• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.609-612
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• 2007

The co-combustion of coal and RPF(Refuse Plastic Fuel) mixture has been experimented in a commercially operating CFB coal boiler and the emissions such as SOx, NOx, TSP and dioxine were measured at the stack. The experimented RPF was supplied by domestic RPF company that is commercially producing RPF pellet from the wasted plastics. Up to 15% of total coal was substituted to RPF and no trouble was happened during normal boiler operation. SOx and NOx concentration was reduced about $15{\sim}20$% and TSP(Total Suspended Particle) was drastically reduced about 30% during co-combustion. Dioxine concentration at mixing ratio of 7.5% was $0.0487ng{\sim}TEQ/Sm^3$ ($O_2$, 12%) that satisfied governmental emission regulation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 초전도 자성체
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• pp.29-33
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• 2002

종자결정성장법은 단결정형 YBCO 초전도체를 제조하기에 매우 유용한 방법이다. 이 방법은 YBCO 성형체 위에 Sm123나 Nd123 종자를 올려놓고 용융 열처리하여 초전도 결정을 특정한 방위로 성장하게 하는 방법이다. 그러나 이 공정의 단점은 초전도체의 결정성장속도가 매우 느리기 때문에 전체공정시간이 길다는 것이다. 이를 개선하고자 본 연구에서는 성형체 위에 같은 결정방위를 갖는 여러 개의 종자들을 동시에 올려 놓고 열처리하여 단결정형 초전도체의 제조시간을 단축하고자 하였다. 이 공정을 다중종자결정성법이라 명명하였으며, 이 공정의 적용으로 공정시간을 상당히 단축할 수 있음을 증명하였다. 본 연구에서는 초전도체의 결정 성장과정, 종자의 갯수와 공정시간의 관계, 종자에서 생성, 성장된 결정들이 만드는 결정입계특성 동에 대해 논의하였다.

• Journal of Microbiology and Biotechnology
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• 제20권5호
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• pp.871-874
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• 2010

Many studies require expression analysis of the same gene/promoter across a range of bacterial genera. However, there is currently a lack of availability of reporters based on the broad-host-range IncQ replicon, which is compatible with a popular improved IncP transfer system that is self-transfer defective. We report IncQ lacZ reporter plasmids with features including (1) compatibility with IncP, IncW, and pBHR/pBBR replicons, (2) a variety of antibiotic markers (Sp-r, Sm-r, Km-r, Cm-r), (3) convenient mobilization via a novel self-transfer-defective IncP conjugation system, and (4) GenBank DNA sequences. Utility is demonstrated using three different promoters in different Gram-negative genera.

• 한국가금학회지
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• 제19권4호
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• pp.177-185
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• 1992

본 연구는 대한양계협회에서 1985년부터 1991년까지 7회에 걸쳐 실시한 산난계 경제능력 검정성적을 기초로 하여 유색산난계의 연파난 발생비율과 다른 형질간의 년차별 평균능력의 변화와 연파난 발생비율이 다른 형질들에 의해 변화되는 정도를 추정하여 상관계수를 구하여 산난계의 연파난 발생비율을 감소시킬 수 있는 산란계 개량 방향과 사양관리조건 개선에 대한 기초 자료를 제시하기 위하여 실시한 것으로 그 결과를 요약하면 다음과 같다. 1. 유색산난계의 18∼72주령 초산일령은 163.6일, 산난율은 79.49％, 산난지수는 272.9개, 난중은 62.69g이었으며, 연파난 발생비율은 1.141％이었고 백색산난계는 18∼72주령에 각 형질의 평균능력이 각각 157.2일, 77.87％, 265.1개, 60.26g이었으며 연파난 발생비율은 1.174％이었다. 2. 유색산난계의 18∼72주령과 18∼78주령에 조사된 각 형질의 능력에 대한 유의성 검정결과 생존율, 초산일령, 산난율, 사료요구율, 체중 및 연파난 발생비율은 고도의 통계적 유의성(P＜0.01)이 인정되었다. 3. 유색산난계의 '85∼'91년 기간중 18∼72주령에는 초산일령은 168.5일에서 155.9일로 단축되었고 연파난 발생비율은 1.4∼l.69％에서 0.89∼0.94％로 감소하였으며, 18∼78주령에는 산난율은 74.5∼75.1％에서 77.8∼80.6％로 증가하였고, 산난지수는 302.0∼304.6개로 증가하였고, 연파난율은 1.54∼2.02％에서 0.98％ 내외로 감소하는 경향을 나타냈다. 4. 유색산난계에 대한 각 형질의 능력에 따른 21∼72주령의 연파난 발생비율과의 상관계수는 초산일령 0.3985, 난중 0.1072, 72주령 체중은 0.4225로 정의 상관을 나타냈으며, 산난율은 -0.5662, 산난지수는 -0.2896, 그리고 사료요구율과는 -0.245로 부의 상관을 나타냈다. 5. 유색산난계의 21∼78주령 각 형질의 능력에 따른 연파난 발생비율과의 상관계수는 초산 일령 0.3971, 난중 0.1171 그리고 78주령 체중은 0.4609의 정의 상관을 나타냈고, 산난율은 -0.5041, 산난지수는 -0.2372 그리고 사료요구율은 -0.2421로 부의 상관을 나타냈다.

