• Membrane Journal
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• v.22 no.2
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• pp.113-119
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• 2012

$YBaCo_2O_{5+{\delta}}$ oxide was synthesized by solid state reaction and a typical dense membrane has been prepared using as-prepared powder by unilateral pressing and sintering at $1,180^{\circ}C$. The $YBaCo_2O_{5+{\delta}}$ membraneswas analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). XRD analysis showed the double layered perovskite structure was observed over $1,150^{\circ}C$ without impurities. Oxygen permeation was measured in the temperature range from 750 to $950^{\circ}C$ according to oxygen partial pressure difference between feed and permeation side. The oxygen permeation flux increased with increasing temperature and oxygen partial pressure and the maximum oxygen flux of $YBaCo_2O_{5+{\delta}}$ membrane with 1.0 mm thickness was about 0.15 mL/$cm^2{\cdot}min$ at $950^{\circ}C$ and $PO_2$ = 0.42 atm. The activation energy for oxygen permeation decreased with decreasing oxygen partial pressure to be 76.0 kJ/mol at the condition of $PO_2$ = 0.21 atm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.351-354
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• 1998

The formation of the $YBa_2Cu_30_{7_\delta}$(Y123) thick films has been investigated by a surface diffusion Imcess between $3BaCu0_2$+2CuO composite coating powder and a $Y_2BaCuO_5$(Y211). This reaction has been studied in the temperature of $930^{\circ}C$ and $940^{\circ}C$ for 2h to 10h in an oxygen atmosphere. The Y211 substrates becomes covered by co-precipitation of Y123 grains and CuO inclusions. X-ray diflractotnctn. revealed that the lager consisted of an orthorhombic crystal structure. The maximum Jc of $400A/\textrm{cm}^2$ is abtained when the specimen was heat-treated at $930^{\circ}C$ for 6h on the Y211 substrate.

• Journal of the Korean institute of surface engineering
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• v.29 no.5
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• pp.430-436
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• 1996

We have grown superconducting thin films on various substrates using a pulsed laser deposition (PLD) method. $YBa_2Cu_3O_7-\delta$ (YBCO) superconducting thin films with the superconducting transition temperature ($T_{c. offset}$) of 87K were grown on Si substrates using yittria-stabilized zirconia (YSZ) and $CeO_2$ double buffer layers. We have developed a large area pulsed laser deposition system. The system was designed to deposit up to 6 different materials on a large area substrate up to 7.5cm in diameter without breaking a vacuum. The preliminary runs of the deposition of YBCO superconducting thin films on $SrTiO_3$ substrate using this system showed a very uniform thickness profile over the entire substrate holder area. $T_{c}$ of the deposited YBCO thin film, however, was scattered depending on the position and the highest value was 85K.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.11a
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• pp.256-259
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• 2002

The critical currents of sintered $YBa_{2}Cu_{3}O_{6.5+\delta}$ were measured as the variables with the corrosive time in the humid air. The corrosive process was studied by means of the current changes. Ag coating on the textured YBCO and polytetrafluoroethylene (PTFE) coating on the sintered YBCO were prepared. The critical current densities of different YBCO samples with and without coatings were compared. Both Ag coating and PTFE coating can well protect YBCO from moisture and $CO_{2}$.

• The Korean Journal of Ceramics
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• v.6 no.2
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• pp.164-167
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• 2000

The barium rich region of the Y-Ba-Cu-O-C system includes a tetragonal perovskite-like phase, which possesses a wide homogeneity region toward yttrium, copper and carbonate ion on the one hand, and toward oxygen, on the other hand. Accounting for vacancies ($\square$-vacancy) this phase could be described by the general formula per unit cell: {Ba$_8$}[Y$_{3-z}$Cu$_{5-x}$$(CO_3)_n$ $\square$$_{x+x-n}$]O$_{y{\pm}{\delta}y}$ (*). Here, cube-octahedral sites are represented in braces, while quasioctahedral ones with proper octahedral (Y, Cul), square (Cu2) and triangular (CO$_3$) configuration are shown in square brackets. The formula (*) was confirmed by full-profile Rietveld refinement based on X-ray diffraction data of YBa$_{5}$Cu$_2$O$_y$ (1-5-2 phase). Homogeneity region limits of the phase (*) at 96$0^{\circ}C$ in air were determined to be -0.33$\leq$x$\leq$1.80, 0.33$\leq$z$\leq$2.00, 0$\leq$n$\leq$3.