• 한국전기전자재료학회논문지
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• 제29권3호
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• pp.186-191
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• 2016

The effects of $Eu^{3+}$ doping on the structural, morphological, and optical properties of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors prepared by solid-state reaction technique were investigated. XRD patterns exhibited that all the synthesized phosphors showed a monoclinic system with a dominant (220) diffraction peak, irrespective of the content of $Eu^{3+}$ ions. The surface morphology of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors was studied using scanning electron microscopy and the grains showed a tendency to agglomerate as the content of $Eu^{3+}$ ions increased. The excitation spectra of the phosphor powders were composed of a strong charge transfer band centered at 294 nm in the range of 230~340 nm and two intense peaks at 354 and 389 nm, respectively, arising from the $^6H_{15/2}{\rightarrow}^6P_{7/2}$ and $^6H_{15/2}{\rightarrow}^4M_{21/2}$ transitions of $Dy^{3+}$ ions. The emission spectra of the $Mg_{0.85}MoO_4$:10 mol% $Dy^{3+}$ phosphors without incorporating $Eu^{3+}$ ions revealed a strong yellow band centered at 573 nm resulting from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$. As the content of $Eu^{3+}$ was increased, the intensity of the yellow emission was gradually decreased, while that of red emission band located at 614 nm began to appear, approached a maximum value at 10 mol%, and then decreased at 15 mol% of $Eu^{3+}$. These results indicated that white light emission could be achieved by controlling the contents of the $Dy^{3+}$ and $Eu^{3+}$ ions incorporated into the $MgMoO_4$ host crystal.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2477-2480
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• 2007

MgAl2O4:Eu3+ red-light emitting powder phosphor was prepared at temperature as low as 500 oC within a few minutes by using the combustion route. The prepared powder was characterized by X-ray diffraction, scanning electron microscopy and Fourier-transform infrared spectrometry. The luminescence of Eu3+-activated MgAl2O4 shows a strong red emission dominant peak around 611 nm, which can be attributed to the 5D0-7F2 transition of Eu3+ ions from the synthesized phosphor particles under excitation (394 nm). Electron paramagnetic resonance (EPR) measurements at the X-band showed that no signal could be attributed to Eu2+ ions in MgAl2O4.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
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• pp.223.1-223
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• 2003

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.203-206
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• 2003

$Y_2O_2S:Eu$ phosphors with fine particle have been synthesized by citric acid-gel method. In this method, $Na_2S_2O_3$ was added to $Y_2O_3S:Eu$ precursor, then the mixture was fired at $1000^{\circ}C$ for 3h in $S_2$ atmosphere. When the $Y_2O_3S:Eu$ precursor was pre-annealed at $400{\sim}700^{\circ}C$ before the firing of the mixture, the fine particles with a diameter of around 1 ${\mu}m$ were obtained after the firing. The phosphor pre-annealed at $400^{\circ}C$ showed a luminance and CIE color coordinates of 2350 $cd/m^2$ and (0.61, 0.37), respectively, at under excitation of 3 kV and $60{\mu}A/cm^2$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 디스플레이 광소자 분야
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• pp.61-64
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• 2002

A novel ceramic synthesis technique, combustion synthesis, is explored to produce a orange-emitting $SnO_{2}:Eu^{3+}$ phosphors. This technique involves a reaction of metal salts with a citric acid as an organic fuel. The variation of the ratio of citric acid to metal introduces change in reaction temperature and atmosphere of the combustion reaction, which in turn influences crystallinity and luminescence properties of the final products seriously. And, the heat treatment of the as-synthesized product increases its luminescence intensity. Especially, the samples treated at above $1100^{\circ}C$ show a orange-emission peak, which is attributed to the formation of single phase and well-crystallized $SnO_{2}:Eu$ oxides in the rutile structure

• 대한화학회지
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• 제46권4호
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• pp.336-345
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• 2002

본 연구에서는 조합화학을 이용하여 $CaO-Gd_2O_3-Al_2O_3$계에서 $Eu^{3+}$와 $Tb^{3+}$활성 적색 및 녹색 PDP용 형광체를 탐색하였으며 탐색된 형광체의 합성온도, 최적조성,발광 특성 등을 조사하였다. $CaO-Gd_2O_3-Al_2O_3$의 삼성분계의 형광특성 라이브러리를 작성하기 위하여 210개의 다른 조성을 가진 시료를 고분자 착체 중합법으로 합성하였다. 합성된 형광체 분말을 VUV PL로 측정하여 형광 특성 라이브러리를 작성하였고 발광특성이 잘 나타난 시료를 XPD를 이용하여 결정 구조를 확인하였다. 적색 형광체로서 탐색된 $Ca_{\alpha}$G$d_{0.95-\alpha-\beta}$$Al_\beta$$O_\delta$ : Eu(0.02< $\alpha+\beta$ <0.04)형광체는 색순도 면에서 상용형광체보다 개선된 특성을 보였으며 녹색 형광체로서 탐색된 $CaGdAl_3O_7$ : Tb, Ca$Al_{12}$$O_{19}$ : Tb, $Gd_4Al_2$$O_9$ : Tb, $Gd_3Al_5$$O_{12}$ : Tb 형광체 중에서 $CaGdAl_3O_7$ : Tb, Ca$Al_{12}$$O_{19}$ : Tb형광체는 상용 형광체에 비해 잔광시간이 짧은 특성을 보였다

