• Title/Summary/Keyword: $V_E$ Spectrum

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Hot-wall epitaxial growth and characterization of $Cd_{1-x}Mn_xTe$ films (Hot-wall epitaxy 법에 의한 $Cd_{1-x}Mn_xTe$ 박막의 성장과 특성)

  • 황영훈;엄영호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.126-131
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    • 1999
  • $Cd_{1-x}Mn_xTe$ thin films were grown on GaTs (100) substrates by hot-wall epitaxy method. From the XRD measurements, it was found that CdTe/GaAs (100)film was grown as a single crystal with the same growth plane of (100) and $Cd_{1-x}Mn_xTe$film as a poly crystal as Mn content was increased, and the lattice constant was decressed with the similar gradient of bulk crystal as x was increased. From the PL measurements, $L_1$line due to the exciton trapped on an acceptor and $L_2$line due to an exciton trapped on a shallow potential fluctuation were observed, and $L_1$line was observed only in $Cd_{0.91}Mn_{0.09}$te but it was disappeared probably due to a stronger lacalization of excitons with increasing alloy fluctuation.$L_2$line was dominant in case of $x{\ge}0.2$and for higher Mn contents the broad transition about 2.0eV associated to the 3d levels of the $Mn^{2+}$ ion dominated the PL spectrum, and the $L_2$ transition become weaker and weaker. For$x{\ge}0.4$, the transition line about 2.0eV due to $Mn^{2+}$ion showed no shift.

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The Physicochemical and Optical Characteristics of FeaSibCcHd Films (FeaSibCcHd 박막의 물리·화학 및 광학적 특성)

  • Kim, Kyung-soo;Jean, Bup-Ju;Jung, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.105-111
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    • 1999
  • When the preparation method of iron silicide films possess the annealing process, the interfacial state of the films is not fine. The good quality films were obtained as the plasma was used without annealing processing. Since the injected precursors were various active species in the plasma state, the organic compound was contained in the prepared films. We confirmed the formation of Fe-Si bonds as well as the organic compound by Fe and Si vibration mode in Raman scattering spectrum at $250cm^{-1}$ and Ft-IR. Because of epitaxy growth being progressed by the high energy of plasma at the low temperature of substrate, iron silicide was epitaxially grown to ${\beta}$-phase that had lattice structure such as [220]/[202] and [115]. Band gap of the prepared films had value of 1.182~1.174 eV and optical gap energy was shown value of 3.4~3.7 eV. The Urbach tail and the sub-band-gap absorptions were appeared by organic compound in films. We knew that the prepared films by plasma were obtained a good quality films because of being grown single crystal.

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COSMOLOGY WITH MASSIVE NEUTRINOS: CHALLENGES TO THE STANDARD ΛCDM PARADIGM

  • ROSSI, GRAZIANO
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.321-325
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    • 2015
  • Determining the absolute neutrino mass scale and the neutrino mass hierarchy are central goals in particle physics, with important implications for the Standard Model. However, the final answer may come from cosmology, as laboratory experiments provide measurements for two of the squared mass differences and a stringent lower bound on the total neutrino mass - but the upper bound is still poorly constrained, even when considering forecasted results from future probes. Cosmological tracers are very sensitive to neutrino properties and their total mass, because massive neutrinos produce a specific redshift-and scale-dependent signature in the power spectrum of the matter and galaxy distributions. Stringent upper limits on ${\sum}m_v$ will be essential for understanding the neutrino sector, and will nicely complement particle physics results. To this end, we describe here a series of cosmological hydrodynamical simulations which include massive neutrinos, specifically designed to meet the requirements of the Baryon Acoustic Spectroscopic Survey (BOSS) and focused on the Lyman-${\alpha}$ ($Ly{\alpha}$) forest - also a useful theoretical ground for upcoming surveys such as SDSS-IV/eBOSS and DESI. We then briefly highlight the remarkable constraining power of the $Ly{\alpha}$ forest in terms of the total neutrino mass, when combined with other state-of-the-art cosmological probes, leaving to a stringent upper bound on ${\sum}m_v$.

