• Title/Summary/Keyword: $Y_2O_3$ additive

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Evaporation Characteristics of a Water Droplet Containing Sodium Acetate Trihydrate as an Additive (첨가제로 아세트산 나트륨-3수화물을 함유한 물 액적의 증발 특성)

  • Park, Jae-Man;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.61-68
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    • 2004
  • The evaporation phenomena of waterr droplet which has sodium acetate trihydrate($CH_3COONa{\cdot}3H_2O$) as a fire suppression additive were studied. Solutions of sodium salt up to 50% and heated stainless-steel surface were used in the experiment. The evaporation process was recorded using a charge-coupled-device camera at 120 frames per second. The average evaporation rate of the sodium acetate trihydrate soluation was lower than that of pure water at a given surface temperature and decreased with the concentration increase due to the precipitation of salt in the liquid film and change of surface tension. The variation of liquied film diameter was measured by time and it was increased by the hot surface temperature increase.

첨가제가 이산화염소 표백에 미치는 영향

  • 윤병호;왕립군;김세종;김용식;최경화
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.84-88
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    • 1999
  • In chlorine dioxide delignigication or bleaching, chlorate is mainly formed by the reaction between chlorite and hypochlorous acid, thus scavengers of chlorine or hypochlorous acid can be used to reduce the formation of chlorate which is unfavorable to environment. In this study, additives such as sulfamic acid, DMSO, hydrogen peroxide, or sodium chlorite was added to chlorine solution or pure $ClO_2$ solution to check their reactivity with $Cl_2$ and $ClO_2$. These additives were also added directly into general $ClO_2$ solution which contained certain amount of chlorine, then the additive-treated $ClO_2$ solution were used in bleaching stages. The aim of this procedure was to remove the original amount of chlorine that was thought to be possibly the main reason for the formation of chlorate and AOX. The additives were found to be able to eliminate chlorine very fast and selectively, but $H_2$ $O_2$ should be used under pH4, otherwise it also reacts with $ClO_2$. After the additives reacted With $Cl_2$, DMSO turned into an inactive product $(CH_3)_2SO_2$, While Sulfamic acid turned into $HClSO_3H$ that still remained active in oxidation, and $NaClO_2$ produced $ClO_2$. The addition of $HNaClO_2$ showed significant improvement in delignification but the deeper delignification led to higher formation of chlorate. When the additive-treated chlorine dioxide solutions were used in bleaching, both sulfamic acid, DMSO, and hydrogen peroxide showed no significant changes of DE brightness and Kappa number. The formation of chlorate was reduced by addition of sulfamic acid, DMSO and hydrogen peroxide.

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EFFECT OF $Na_{2}O$ ADDITION ON MAGNETIC PROPERTIES OF $SrZn_{2}-W$ TYPE HEXAGONAL FERRITE

  • Yamamoto, Hiroshi;Fujii, Hiroshi;Mitsuoka, Takayuki
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.735-739
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    • 1995
  • An experiment was carried out to investigate the effect of $Na_{2}O$ additive on the magnetic and physical properties of $SrZn_{2}-W$ type hexagonal ferrite. The specimens were prepared by the conventional manufacturing methods without atmosphere control. It was found that the magnetic properties of SrO.2ZnO.$8Fe_{2}O_{3}$ are considerably improved on adding 1.5wt% $Na_{2}O$. Theoptimum condition of making magnet with suitable properties are as follows : chemical analysis composition : $Sr^{2+}_{0.852}Zn^{2+}_{1.721}Na^{+}_{0.301}Fe^{2+}_{0.723}Fe^{3+}_{15.703}O_{27}$ ; semisintering condition : $1300^{\circ}C\;{\times}\;1h$ in air ; sintering condition : $1250^{\circ}C\;{\times}\;0.5h\;T_{c}=371^{\circ}C,\;H_{A}=1091.5kA/m,\;K_{A}=2.13{\times}10^{5}J/m^{3}\;and\;n_{B}=31.8\mu\textrm{B}$.

