0^{\circ}C$ is approximated by $\sigma$ $\alpha$ $Po_2^{1/5.3}$. This shows that the conduction mechanism is associated with doubly ionized metal vacancies. Fairly low activation energy and the lack of oxygen pressure dependence are found over the temperature range of 650 to 75$0^{\circ}C$. The conduction mechanism can be explaned by not metal vacancies, but hopping oxygen ions in the oxide.

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Production and Properties of Mannanase by a Bacillus amyloliquefaciens Isolate (Bacillus amyloliquefaciens 분리균의 Mannanase 생산성과 효소특성)

  • Yoon, Ki-Hong
    • Korean Journal of Microbiology
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    • v.50 no.2
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    • pp.158-163
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    • 2014
  • In the acidic LB plate, a bacterial strain was isolated from homemade soybean paste as a producer of the extracellular mannanase. The isolate YB-1402, which was a Gram-positive rod-shaped bacterium with spore, has been identified as Bacillus amyloliquefaciens on the basis of its 16S rDNA sequence and biochemical properties. Maximum mannanase productivity of the isolate YB-1402 was reached approximately 150 U/ml in LB broth supplemented with konjac (3.0%). The molecular mass of YB-1402 mannanase was estimated to approximately 38.0 kDa by zymogram of the culture filtrate on SDS-PAGE. The mannanase of culture filtrate was the most active at $55^{\circ}C$ and pH 5.5. The mannanase activity was completely maintained after pre-incubation at pH 3.0 to 10.0 for 1 h. The predominant products resulting from the mannanase hydrolysis were mannose, mannobiose and mannotriose for LBG or mannooligosaccharides. The enzyme could hydrolyze mannooligosaccharides larger than mannobiose.

Crystal Growth and Spectroscopic Investigation of Yb,Er:$YCa_4O{(BO_3)}_3$ for 1.55$\mu m$ Laser

  • Jeong, Suk-Jong;Yu, Young-Moon
    • Proceedings of the Optical Society of Korea Conference
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    • 1999.08a
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    • pp.220-221
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    • 1999
  • Single crystals of Yttrium Calcium Oxyborate (YCOB) doped with different concentrations of Er3+ and Yb3+ ions were growth by Czochralski method. High qualities of crystals in morphology and transparency were obtained . Analysis on crystal structure and lattice parameters were performed by X-ray diffraction method. It was found that congruent melting composition is YCA4.2O1.2(BO3)3. Absorption and fluorescence properties of grown crystals were also reported.

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Microstructure and Mechanical Properties of Mg-Zn-Y-Yb Alloys Produced by Consolidation of Rapidly Solidified Ribbons

  • Sakamoto, Yoshihito;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1045-1047
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    • 2006
  • Fabrication of $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy has been performed through the consolidation of rapidly solidified ribbons. The $Mg_{95.75}Zn_1Y_3Yb_{0.25}$ bulk alloy exhibited excellent mechanical properties, high tensile yield strength of 530 MPa, and large elongation of 3 %. Microstructure of the alloy was characterized by equiaxed fine grains that consist of -Mg, long period ordered (LPO) structure phase, and $Mg_5RE$-type cubic compound. The strengthening of the alloys may be due to fine grains with LPO structure phase and $Mg_5RE$-type compound.

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Production and Properties of Mannanase and Xylanase by a Bacillus subtilis Isolate (Bacillus subtilis 분리균의 Mannanase와 Xylanase 생산성과 효소 특성)

  • Yoon, Ki-Hong
    • Microbiology and Biotechnology Letters
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    • v.43 no.3
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    • pp.204-211
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    • 2015
  • A bacterial strain capable of hydrolyzing xylan and locust bean gum (LBG) was isolated from the Saemangeum tideland of Korea. Based on the biochemical properties and the 16S rRNA gene sequence, the isolate YB-30 was identified as Bacillus subtilis. Xylanase productivity was increased effectively when B. subtilis YB-30 was grown in the presence of wheat bran, while mannanase productivity was increased drastically when grown in the presence of konjac or LBG. Particularly, maximum mannanase and xylanase activities were detected in the culture filtrate of media containing 3.5% konjac and 1% wheat bran. Both enzyme productivities reached maximum levels in the stationary growth phase. The culture filtrate exhibited the highest activity at 60℃ and pH 6.0 for mannanase and at 55℃ and pH 5.5 for xylanase, respectively. Both enzymes were not stable at high temperatures and xylanase was less stable than mannanase. In addition, wheat bran was hydrolyzed to liberate reducing sugar to a greater extent than rice bran by the culture filtrate because the wheat bran contained more arabinoxylan than the rice bran. Hence, xylanase and mannanase produced by B. subtilis YB-30 have a potential use as feed additive enzymes.