Comparative Study of Undoped and Nickel-Doped Molybdenum Oxide Photoanodes for PEC Water Splitting

  • Garcia-Garcia, Matias
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.377-389
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    • 2022
  • The current global energy supply depends heavily on fossil fuels. This makes technology such as direct water splitting from harvesting solar energy in photoelectrochemical (PEC) systems potentially attractive due to its a promising route for environmentally benign hydrogen production. In this study, undoped and nickel-doped molybdenum oxide photoanodes (called photoanodes S1 and S2 respectively) were synthesized through electrodeposition by applying -1.377 V vs Ag/AgCl (3 M KCl) for 3 hours on an FTO-coated glass substrate immersed in molibdatecitrate aqueous solutions at pH 9. Scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) were used for microstructural and compositional characterizations of the photoanodes. In addition, the optical and photoelectrochemical characterizations of these photoanodes were performed by UV-Visible spectroscopy, and linear scanning voltammetry (LSV) respectively. The results showed that all the photoanodes produced exhibit conductivity and catalytic properties that make them attractive for water splitting application in a photoelectrochemical cell. In this context, the photoanode S2 exhibited better photocatalytic activity than the photoanode S1. In addition, photoanode S2 had the lowest optical band-gap energy value (2.58 eV), which would allow better utilization of the solar spectrum.

Growth and Characterization of AgGa$Se_2$ Single Crystal Thin Films by Hot Wall Epitaxy (Hot Wall Epitaxy (HWE)법에 의한 AgGa$Se_2$ 단결정 박막 성장과 특성)

  • Hong, Gwang-Jun;Lee, Gwan-Gyo;Park, Jin-Seong
    • Korean Journal of Materials Research
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    • v.11 no.5
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    • pp.419-426
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    • 2001
  • The stochiometric $AgGaSe_2$ polycrystalline mixture of evaporating materials for the $AgGaSe_2$ single crystal thin film was prepared from horizontal furnace. To obtain the single crystal thin films, $AgGaSe_2$ mixed crystal and semi-insulating GaAs(100) wafer were used as source material and substrate for the Hot Wall Epitaxy (HWE) system, respectively. The source and substrate temperature were fixed at$ 630^{\circ}C$ and $420^{\circ}C$, respectively. The thickness of grown single crystal thin films is 2.1$\mu\textrm{m}$. The single crystal thin films were investigated by photoluminescence and double crystal X-ray diffraction(DCXD) measurement. The carrier density and mobility of AgGaSe$_2$ single crystal thin films measured from Hall effect by van der Pauw method are $4.89\Times10^{17}$ cm$^{-3}$ , 129cm2/V.s at 293K, respectively. From the Photocurrent spectrum by illumination of perpendicular light on the c-axis of the AgGaSe$_2$ single crystal thin film, we have found that the values of spin orbit splitting $$\Delta$S_{o}$ and the crystal field splitting $\Delta$C$_{r}$, were 0.1762eV and 0.2474eV at 10K, respectively. From the photoluminescence measurement of AgGaSe$_2$ single crystal thin film, we observed free excision (EX) observable only in high quality crystal and neutral bound exciton ($D^{o}$ , X) having very strong peak intensity. And, the full width at half maximum and binding energy of neutral donor bound excition were 8mev and 14.1meV, respectively. By Haynes rule, an activation energy of impurity was 141 meV.ion energy of impurity was 141 meV.

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Study on energy of valence-band splitting from photocurrent spectrum of photoconductive $CdGa_2Se_4$ thin films

  • Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.66-66
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    • 2009
  • The photoconductive $CdGa_2Se_4$ layer was grown through the hot wall epitaxy method. From the photocurrent (PC) measurements, the three peaks in the PC spectra were associated with the band-to-band transitions. The PC intensities were observed to decrease with decreasing temperature. The valence-band splitting on $CdGa_2Se_4$ was also observed by means of the PC spectroscopy. The crystal field splitting and the spin orbit splitting turned out to be 0.1604 and 0.4179 eV at 10 K, respectively.

