• Title/Summary/Keyword: $UV/O_2$

Search Result 2,205, Processing Time 0.031 seconds

Effects of the Introduction of UV Irradiation and Rapid Thermal Annealing Process to Sol-Gel Method Derived Ferroelectric Sr0.9Bi2.1Ta1.8Nb0.2O9 Thin Films on Crystallization and Dielectric/Electrical Properties (UV 노광과 RTA 공정의 도입이 Sol-Gel 법으로 제조한 강유전성 Sr0.9Bi2.1Ta1.8Nb0.2O9 박막의 결정성 및 유전/전기적 특성에 미치는 영향)

  • 김영준;강동균;김병호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.1
    • /
    • pp.7-15
    • /
    • 2004
  • The ferroelectric SBT thin films as a material of capacitors for non-volatile FRAMs have some problems that its remanent polarization value is relatively low and the crystallization temperature is quite high abovc 80$0^{\circ}C$. Therefore, in this paper, SBTN solution with S $r_{0.9}$B $i_{2.1}$T $a_{1.8}$N $b_{0.2}$$O_{9}$ composition was synthesized by sol-gel method. Sr(O $C_2$ $H_{5}$)$_2$, Bi(TMHD)$_3$, Ta(O $C_2$ $H_{5}$)$_{5}$and Nb(O $C_2$ $H_{5}$)$_{5}$ were used as precursors, which were dissolved in 2-methoxyethanol. SBTN thin films with 200 nm thickness were deposited on Pt/Ti $O_2$/ $SiO_2$/Si substrates by spin-coating. UV-irradiation in a power of 200 W for 10 min and rapid thermal annealing in a 5-Torr-oxygen ambient at 76$0^{\circ}C$ for 60 sec were used to promote crystallization. The films were well crystallized and fine-grained after annealing at $650^{\circ}C$ in oxygen ambient. The electrical characteristics of 2Pr=11.94 $\mu$C/$\textrm{cm}^2$, Ps+/Pr+=0.54 at the applied voltage of 5 V were obtained for a 200-nm-thick SBTN films. This results show that 2Pr values of the UV irradiated and rapid thermal annealed SBTN thin films at the applied voltage of 5 V were about 57% higher than those of no additional processed SBTN thin films. thin films.lms.s.s.

Preparation of $TiO_2$ thin films by coating-pyrolysis process of Ti-naphthenate (Ti-naphthenate의 코팅-열분해에 의한$TiO_2$ 박막의 제조)

  • 김진영;김승원;장우석;김현태;최상원
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.12 no.1
    • /
    • pp.7-10
    • /
    • 2002
  • $TiO_2$ thin films were prepared by coating and subsequent pyrolysis processes using Titanium-naphthenate as a raw material. $TiO_2$ thin films were made by spin-coating technique on the glass substrates, and heat treated at 45$0^{\circ}C$, The transmittance, refractive index, crystallinity and surface morphology of the $TiO_2$ thin films were measured by UV/Vis spec trophotometer, x-ray diffractometer and scanning electron microscope. $TiO_2$thin films on the slide glass showed the trans mittance of 70-90% and refractive index of 2.6 at 420 nm. The results of XRD and SEM showed that the $TiO_2$ thin films exhibited the anatase phase and the thread-like surface morphology.

Investigation of the influence of substrate surface on the ZnO nanostructures growth (기판 표면의 영향에 의한 ZnO 나노 구조 성장에 관한 연구)

  • Ha, Seon-Yeo;Jung, Mi-Na;Park, Seung-Hwan;Yang, Min;Kim, Hong-Seung;Lee, Uk-Hyeon;Yao, Takafumi;Jang, Ji-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • v.9 no.1
    • /
    • pp.1022-1025
    • /
    • 2005
  • The effect of substrate surface to the formation of ZnO nanostructures has been investigated using Si (111), $Al_2O_3$(C-plane) $Al_2O_3$(A-plane), and $Al_2O_3$(R-plane) substrates. The growth temperature was controlled from 500$^{\circ}C$ ${\sim}$ 600$^{\circ}C$, and the luminescence properties were investigated by a series of photoluminescence (PL) measurements at the elevating temperatures. ZnO nanostructures grown on Si substrate show strong UV emission intensity along with green emission positioned at 3.22 eV and 2.5 eV, respectively. However, green emission was not observed from the ZnO nanostructures grown on $Al_2O_3$ substrates. It is explained in terms of the difference of the surface energy between Si and $Al_2O_3$. Also, the origin of UV emissions has been discussed by using the temperature-dependent PL. The distinction of the PL spectra is interpreted in terms of the difference of the impurity included in the nanostructures.

