• Title/Summary/Keyword: $Tm_2O_3$

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1.55 μm polarization mode splitter utilizing two mode interference of Ti:LiNbO3 optical waveguides (1.55 μm Ti:LiNbO3 광도파로의 두 모드 간섭을 이용한 편광모드 분리기)

  • 김정희;정기조;정홍식;이한영
    • Korean Journal of Optics and Photonics
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    • v.13 no.1
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    • pp.32-37
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    • 2002
  • Passive polarization mode splitters at λ= 1.55 ${\mu}{\textrm}{m}$ were designed and fabricated based on Ti:x-cut LiNbO$_3$ single-mode optical waveguide and two-mode interference theory. The splitting ratio with waveguide width 8 ${\mu}{\textrm}{m}$, branching angle 0.55$^{\circ}$ and interfering length 470 ${\mu}{\textrm}{m}$ showed 16.18 dB, 21.25 dB for TE and TM input polarization modes, respectively. Polarization cross-talk of -16.28 dB and -21.28 dB for TE and TM modes was achieved. Total insertion losses of 2.24 dB/cm (TE) and 2.41 dB/cm (TM) were also measured. The devices operated nearly wavelength independently over a range or 30 nm.

A Study on Electrooptic Guided-Wave TE-TM Mode Converter (전기광학효과를 이용한 광도파로형 TE-TM 모드 변환기에 관한 연구)

  • Hong Sik Jung
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.2
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    • pp.29-35
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    • 1993
  • A guided-wave TE to TM mode converter was demonstrated by using of the off-diagonal electrooptic coefficients in LiTaO$_{3}$. The input mode is coupled to the other orthogonal mode by the electrooptically induced off-diagonal polarizability. Compared with LiNbO$_{3}$, LiTaO$_{3}$ provides a smaller birefringence and thus a larger phase match period and larger optical bnadwidth. A novel electrode structure allowed a first-order Bragg-coupling phase matching. TE/TM mode conversion efficiency of 90% at 25 [V] was demonstrated with ${\lambda}$=0.63$\mu$m He-Ne laser.

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Effects of Additives on the Characteristics of Sodium Borosilicate Thin Film Fabricated by AFD Method (첨가제가 AFD법에 의해 제조된 광소자용 Sodium Borosilicate 박막의 물성에 미치는 영향)

  • Chung, Hyung-Gon;Chun, Young-Yun;Mun, Jong-Ha;Chung, Suck-Jong;Lee, Hyung-Jong
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.693-698
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    • 1998
  • The effects of $AI_{2}$$O_{3}$ and the ratio of $Na_2O/B_2O_3$ on the phase separation and optical properties of sodium borosilicate glass film fabricated by AFD(Aerosol Flame Deposition) were investigated. When AI,O, of 6wt% was added to $66SiO_2-27B_2O_3-7Na_2O$ the clear glass film without any crystallization was produced under air-quenching condition after consolidation. As the amount of $AI_{2}$$O_{3}$ increased from 1.5 to 6.0 wt% the refractive index linearly increased from 1.4610 to 1.4701, and the difference of TE and TM mode causing by residual stress in film increased gradually. However, the difference of TE and TM mode to reveal birefringence could be minimized by annealing below the glass transition temperature after consolidation and air quenching. On the other hand. as the ratio of $Na_2O/B_2O_3$ increased the refractive index and birefringence of glass film tended to increase, but the measurement of their values were not available at over the critical ratio of $Na_2O/B_2O_3$, because of the cloudiness due to crystallization. The phase separation was greatly accelerated with increasing the ratio of $Na_2O/B_2O_3$.

