• Title/Summary/Keyword: $SrTiO_2$

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Electrical Properties of $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\}Ti_{1.02}O_3$ for SMD-type Dielectric Trimmer Condenser (SMD-type Trimmer Condenser용 $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\}Ti_{1.02}O_3$)

  • Kang, D.H.;Cha, H.J.;Nam, K.C.;Hu, J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.597-600
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    • 2002
  • Electrical properties of $\{(Sr_xCa_{1-x})_{0.95-y-z}Bi_2Pb_{0.05+y}\})Ti_{1.02}O_3$ ceramic were studied as a function of Sr/Ca ratio and Bi, Pb contents. Dielectric properties of specimens with different x, y, z values were explained in terms of ionic polarizability with Molecular Additionally Rules and Clausius-Mosotti equation. For the composition of $\{(Sr_{0.62}Ca_{0.38})_{0.90}Bi_{0.01}Pb_{0.09}\})Ti_{1.02}O_3$ and $\{(Sr_{0.62}Ca_{0.38})_{0.905}Bi_{0.015}Pb_{0.08}\})Ti_{1.02}O_3$, dielectric constant$({\varepsilon}_r)$, quality factor(Q) and temperature coefficient(TC) were 389, 3048, -1490 and 394, 1869, -1340 at 1MHz, respectively.

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The study on Dielectric and Strain Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-SrTiO_3$ Ceramics. ($Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3-SrTiO_3$ 세라믹의 유전 및 변위 특성에 관한 연구(II))

  • Lee, H.Y.;Lee, J.;Jung, H.D.;Paek, Y.C.;Lee, H.K.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1466-1468
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    • 1994
  • In this paper Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics have been investigated as a function of the amount of $SrTiO_3(ST)$. The $SrTiO_3$ content is ranged from 0.01-0.06(wt%). As the amount of ST is increased, dielectric constant has a maximum value at 0.05 mol composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and ramnant polarization has a maximum value at 0.01mol composition.

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The study on Dielectric and Strain Properties of ((1-y-x)Pb(Mg$_{1}$3 Nb$_{2}$3/)O$_3$-yPbTiO$_3$-xSrTiO$_3$Ceramics ((1-y-x)Pb(Mg$_{1}$3 Nb$_{2}$3/)O$_3$-yPbTiO$_3$-xSrTiO$_3$세라믹의 유전 및 변위 특성에 관한 연구)

  • 이해영;이덕출;이능헌;김용혁
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.5-8
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    • 1994
  • In this paper, Dielectric and strain properties of (1-x-y)PMN-yPT-xST Ceramics hale been investigated as a function of the amount of SrTiO$_3$(ST). The SrTiO$_3$ content is ranged from 0.01-0.05(wt%). As the amount of ST is increased, dielectric constant has a maximun value at 0.05 mol% composition. The Curie temperature is decreased linearly with increasing ST composition and Polarization properties have been investigated. Coercive field and remnant polarization has a maximum value at 0.01mo1% composiion.

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Preparation of Bi$_4$Ti$_3$O$_{12}$ Films by Dipping-Pyrolysis Process (도포 열분해법을 이용한 Bi$_4$Ti$_3$O$_{12}$제조에 관한 연구)

  • 황규석;이형민;김병훈
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.1002-1005
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    • 1998
  • Bismuth titanate thin films were prepared on {{{{ { SrTiO}_{3 } }}(100) and Si(100) substrates by dipping-pyrolysis pro-cess using metal naphthenates as starting materials. crystallinity and in-phase alignment of the films were analyzed by X-ray diffraction $\theta$-2$\theta$ scans and $\beta$ scans (pole-figures) respectively. Highly c-axis-oriented {{{{ { { {Bi }_{4 }Ti }_{3 }O }_{12 } }} thin films with smooth surfaces were obtained after heat treatment at 75$0^{\circ}C$ on {{{{ { SrTiO}_{3 } }}(100) sub-strate while the films grown of Si(100) exhibited polycrstalline characteristics. C-axis oriented film show-ed an epitaxial relationship with the {{{{ { SrTiO}_{3 } }} substrate.

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Structural Properties of $MgTiO_3-SrTiO_3$ Geramics with Sintering Temperature (소결온도에 따른 $MgTiO_3-SrTiO_3$ 세라믹의 구조적 특성)

  • Choi, Eui-Sun;Lee, Moon-Kee;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.953-955
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    • 1999
  • The (1-x)$MgTiO_3-SrTiO_3$ (x=0. 0.1, 0.2, 0.3) ceramics were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature and composition ratio by XRD, SEM and BT-TGA. Increasing the sintering temperature from $1300^{\circ}C$ to $1600^{\circ}C$, second phase was decreased and grain size was increased. The average gram size of the 0.8$MgTiO_3-SrTiO_3$ ceramics sintered at $1600^{\circ}C$ were $3.61{\mu}m$.