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Study on the Cycling Performances of Lithium-Ion Polymer Cells Containing Polymerizable Additives

  • Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.319-322
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    • 2009
  • Gel polymer electrolytes were prepared by immersing a porous poly(vinylidene fluoride-co-hexafluoropropylene) membrane in an electrolyte solution containing small amounts of polymerizable additive (3,4-ethylenedioxythiophene, thiophene, biphenyl). The organic additives were electrochemically oxidized to form conductive polymer films on the electrode at high potential. With the gel polymer electrolytes containing different organic additive, lithium-ion polymer cells composed of carbon anode and LiCo$O_2$ cathode were assembled and their cycling performances were evaluated. Adding small amounts of thiophene or 3,4-ethylenedioxythiophene to the gel polymer electrolyte was found to reduce the charge transfer resistance in the cell and it thus exhibited less capacity fading and better high rate performance.

Characteristics of the sintered body of the Al2TiO5 with addition of LAS (β-spodumene) and Fe2O3 (LAS (β-spodumene)와 Fe2O3 첨가에 따른 Al2TiO5의 소결체 특성 연구)

  • Kim, Sang-Hun;Kang, Eun-Tae;Kim, Ung-Soo;Hwang, Kwang-Taek;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.57-63
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    • 2012
  • $Al_2TiO_5$ ceramics were sintered by a solid-state reaction. LAS (${\beta}$-spodumene) and $Fe_2O_3$ were added to the $Al_2TiO_5$ composition for enhancement of sintering behavior such as mechanical strength and thermal shock resistance. The sintered body was much densified by addition of LAS and $Fe_2O_3$ because LAS formed the liquid-phase and $Fe_2O_3$ suppressed the grain growth. We have systematically investigated the sintering characteristics, microstructures, mechanical properties, and thermal shock resistance according to the change of the amount of additive. When the additive of LAS (20 wt%)-$Fe_2O_3$ was added to $Al_2TiO_5$, it confirmed that superior mechanical properties of the fracture strength of over 120 MPa and the thermal shock resistance of over $1,200^{\circ}C$ were achieved.

Effeet of Al2O3, MgO and SiO2 on Sintering and Hydration Behaviors of CaO Ceramics

  • Kim, Do-Kyung;Cho, Churl-Hee;Goo, Bong-Jin;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.528-534
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    • 2002
  • CaO ceramics were prepared by conventional sintering process and their hydration behaviors were evaluated by measuring weight increment on saturated water vapor pressure at ambient temperature. CaCO$_3$ and limestone were used as CaO source materials and $Al_2$O$_3$, MgO and SiO$_2$ were added as sintering agents. $Al_2$O$_3$ was a liquid phase sintering agent to increase densification and grain growth rates, whereas MgO and SiO$_2$, densification and grain growth inhibitors. Regardless of composition, all of the prepared CaO ceramics showed the improved hydration resistance as bulk density increased. Especially, when bulk density was more than 3.0 g/㎤, there was no weight increment after 120 h of hydration. Therefore, to decrease contact area between CaO and water vapor by increasing bulk density with the $Al_2$O$_3$ sintering additive was effective for the improvement of CaO hydration resistance.

Synthesis of Silicon Nitride from Ethyl Silicate(II) : Effect of Additive on the Nitridation of Silicon Nitride (Ethyl Silicate로부터 Silicon Nitride의 합성(II) : 실화반응에서 첨가제의 영향)

  • 오일환;박금철
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.561-569
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    • 1988
  • Mixtures of very small amounts of additive, carbon and silica(about 0.46${\mu}{\textrm}{m}$) which synthesized by the hydrolysis of ethyl silicate, the molar ratio of SiO2/C was fixed to 1/10, was nitrided at 145$0^{\circ}C$. It was considered that the optimum amount of additive to promote the nitridation reaction was below 2.0wt%. By the addition of additive, the nitridation reaction was promoted and formation of $\beta$-Si3N4 was promoted at 145$0^{\circ}C$ for 1hour, but, the nitridation reaction was decreased and the ratio of $\alpha$/$\beta$ of Si3N4, was increased at 145$0^{\circ}C$ for 5 hours. The crystal phase was $\alpha$ phase and the nitridation reaction was promoted and the particle size of silicon nitride was become smaller by the addition of $\alpha$-Si3N4, but silicon nitride of whisker-like form was produced by the addition of transition elements. There was a difference in the lattice constants of $\alpha$-Si3N4, but no difference in its of $\beta$-Si3N4 according to kinds of added substance and reaction time.