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Fluorine and Heavy Metal Oxide Effects on Spectral Properties of Tm3+ in Silicate Glasses

  • Cho, Doo-Hee;Seo, Hong-Seok;Park, Bong-Je;Park, Yong-Gyu
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.725-729
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    • 2003
  • The fluorine doping along with heavy metal oxides remarkably raised the $^3$H$_4$ lifetime and the quantum efficiency in Tm$^{3+}$-doped silicate glasses. 29 mol% of fluorine substitution for oxygen in 70SiO$_2$-15Pbo-12ZnO-3KO$_{1}$2/ glass raised $^3$H$_4$ lifetime to 193 $mutextrm{s}$. Refractive indices were raised by heavy metal oxide substitution, but hardly changed by fluorine substitution. The fluorine doping changed the local structure around Tm$^{3+}$ions, then low energy vibrations related to fluorine are considered to largely reduce the multi-phonon relaxation rates in the oxyfluoride silicate glasses. The $^3$H$_4$ lifetimes and absorption and emission spectra of Tm$^{3+}$doped silicate and oxyfluoride silicate glasses are reported, and Judd-Ofelt calculation results are discussed in this paper.

Solubility of Mixed Lanthanide Hydroxide and Oxide Solid Solutions

  • Moniruzzaman, Mohammad;Kobayashi, Taishi;Sasaki, Takayuki
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.3
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    • pp.353-366
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    • 2021
  • The solubilities of different multicomponent lanthanide oxide (Ln2O3) solid solutions including binary (Ln1 and Ln2 = La, Nd, Eu, or Tm), ternary (Ln1, Ln2, and Ln3 = La, Nd, Eu, or Tm), and higher systems (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were studied after aging for four weeks at 60℃. Our recent study revealed that the phase transformations in binary ((La, Nd) and (La, Eu)) and ternary (La, Nd, Eu) systems are responsible for the formation of (La, Nd)(OH)3, (La, Eu)(OH)3, and (La, Nd, Eu)(OH)3 solid solutions, respectively. The variations in the mole fractions of La3+, Nd3+, and Eu3+ in the sample solutions of these hydroxide solid solutions indicated that a thermodynamic equilibrium might account for the apparent La, Nd, and Eu solubilities. Conversely, the binary and ternary systems containing Tm2O3 as the heavy lanthanide oxide retained the oxide-based solid solutions, and their solubility behaviors were dominated by their congruent dissolutions. In the higher multicomponent system, the X-ray diffraction patterns of the solid phases, before and after contact with the aqueous phase indicated the formation of a stable oxide solid solution and their solubility behavior was explained by its congruent dissolution.

Photoluminescence properties and energy transfer of $Dy^{3+}$ and $Tm^{3+}$ co-activated $CaZrO_3$ phosphor for white LEDs

  • Li, Yezhou;Wang, Yuhua
    • Journal of Information Display
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    • v.12 no.2
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    • pp.93-96
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    • 2011
  • Single-phased $CaZrO_3:Dy^{3+}$, $Tm^{3+}$ series have been successfully synthesized by solid-state reaction, and their luminescence properties were investigated. Under 355 nm excitation, $CaZrO_3:Dy^{3+}$ series showed characteristic emission of $Dy^{3+}$, which exhibited yellowish white color. By introducing $Tm^{3+}$ into the matrix, the emitted hue of the $Dy^{3+}$-doped sample could be easily tailored to white, and simultaneously, energy transfer from $Tm^{3+}$ to $Dy^{3+}$ was observed. The color coordinates of the optimum white-emitting sample were (0.321, 0.323), which were very close to the data of the National Television Standard Committee (0.33, 0.33). The co-activated phosphors presented good match to ultraviolet light-emitting diodes (LEDs), which revealed that they could be novel promising phosphors utilized in white LED application.

Performance Evaluation of I/O Intensive Stress Test in Cluster File System SANiqueTM (집중적인 입출력 스트레스 테스트를 통한 클러스터 파일 시스템 SANiqueTM의 성능평가)

  • Lee, Kyu-Woong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.2
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    • pp.415-420
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    • 2010
  • This paper describes the design overview of shared file system $SANique^{TM}$ and analyzes the performance evaluation results of I/O intensive stress test based on various cluster file system architectures. Especially, we illustrate the performance analysis for the comparison results between the $SANique^{TM}$ and the Linux file system EXT3 system that is used to generally in Unix world. In order to perform our evaluation, Oracle 10g database system is operated on the top of cluster file system, and we developed the various kinds of testing tools which are compiled by ESQL/C from Oracle. Three types of architectures are used in this performance evaluation. Those are the cluster file system $SANique^{TM}$, EXT3 and the combined architecture of $SANique^{TM}$ and EXT3. In this paper, we present that the results of $SANique^{TM}$ outperforms other cluster file systems in the overhead for providing the true sharing over the connecting server nodes.