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MONTE CARLO SIMULATION OF COMPTONIZATION IN A SPHERICAL SHELL GEOMETRY

  • SEON KWANG IL;MIN KYOUNG WOOK;CHOI CHUL SUNG;NAM UK WON
    • Journal of The Korean Astronomical Society
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    • v.27 no.1
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    • pp.45-53
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    • 1994
  • We present the calculation of X -ray spectra produced through Compton scattering of soft X-rays by hot electrons in the spherical shell geometry, using fully relativistic Monte Carlo simulation. With this model, we show that the power-law component, which has been observed in the low luminosity state of low-mass X-ray binaries (LMXBs), is explained physically. From a spectral. analysis, we find that spectral hardness is mainly due to the relative contribution of scattered component. In addition, we see that Wi en spectral features appear when the plasma is optically thick, especially in the high energy range, $E{\gtrsim}100keV$. We suggest that after a number of scattering the escape probability approaches an asymptotic form depending on the geometry of the scattering medium rather than on the initial photon spectrum.

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An Antimicrobial Activity of a Peptidic Molecule from the Centipede, Scolopendra subspinipes mutilans L. Koch

  • Eun Jae Soon;Leem Jae-Yoon
    • Biomolecules & Therapeutics
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    • v.13 no.4
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    • pp.240-245
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    • 2005
  • An antimicrobial molecule was purified from centipede, Scolopendra subspinipes mutilans L. Koch, by reverse phase-HPLC. Its molecular weight was determined to be 1208.5493 by using matrix-assisted laser desorption ionization-time of flight (MALDI-TOF) mass spectrometry. Total amino acid composition analysis revealed that it consists of E, G, P, V, L, F, and W. It exhibited a broad antimicrobial spectrum against not only Gram-negative, but also Gram-positive bacteria. Furthermore, it was found to have an antimicrobial activity against vancomycin resistant enterococci (VRE). It may be a useful molecule for a new antibiotic development, especially against drug-resistant bacteria. We suggest that it may playa role in the defense system of this animal. This is the first report of a peptidic antimicrobial substance from centipede.

Implementation of fiber-optic temperature sensor system base on optical absorption device (광흡수 소자를 이용한 광온도 센서 시스템의 구현)

  • 김영수;김요희
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.9
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    • pp.128-134
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    • 1995
  • A fiber-optic temperature sensor utilizing an optical absorption device (InP) was fabricated. The spectrum of transmitted light through an InP device was obtained at the three temperatures(249 K, 369 K). A stabilized LED(light emmiting diode) driver, photoreceiver, and signal proocessing electronics were designed. An intensity referencing technique was adopted in order to minimize the fluctuation of output signal due to external pertubation of the transmitting optical fiber. The optical absorption edge of the InP device moves to longer wavelength at a rate of 0.42 nm / K, and energy gap of InP is 1.35 eV at room temperature. From these results, it is concluded that the InP device has temperature dynamic range of 300 K with LED of center wavelength of 940nm and spectral width of 50nm. The designed fiber-optic temperature sensor system showed good linearity within the temperature range from -30$^{\circ}C$ to + 150$^{\circ}C$.

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Physical Studies of Burnable Absorbers in Hexagonal Fuel Assembly

  • Kim, Taek-Kyum;Kim, Young-Jin;Chang, Moon-Hee
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11a
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    • pp.15-20
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    • 1996
  • We present the result of physical studies for three integral-type burnable absorbers of gadolinia, erbia and IFBA, in the hexagonal fuel assembly. The analysis of nuclear characteristics for gadolinia and IFBA cases shows that the spectrum hardening of hexagonal fuel assembly compared to rectangular one leads to smaller reactivity hold-down worth(RHW) and less change of MTC in the negative direction per insertion of one burnable absorber rod. Erbia case, on the other hand, exhibits reversed trend in RHW and MTC due to the enhanced absorption of large resonance of Erbium at 0.5 eV It turns out to be that Erbia performs best in terms of minimizing the peak pin power and maintaining as more negative MTC as practically attainable during the entire operational phase, and IFBA provides the least residual reactivity penalty at EOC. Therefore, we take Erbium as the suitable burnable absorber and provide optimal designs of 60, 120, 180, 240 and 300 erbia-shimmed hexagonal fuel assemblies with regard to minimizing the peak pin power.

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