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Effects of Lithium Bis(Oxalate) Borate as an Electrolyte Additive on High-Temperature Performance of Li(Ni1/3Co1/3Mn1/3)O2/Graphite Cells (LiBOB 전해액 첨가제 도입에 따른 Li(Ni1/3Co1/3Mn1/3)O2/graphite 전지의 고온특성)

  • Jeong, Jiseon;Lee, Hyewon;Lee, Hoogil;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.58-67
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    • 2015
  • The effects of electrolyte additives, lithium bis(oxalate)borate (LiBOB), fluoroethylene carbonate (FEC), vinylene carbonate (VC), 2-(triphenylphosphoranylidene) succinic anhydride (TPSA), on high-temperature storage properties of $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$/graphite are investigated with coin-type full cells. The 1 wt.% LiBOB-containing electrolyte showed the highest capacity retention after high temperature ($60^{\circ}C$) storage for 20 days, 86.7%, which is about 5% higher than the reference electrolyte, 1.15M lithium hexafluorophosphate ($LiPF_6$) in ethylene carbonate/ethyl methyl carbonate (EC/EMC, 3/7 by volume). This enhancement is closely related to the formation of semi-carbonate compounds originated from $BOB^-$ anions, thereby resulting in lower SEI thickness and interfacial resistance after storage. In addition, the 1 wt.% LiBOB-containing electrolyte also exhibited better cycle performance at 25 and $60^{\circ}C$ than the reference electrolyte, which indicates that LiBOB is an effective additive for high-temperature performance of $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$/graphite chemistry.

Effect of the supporting substrate on the production yield for geometrically controlled carbon coils

  • Park, Se-Mi;Kim, Sung-Hoon;Jeon, Young-Chul;Kim, DongUk
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.218-219
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    • 2012
  • Carbon coils could be synthesized using $C_2H_2/H_2$ as source gases and $SF_6$ as an incorporated additive gas under thermal chemical vapor deposition system. Prior to the carbon coils deposition reaction, two kinds of samples having different combination of Ni catalyst and substrate were employed, namely a commercially-made $Al_2O_3$ ceramic boat with Ni powders and a commercially-made $Al_2O_3$ substrate with Ni layer. By using a commercially-made $Al_2O_3$ ceramic boat, the production yield of carbon coils could be enhanced as much as 10 times higher than that of $Al_2O_3$ substrate. Furthermore, the dominant formation of the microsized carbon coils could be obtained by using $Al_2O_3$ ceramic boat.

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A study on the ZNR (Zinc Oxide Nonlinear Resistor) with $KNO_3$ ($KNO_3$의 첨가가 ZNR (Zinc Oxide Nonlinear Resistor)에 미치는 영향에 관한 연구)

  • 안영필;김복희
    • Journal of the Korean Ceramic Society
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    • v.17 no.3
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    • pp.133-140
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    • 1980
  • Nonohmic properties of ZnO ceramics with various small amounts of additives were studied in relation to sintering temperature and additive content. The kinds of additives used were basic additives ($Bi_2O_3$, $BaCO_3$, $MnCO_3$, $Cr_2O_3$) and $KNO_3$ Especially this study has focused on the effects of $KNO_3$ in ZnO ceramics with basic additives. SEM studies indicated that microstructures of ZnO, $KNO_3$ and basic additives showed homogenuous grain size in comparison to ZnO and basic additives compounds. The nonohmic exponent ($\alpha$) in ZnO, $KNO_3$ and basic additives component were measured as high as 40.

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