Nonstoichiometry of the Thulium Sesquioxide (산화툴륨의 비화학양론)

  • Chul Hyun Yo;Eun Seok Lee;Woong Bum Pyon;Jae Shi Choi;Moo Sil Pyon
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.25-30
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    • 1989
  • The nonstoichiometry and electrical conductivities of Tm$_2O_3$ were studied in the oxygen pressure $2\;{\times}\;10^{-1}\;-1\;{\tiems}\;10^{-4}$ atm under the temperature ranges from 700 to 1100$^{\circ}$C. The x values of $TmO_{1.5+X}$ were varied in the ranges of 0.1004∼0.0110. The enthalpies of formation of the nonstoichiometric compounds were found to be 5.40-4.71 kcal/mole, and the average activation energy obtained from the plots of log conductivity vs. 1000/T was 1.65 eV. The Po$_2$ dependencies of the electrical conductivity were found to be linear and closely approaximated to ${\sigma}{\alpha} PO{\frac{1}{2}^{/5.3}$ in the temperature range 700∼1100$^{\circ}$C. The nonstoichiometry and the electrical conductivity are due to trivalent metal vacancies.

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The application of multifunctional metal oxide for wastewater treatment: Adsorption and disinfection (다기능 금속산화물의 하수처리 적용-흡착 및 살균)

  • Kim, Heegon;Park, Duckshin;An, Byungryul
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.4
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    • pp.251-258
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    • 2019
  • The physical treatment such as chemical precipitation or adsorption was usually added after biological treatment in wastewater treatment process since it was enforced to reduce the concentration of phosphate for wastewater effluent to 0.2 mg/L as P which was well known as one of main nutrient causing eutrophication in waterbody. Therefore, the new material functioned for both adsorption and disinfection was prepared with Fe and Cu, and $TiO_2$, respectively, by changing the ratio of concentration referred to tri-metal (TM). According to SEM-EDS, $TiO_2$ was 30~40% composition for any TM regardless of any synthesis condition. However, the ratio of composition for Fe and Cu was dependent on the initial Fe and Cu concentration, respectively. The removal efficiency of phosphate was obtained to 15% at low initial concentration and the maximum uptake (Q) was calculated to ~11 mg/g through Langmuir isotherm model using TM1 which was synthesized at 1000 mg/L, 1000 mg/L, and 2 g (10 g/L) for $Fe(NO_3)_3$, $Cu(NO_3)_2$, $TiO_2$, respectively. In disinfection test, the efficiency of virus removal using TM was increased with increase of dosage of TM and can be reached 98% at 0.2 g.

Design of $Ti:LiNbO_3$ Three-Waveguide Optical Switch with Center-Waveguide Fed (가운데 도파로 입사된 $Ti:LiNbO_3$ 세 도파로 광스위치의 설계 및 제작)

  • Huh, Chang-Yul;Han, Young-Tak;Kim, Chang-Min
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.6
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    • pp.64-71
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    • 2000
  • An optical switch composed of identical, equally-spaced $Ti:LiNbO_3$ three-waveguides was designed and fabricated. Patterned Ti was diffused into z-cut $LiNbO_3$ substrates. $SiO_2$ buffer layer was evaporated to reduce the propagation loss of TM mode, and Al electrodes of CPW structure were built on the layer for switching of the guided beam. The optical switching phenomenon was confirmed when a beam of ${\lambda}=1.3{\mu}m$ was launched into the center waveguide and an electric field was applied to detune the three waveguides symmetrically.

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