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제일 원리 사용 Y-doped SrTiO3 연료극 특성 이해 및 3d 전위 금속 치환에 의한 표면 반응성 제어

  • Ham, Hyeong-Cheol;Kim, Hui-Su;Kim, Yong-Min;Yun, Chang-Won;Yun, Seong-Pil;Han, Jong-Hui;Nam, Seok-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.140-140
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    • 2012
  • 최근에 고체산화물 연료전지(SOFC) 연료극 조건에서 우수한 상 안정성, 높은 혼합 전자/이온 전도도 및 황/탄소 저항성 때문에 yttrium-doped strontium titanium oxide (Y-doped SrTiO3)가 대체 연료극 재료로 주목을 받아 왔다. 그러나 Y-doped SrTiO3는 연료 산화에 대해서 기존의 Ni 계열 연료극보다 낮은 전기화학적 활성을 보이는 단점이 있다. 따라서, 효율적인 Y-doped SrTiO3 계열의 연료극 재료를 개발하기 위해서는 Y-doped SrTiO3의 연료극 특성 및 반응성의 이해가 필수적이다. 본 발표에서는 SOFC 연료극에서 수소 산화 반응성을 결정함에 있어 표면 산소 vacancy 형성 에너지의 역할에 대한 spin-polarized DFT (density functional theory) 결과를 발표할 예정이다. 표면 산소 vacancy 형성 에너지는 수소 산화 반응[H2+O (surface) ${\rightarrow}$ OH+OH ${\rightarrow}$ H2O+O (vacancy)]과 밀접한 관계가 있다는 것을 확인하였다. 또한 Y-doped SrTiO3의 표면을 3d-전이금속을(Sc, V, Cr, Fe, Co, Mn, Ni, Cu) 도핑함으로써 표면 산소 vacancy 형성 에너지를 제어할 수 있다는 것을 보였다.

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Impedance-Based Characterization of 2-Dimenisonal Conduction Transports in the LaAlO3/SrxCa1-xTiO3/SrTiO3 systems

  • Choi, Yoo-Jin;Park, Da-Hee;Kim, Eui-Hyun;Park, Chan-Rok;Kwon, Kyeong-Woo;Moon, Seon-Young;Baek, Seung-Hyub;Kim, Jin-Sang;Hwang, Jinha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.171.2-171.2
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    • 2016
  • The 2-dimensiona electron gas (2DEG) layers have opened tremendous interests in the heterooxide interfaces formed between two insulating materials, especially between LaAlO3 and $SrTiO_3$. The 2DEG layers exhibit extremely high mobility and carrier concentrations along with metallic transport phenomena unlike the constituent oxide materials, i.e., $LaAlO_3$ and $SrTiO_3$. The current work inserted artificially the interfacial layer, $Sr_xCa_{1-x}TiO_3$ between $LaAlO_3$ and $SrTiO_3$, with the aim to controlling the 2-dimensional transports. The insertion of the additional materials affect significantly their corresponding electrical transports. Such features have been probed using DC and AC-based characterizations. In particular, impedance spectroscopy was employed as an AC-based characterization tool. Frequency-dependent impedance spectroscopy have been widely applied to a number of electroceramic materials, such as varistors, MLCCs, solid electrolytes, etc. Impedance spectroscopy provides powerful information on the materials system: i) the simultaneous measurement of conductivity and dielectric constants, ii) systematic identification of electrical origins among bulk-, grain boundary-, and electrode-based responses, and iii) the numerical estimation on the uniformity of the electrical origins. Impedance spectroscopy was applied to the $LaAlO_3/Sr_xCa_{1-x}TiO_3/SrTiO_3$ system, in order to understand the 2-dimensional transports in terms of the interfacial design concepts. The 2-dimensional conduction behavior system is analyzed with special emphasis on the underlying mechanisms. Such approach is discussed towards rational optimization of the 2-dimensional nanoelectronic devices.

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The Luminescent Properties of SrTiO$_3$ :Al, Pr Red Phosphor (Al과 Pr이 첨가된 SrTiO$_3$ 적색 형광체의 발광 특성)

  • 박정규;류호진;박희동;최승철
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.478-482
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    • 1999
  • SrTiO3 :Al, Pr phosphor as an oxide compound phosphor is expect to be applied for a field emission display(FED). In this phosphor the excitation spectrum shows a different tendency according to an addition Al3+ and Pr3+ In this excitation spectrum the main peak at 359 nm represent excitation level of Pr3+(1S0longrightarrow1D2 transition) and the absorption characteristic according to Ti/Sr molar ratio is influenced by the structure symmetry. The emission spectrum exhibits the red luminescence with the radiative decay of the 1D2 states(1D2 longrightarrow3H4 transition) The concentration quenching phenomena at 1D2 state shows up as Al3+ and Pr3+ ion concentration increases.

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