• Title/Summary/Keyword: $Y_2O_3$: $Eu^{3+}$

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Geochemical Studies on Petrogenesis of the Cretaceous Myeongseongsan Granite in the Northwestern Gyeonggi Massif (경기육괴 북서부에 분포하는 백악기 명성산 화강암의 성인에 대한 지화학적 연구)

  • Yi, Eun Ji;Park, Ha Eun;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.26 no.4
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    • pp.327-339
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    • 2017
  • The Cretaceous Myeongseongsan Granite in the northwestern Gyeonggi Massif consists of a major pale pink-colored biotite monzogranite and a minor white-colored biotite alkaligranite. Low Sr and high Ba concentrations, negative Eu-anomalies in REE plot, negative Sr anomalies in spider diagram, a negative correlation between Sr and Rb, and positive correlations between Sr and Ba and $Eu/Eu^*$ indicate that a fractional crystallization of both plagioclase and K-feldspar played a significant role during magma evolution. The Myeongseongsan Granite is plotted in I-& S-type granites on I, S, A-type granite classification scheme. While the biotite monzogranite is plotted in unfractionated I-& S-type granite, the biotite alkaligranite is plotted in fractionated I-& S-type granite, which indicates that the biotite alkaligranite is a more differentiated product. In order to elucidate the nature of the protoliths of the peraluminous Myeongseongsan magma, we plotted in $Al_2O_3/TiO_2$ vs. $CaO/Na_2O$ and Rb/Sr vs. Rb/Ba diagrams, and they suggest that the Myeongseongsan Granite was derived from clay-poor metagreywackes and meta-psammites or their igneous counterparts. Whole-rock zircon saturation temperature indicates that the Myeongseongsan magma was melted at $740-799^{\circ}C$.

Effect of Chip Wavelength and Particle Size on the Performance of Two Phosphor Coated W-LEDs

  • Yadav, Pooja;Joshi, Charusheela;Moharil, S.V.
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.2
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    • pp.66-68
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    • 2014
  • Most commercial white LED lamps use blue chip coated with yellow emitting phosphor. The use of blue excitable red and green phosphors is expected to improve the CRI. Several phosphors, such as $SrGa_2S_4:Eu^{2+}$ and $(Sr,Ba)SiO_4:Eu^{2+}$, have been suggested in the past as green components. However, there are issues of the sensitivity and stability of such phosphors. Here, we describe gallium substituted $YAG:Ce^{3+}$ phosphor, as a green emitter. YAG structures are already accepted by the industry, for their stability and efficiency. LEDs with improved CRI could be fabricated by choosing $Y_3Al_4GaO_{12}:Ce^{3+}$ (green and yellow), and $SrS:Eu^{2+}$ (red) phosphors, along with blue chip. Also, the effect of a slight change in chip wavelength is studied, for two phosphor-coated w-LEDs. The reduction in particle size of the coated phosphors also gives improved w-LED characteristics.

Synthesis of Barium Hexaaluminate Phosphros Using Combinatorial Chemistry (조합화학을 이용한 망간(2+)과 유로피움)2+)이 첨가된 Barium Hexaaluminate 형광체의 합성 및 광특성 분석)

  • 박응석;최윤영;손기선;김창해;박희동
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.134-139
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    • 2000
  • The main objective of the present investigation is to show the feasibility of combinatorial chemistry by applying this method to phosphor syntehses. In this respect barium hexaaluminate phosphor was prepared by the split-pool combinatorial method, which enabled much more rapid search of optimum compositions of target phosphors than conventional synthetic methods. Barium hexaaluminate phosphors doped with Eu2+ exhibit blue emission while those co-doped with Mn2+ and Eu2+ exhibit green emission. Basically, the phosphor doped with 1.3 mole of Ba and 0.06~0.15 mole of Eu2+ exhibit the maximum value of emission intensity at 435${\mu}{\textrm}{m}$. Under the UV and VUV extitations, the barium hexaaluminate phosphor co-doped with Mn2+ and Eu2+ shows strong green emission.

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Comparative Study on Geochemical Characteristics of Stream Sediments and Mylonitic Granites in the Unbong Area (운봉지역 하상퇴적물과 압쇄상화강암류의 지구화학적 특성 비교연구)