  • PDF

Photocatalytic Efficiency of $TiO_2$Thin Films by Spin-coating (Spin-coating법에 의한 $TiO_2$의 광촉매 효율)

  • Kim, Beom-Jun;Byeon, Dong-Jin;Lee, Jung-Gi;Park, Dal-Geun
    • Korean Journal of Materials Research
    • /
    • v.10 no.4
    • /
    • pp.264-269
    • /
    • 2000
  • TiO$_2$thin films were prepared on the glass by a conventional spin coating method with $TiO_2$ sol(30wt%, anatase). The thickness of the thin films were controlled by the number of coating cycles: one cycle is composed of spin coating, drying, and heating process. The reaction rate of the film was obtained by the photodecomposition of gaseous benzene under 0.44 and 2.0mW/$\textrm{cm}^2$ UV light on the film surface. For an incident UV light intensity of 0.44mW/$\textrm{cm}^2$, the reaction rate was increased with the thickness of the film, caused by extent of surface area, but there was no change over the thickness of about 4$\mu\textrm{m}$. The porous $TiO_2$ thin film has comparatively vast effective surface area, which under relatively high-intensity UV illumination causes the reaction rate to be controlled by the film thickness.

  • PDF

펜톤-유사 반응과 광-펜톤-유사 반응을 이용한 염료의 탈색 비교

  • Park, Yeong-Sik;Kim, Dong-Seok
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 2006.11a
    • /
    • pp.353-356
    • /
    • 2006
  • 펜톤-유사 반응의 최척 철 입자 양과 $H_2O_2$ 주입 량은 각각 25 g/L, 60 mmol로 나타났고, 광-펜톤-유사 반응의 최적 철 입자 양과 $H_2O_2$ 양은 각각 0.25 g/L 와 0.625 mmol로 나타나 철 입자 양은 100배, $H_2O_2$ 양은 96배 차이나 펜톤-유사 반응의 경우 다량의 철 입자와 $H_2O_2$ 소비로 인해 RhB의 탈색반응에는 적절하지 않은 것으로 나타났다. 그러나 UV를 함께 적용한 광-펜톤-유사 반응의 경우 철 입자 양과 $H_2O_2$ 양이 적어 적절한 것으로 사료되었다. RhB의 완전한 탈색을 위해서는 적절한 UV 등 전력이 필요하다고 사료되었다.

  • PDF

Development of the Functional Films Coated with Nano-TiO2 Particles for Food Packaging and Removal of Off-flavor from Soybean Sprouts (나노 TiO2를 적용한 식품 포장 필름 개발 및 콩나물의 이취 제거)

  • Choi, Yeonwook;Jeon, Kyu Bae;Song, Kihyeon;Kim, Jai Neung
    • Korean Journal of Food Science and Technology
    • /
    • v.47 no.6
    • /
    • pp.733-737
    • /
    • 2015
  • For testing the ultraviolet (UV)-blocking property of functional films coated with Nano-$TiO_2$ particles, UV-Vis spectra of oriented polypropylene (OPP) films uncoated and coated with $TiO_2$ of 3% and 5% in Polyurethane (PU) and polyvinyl butyral (PVB)-Cellulose binders were measured. The result of UV-Vis analyses showed that the film coated with 5% $TiO_2$ in PVB binders had a significant effect on UV protection of 90% compared with the film uncoated. Also The result of The photodegradation of methylene blue (MB), OPP films coated with 5% in both PU and PVB binders had a high photocatalytic activity for MB degradation. To evaluate the effect of the developed functional film coated with Nano-$TiO_2$ particles, fresh soybean sprouts were used. Nano-$TiO_2$ coated film was observed to decompose the off-flavor produced by soybean sprouts within packages during distribution, but uncoated film did not. Therefore, Nano-$TiO_2$ coated film package could give the greatest effect in extending the shelf life of soybean sprouts.

Thin film growth of ε-Ga2O3 and photo-electric properties of MSM UV photodetectors (ε-Ga2O3 박막 성장 및 MSM UV photodetector의 전기광학적 특성)

  • Park, Sang Hun;Lee, Han Sol;Ahn, Hyung Soo;Yang, Min
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.29 no.4
    • /
    • pp.179-186
    • /
    • 2019
  • In this study, we investigated the structural properties of $Ga_2O_3$ thin films and the photo-electrical properties of metal-semiconductor-metal (MSM) photodetectors deposited by Ti/Au electrodes. $Ga_2O_3$ thin films were grown at different temperatures using metal organic chemical vapor deposition (MOCVD). The crystal phase of $Ga_2O_3$ changed from ${\varepsilon}$-phase to ${\beta}$-phase depending on the growth temperature. The crystal structure of ${\varepsilon}-Ga_2O_3$ was confirmed by X-ray diffraction (XRD) analysis and the formation mechanism of crystal structure was discussed by scanning electron microscopy (SEM) images. From the results of current-voltage (I-V) and time-dependent photoresponse characteristics under the illumination of external lights, we confirmed that the MSM photodetector fabricated by ${\varepsilon}-Ga_2O_3$ showed much better photocurrent characteristics in the 266 nm UV range than in the visible range.