• 한국세라믹학회지
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• 제47권2호
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• pp.122-126
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• 2010

In this article photoluminescence of the $Al_2O_3:xCr_2O_3$ solid solutions prepared by solid state reaction method are represented. The effect of $Cr_2O_3$-activator concentration and heat treatment time on the PL characteristics have been discussed in conjunction with microstructure of phosphor samples. The $Al_2O_3:xCr_2O_3$ phosphors show the highest PL intensity at x=0.003 mole when the samples are reacted at $1600^{\circ}C$ for 5 h. The PL emission and absorption spectra show the maximum peaks at 698 nm and at 398 nm respectively. The CIE color coordinate is (x=0.646, y=0.316) at 0.003 mole $Cr_2O_3$, which value is very close to the NTSC coordinate of red color. This characteristic feature of $Al_2O_3:xCr_2O_3$ has been applied for an additive to improve the color characteristic of other red phosphor $LiEuW_2O_8$ which has a relatively poor color purity with an emission peak centered at 615 nm and with a CIE coordinate (x=0.530, y=0.280). The $Al_2O_3:0.003Cr_2O_3$ phosphor has been mixed with the $LiEuW_2O_8$ phosphor powder and the PL characteristics and CIE color coordinates are characterized. The $Al_2O_3:xCr_2O_3$ phosphor was found effective for improving the CRI (color rendering index) of $LiEuW_2O_8$ phosphor.

• 전기화학회지
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• 제16권3호
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• pp.184-189
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• 2013

졸-겔법 및 졸-겔법과 연소법을 함께 사용한 하이브리드법으로 각각 얻어진 건식 젤을 열처리하여 $Ba_2SiO_4:Eu^{2+}$ ($B_2S:Eu^{2+}$) 분말을 합성하였으며, 이들 공정에 따른 구조 및 발광 특성 변화를 조사 하였다. Si 공급원으로서는 tetraethyl orthosilicate (TEOS)를 사용하였다. 졸-겔법에 의한 건식 젤로 하소 과정 없이 합성한 경우 TEOS 양의 변화에 따라서 상전이가 관찰되었으며, 1.2M TEOS에서 $B_2S:Eu^{2+}$ 단일상을 얻었을 수 있었다. 반면에 하소 과정을 거친 1.2M TEOS로 합성된 분말에서는 졸-겔법과 하이브리드법 모두 $B_2S:Eu^{2+}$와 미량의 $BaSiO_3:Eu^{2+}$ ($BS:Eu^{2+}$) 상이 혼재하는 분말을 얻을 수 있었으나, 이들 분말은 하소 과정 없이 합성된 것보다 발광특성이 약 두배 정도 우수하였다. 하이브리드법에 의한 $B_2S:Eu^{2+}$는 졸-겔법에 의한 것에 비하여 발광강도가 약간 떨어지나 공정 시간을 획기적으로 단축 시킬 수 있는 장점을 보이고 있었다. 1.1M TEOS로 하소 과정을 거쳐 하이브리드법으로 얻어진 분말은 $B_2S:Eu^{2+}$ 단일상으로 구성되어 있었으며, $Eu^{2+}$이온의 $4f^65d^1{\rightarrow}4f^7$ 전이에 의한 가장 강한 강도를 갖는 녹색 발광 (505 nm) 스펙트럼을 보이고 있었다.

• 전기화학회지
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• 제12권3호
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• pp.234-238
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• 2009

In the excitation spectra of $YNbO_4$ : $Eu^{3+}$, the charge transfer (CT) band around 270 nm due to $[NbO_4]^{3-}$$-Eu^{3+}$ interaction and sharp excitation peaks by f-f transition of $Eu^{3+}$ strongly appeared simultaneously. CT band depended on the structural properties of powders, showing the red-shift with increasing the crystallinity, while the f-f transition peaks were independent of the crystallinity. For $YNb_{1-x}Ta_xO_4$ : $Eu^{3+}$ (x = 0.05.0.2), $[TaO_4]^{3-}$. configuration was locally constructed, leading to the blue-shift in CT band and the decrease in the red emission intensity with increasing the Ta content.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1355-1359
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• 2006

Due to its efficient red emission, $Eu^{3+}$ ion has been doped in various host materials. $GdCa_4B_3O_{10}:Eu^{3+}$ phosphor for red emission has been prepared by solid state reaction. Photoluminescence properties for the phosphor under UV and VUV excitation were investigated. The $GdCa_4B_3O_{10}:Eu^{3+}$ phosphor under both excitation conditions shows typical red emission spectrum centered at 611 nm with several weak peaks due to energy transfer from $^5D_O\;to\;^7F_J(J=1,2,3,4)$ of $Eu^{3+}$ ion. On the other hand, the activator content exhibiting the concentration quenching under UV and VUV irradiation is 10 mole% and 2.5 mole%, respectively.