  • Park, Young-Seog;Park, Dae-Woo;Kim, Jong-Kyun;Kim, Sung-Won
    • Economic and Environmental Geology
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    • v.40 no.6
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    • pp.727-738
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    • 2007
  • The present study investigation the geochemical characteristics of the stream sediments in the Unbong area was conducted to enable a understanding the natural background and a prediction the prospects of geochemical disaster as a result of that bed rocks(mylonitic granites, Kim et al., 1992). We systematically collected seventy three stream sediments samples by wet sieving along the primary channels. Major, trace and rare earth element(REE) concentrations, combined with mineralogical characteristics, were determined by XRD, XRF, ICP-AES and NAA analysis methods. Major element concentrations for the stream sediments in the Unbong area were $SiO_2\;36.94{\sim}65.39wt.%,\;Al_2O_3\;10.15{\sim}21.77wt.%,\;Fe_2O_3\;3.17{\sim}10.90wt.%,\;CaO\;0.55{\sim}5.27wt.%,\;MgO\;0.52{\sim}4.94wt.%,\;K_2O\;1.38{\sim}4.54wt.%,\;Na_2O\;0.49{\sim}3.36wt.%,\;TiO_2\;0.39{\sim}1.27wt.%,\;MnO\;0.04{\sim}0.22wt.%,\;P_2O_5\;0.08{\sim}0.54wt.%$. Trace and REE concentrations for the stream sediments were $Cu\;4.8{\sim}134ppm,\;Pb\;24.2{\sim}82.5ppm,\;Sr\;95.9{\sim}739ppm,\;V\;19.9{\sim}124ppm,\;Zr\;52.9{\sim}145ppm,\;Li\;25.2{\sim}3.3ppm,\;Co\;3.87{\sim}50.0ppm,\;Cr\;17.4{\sim}234ppm,\;Hf\;3.93{\sim}25.2ppm,\;Sc\;4.60{\sim}20.6ppm,\;Th\;3.82{\sim}36.9ppm,\;Ce\;45.7{\sim}243ppm,\;Eu\;0.89{\sim}2.69ppm,\;Yb\;1.42{\sim}5.18ppm$. According to the comparison of average major element concentrations, CaO, $Na_2O\;and\;K_2O$ contents are higher in stream sediments than in bed rocks(mylonitic granites, Kim et al., 1992) $Al_2O_3\;and\;SiO_2$ contents show good correlation both stream sediments and bed rocks(mylonitic granites, Kim et al., 1992). Yb and Eu in the stream sediments show a positive correlation with $SiO_2$. In contrast, the stream sediments display a negative correlation.

White ACPEL Device with ZnS:Cu,Cl, $Tb_3Al_5O_{12}:Ce^{3+}$, and CaS:$Eu^{2+}$ Phosphors Using a Layered Structure

  • Park, Bong-Je;Seo, Hong-Seok;Ahn, Jun-Tae;Oh, Dae-Kon;Chung, Woon-Jin;Han, Ji-Yeon;Jang, Ho-Seong;Jeon, Duk-Young
    • ETRI Journal
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    • v.31 no.6
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    • pp.803-805
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    • 2009
  • Improvement of the color rendering index (CRI) and luminance of a white alternate current powder electroluminescent (ACPEL) device has been attempted using ZnS:Cu,Cl, $Tb_3Al_5O_{12}$:Ce (TAG:Ce), and CaS:Eu phosphors with a layered structure. The device with TAG:Ce and ZnS:Cu,Cl phosphors showed a CRI of 75, with a luminance increase of about 30% depending on the thickness of the TAG:Ce. Further CRI improvement was attempted using CaS:Eu. When they were separately screen-printed, the CRI was increased up to 89 with no decrease in luminance.

Enhanced light-emitting performances of $Y_2O_3:Eu$ phosphor for FPD application.

  • Nazarov, Michael;Kang, Jong-Hyuk;Jeon, Duk-Young;Bukesov, Sergey;Popovici, Elisabeth-Jeanne;Muresan, Laura
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1087-1090
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    • 2004
  • Samples of yttrium oxide doped with trivalent europium have been prepared by ceramic techniques, under different synthesis conditions; barium chloride ($BaCl_2$) and sodium tetraborate ($Na_2B_4O_7$) were tested as flux. The improvement of luminescence properties in dependence on substitution of $Eu^{3+}$ for $Y^{3+}$ in the host lattice, under electron and UV excitations is demonstrated The obtained results are discussed with respect to the employed processing method.

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Ferroelectric properties of BET Thin Films for FRAM (FRAM 응용을 위한 BET 박막의 강유전 특성)

  • Kim, Kyoung-Tae;Kim, Tae-Hyung;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.200-203
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    • 2003
  • Ferroelectric europium-substitution $Bi_4Ti_3O_{12}$ thin films were fabricated by spin-coating onto a Pt/Ti/$SiO_2$/Si substrate. The $Bi_{3.25}Eu_{0.75}Ti_3O_{12}$ (BET) films have polycrystalline structure annealed at 700 C. We investigated that the influence of $Bi_4Ti_3O_{12}$ thin films by substituting for Bi ions with Bi ions using X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). From the XPS measurement, it was suggested that the stability of the metal-oxygen octahedral should be related to substitute for Bi ions with Eu ions at annealed $800^{\circ}C$. The BET thin films showed a large remanent polarization (2Pr) of $60.99C/cm^2$ at an applied voltage of 10 V. The BET thin films exhibited no significant degradation of switching charge at least up to $5{\times}10^9$ switching cycles at a frequency of 50 kHz.

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Growth and characterization of Eu-doped bismuth titanate (BET) thin films deposited by sol-gel method

  • Kang Dong-Kyun;Kim Byong-Ho
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.05a
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    • pp.194-197
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    • 2006
  • Lead-free bismuth-layered perovskite ferroelectric europium-substituted $Bi_{4}Ti_{3}O_{12}(BTO)$ thin films have been successfully deposited on Pt/Ti/$SiO_2$/Si substrate by a sol-gel spin-coating process. $Bi(TMHD)_3,\;Eu(THMD)_3,\;Ti(OiPr)_4$ were used as the precursors, which were dissolved in 2-methoxyethanol. The thin films were annealed at various temperatures from $600^{\circ}\;to\;720^{\circ}C$ in oxygen ambient for 1 hr, which was followed by post-annealed for 1 hr after depositing a Pt electrode to enhance the electrical properties. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to analyze the crystallinity and surface morphology of layered perovskite phase, respectively. The remanent polarization value of the BET thin films annealed at $720^{\circ}C\;was\;25.95{\mu}C/cm^2$ at an applied voltage of 5 V.

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