Synthesis of CaZrO3 : Eu3+ phosphor by skull melting method (스컬용융법에 의한 CaZrO3 : Eu3+ 형광체 합성)

  • Choi, Hyunmin;Kim, Youngchool;Seok, Jeongwon
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.30 no.4
    • /
    • pp.131-135
    • /
    • 2020
  • Single crystal phased CaZrO3 : Eu3+ phosphor have been synthesized by skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were investigated XRD (X-ray diffraction), SEM (scanning electron microscopy), UV (ultraviolet) fluorescence reaction and PL (photo luminescence). The starting materials having chemical composition of CaO: ZrO2 : Eu2O3= 0.962 : 1.013 : 0.025 mol% were charged into a cold crucible. The cold crucible was 120 mm in inner diameter and 150 mm in inner height, and 3 kg of mixed powder (CaO, ZrO2 and Eu2O3) was completely melted within 1 hour at an oscillation frequency of 3.4 MHz, maintained in the molten state for 2 hours, and finally air-cooled. The XRD results show that synthesized phosphor is stabilized in orthorhombic perovskite structure without any impurity phases. The synthesized phosphor could be excited by UV light (254 or 365 nm) and the emission spectra results indicated that bright red luminescence of CaZrO3 : Eu3+ due to magnetic dipole transition 5D07F2 at 615 nm was dominant.

Changes in Antioxidant and Nitrite Scavenging Activities of Angelica keiskei and Brassica loeracea var. acephala Vegetable Juices Treated with UV Irradiation during Storage (UV 조사한 신립초 및 케일 녹즙의 항산화 활성 및 아질산염 소거작용의 변화)

  • Choi, Goo-Hee;Kwon, Sang-Chul;Lee, Kyung-Haeng
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.39 no.8
    • /
    • pp.1187-1193
    • /
    • 2010
  • To elongate the shelf-life of Angelica keiskei and Brassica loeracea var. acephala vegetable juices, UV irradiation was used and the changes of antioxidant activity and nitrite scavenging ability were investigated. The content of polyphenols of vegetable juices were slightly reduced by UV treatment and/or storage period. The DPPH radical-scavenging activities of the vegetable juices treated by UV were higher than that of control but were not changed during storage. However, $ABTS{\cdot}^+$ reducing activities of the vegetable juices were reduced by UV treatment. The $ABTS{\cdot}^+$ reducing activity of Brassica loeracea var. acephala juice was lower when the flow rate was slower. The ferrous ion chelating effects of Angelica keiskei vegetable juices were reduced by UV treatment. In contrast, the ferrous ion chelating effects of Brassica loeracea var. acephala vegetable juices were not different from those of right after manufacturing. The ferrous ion chelating effects on both vegetable juices increased during storage periods. The inhibitory activity of lipid oxidation was decreased slightly by UV treatment on vegetable juices. The nitrite scavenging ability of Angelica keiskei and Brassica loeracea var. acephala vegetable juices treated by UV irradiation was not different from that of control. The nitrate scavenging abilities of vegetable juices in pH 1.2 were higher than those in pH 3.0 and 4.2.

UV/$TiO_2$공정을 이용한 수중 MTBE의 광촉매 분해

  • 김성수;류성필;오윤근
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 2003.11b
    • /
    • pp.41-44
    • /
    • 2003
  • UV/$TiO_2$ 공정을 이용한 수중 MTBE의 광분해에 관한 연구 결과 다음과 같은 결론을 얻을 수 있었다. MTBE는 초기농도가 낮을수록 제거효율이 증가하는 것을 볼 수 있었으며, 공기주입량이 4L/min인 경우 반응시간 160분 후 완전히 제거되었으며, 공기주입이 없는 경우에 비해 제거효율이 40%정도 높게 나타났다. 과산화수소 농도와 반응시간에 따른 MTBE 제거효율은 1M-$H_2O_2$ 300mL를 첨가한 경우 반응시간 160분 후에 완전히 제거되었으며, 1M-$H_2O_2$ 200m1는 반응시간 180분 후 거의 제거되었으며 $H_2O_2$를 첨가하지 않은 경우 반응시간 180분 후 68%의 제거효율을 보여 과산화수소 첨가시 제거효율이 증가하는 경향을 보였다.

  • PDF