• 방사성폐기물학회지
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• 제18권3호
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• pp.337-346
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• 2020

Two commonly used ceramics in molten salt research are alumina and mullite. The two ceramics were exposed to a combination of rare earth chlorides (YCl₃, SmCl₃, NdCl₃, PrCl₃, and CeCl₃; each rare earth chloride of 1.8 weight percent) in LiCl-KCl at 773 K for approximately 13 days. Scanning electron microscopy with wave dispersion spectra was utilized to investigate a formation layer or deposition of rare earths onto the ceramic. Only the major constituents of the ceramics (Al, Si, and O₂) were observed during the wave dispersion spectra. X-ray fluorescence was used as well to determine concentration changes in the molten salt as a function of ceramic exposure time. This study shows no evidence of ionic exchange or layer formation between the ceramics and molten chloride salt mixture. There are signs of surface tension effects of molten salt moving out of the tantalum crucible into secondary containment.

• Bulletin of the Korean Chemical Society
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• 제18권8호
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• pp.868-873
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• 1997

Nucleophilic substitution reactions of 1-phenylethyl chlorides (1-PEC; YC6H4CH(CH3)Cl) with phenoxides (XC6H4O-) and thiophenoxides (XC6H4S-) are investigated theoretically using the PM3 method. The Bronsted α and β values are greater for the phenoxides indicating a more advanced reaction in the transition state (TS) than for the thiophenoxides. This is supported by a greater magnitude of ρX (- 6.4 ∼ - 7.4) and ρXY (- 0.76) for the phenoxides than for the thiophenoxides (ρX = - 3.6 ∼ - 4.4 and ρXY = - 0.60). The percentage bond order changes, %Δn≠, suggest that the extents of bond making and breaking are similar for the phenoxides and hence the TS is symmetrical, but bond making is somewhat greater than bond cleavage for the thiophenoxides indicating an unsymmetrical TS. The reactions in the gas phase for both nucleophile series proceed by a SN2 mechanism with a tight TS and negative charge development on the reaction center carbon, Cα. The reactions in water investigated with model systems of benzyl and 1-phenylethyl chlorides using the Cramer-Truhlar solvation model (PM3-SM3) indicate that the reactions of 1-PEC are far more complex due to enhanced stabilization of the carbocation by the methyl substitution for a benzylic hydrogen.

• 자원환경지질
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• 제56권3호
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• pp.259-275
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• 2023

Pan African granitoids of Kaiama is comprised of K-feldspar rich granites, porphyritic granites, and granitic gneiss that are intruded by quartz veins and aplitic veins and dykes which trend NE-SW. In order to establish the geochemical signatures, petrogenesis, and tectonic settings of the lithological units, petrological, petrographical, and geochemical studies was carried out. Petrographic analysis reveals that the granitoids are dominantly composed of quartz, plagioclase feldspar, biotite, and k-feldspar with occasional muscovites, sericite, and opaque minerals that constitute very low proportion. Major, trace, and rare earth elements geochemical data reveal that the rocks have moderate to high silica (SiO₂=63-79.7%) and alumina (Al₂O₃=11.85-16.15) contents that correlate with the abundance of quartz, feldspars, and biotite. The rocks are calc-alkaline, peraluminous (ASI=1.0-<1.2), and S-type granitoids sourced by melting of pre-existing metasedimentary or sedimentary rocks containing Al, Na, and K oxides. They plot dominantly in the WPG and VAG fields suggesting emplacement in a post-collisional tectonic setting. On a multi-element variation diagram, the granitoids show depletion in Ba, K, P, Rb, and Ti while enrichment was observed for Th, U, Nd, Pb and Sm. Their rare-earth elements pattern is characterized by moderate fractionation ((La/Yb)_N=0.52-38.24) and pronounced negative Eu-anomaly (Eu/Eu^*=0.02-1.22) that points to the preservation of plagioclase from the source magma. Generally, the geochemical features of the granitoids show that they were derived by the partial melting of crustal rocks with some input from greywacke and pelitic materials in a typical post-collisional tectonic setting.

• 자원리싸이클링
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• 제13권2호
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• pp.9-15
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• 2004

석유화학공정으로부터 폐기되는 폐산화철촉매를 이용하여 도금합성폐수중 크롬회수에 관한 연구를 회분식과 연속식으로 실시하였다. 도금합성제수 중 $CrO _{4}^{-2}$ 형태의 음이온으로 존재하는 6가 크롬은 폐산화철촉매의 등전점(pH 3.0)이하에서 폐촉매와 물리적 흡착을 한다. 한편, 6가 크롬은 pH 3.0 이상에서도 폐촉매의 수산화철과 산화환원반응에 의해 일부 환원되어 $Cr(OH)_3$로 침전한다. 컬럼을 이용한 크롬 연속회수실험에서 크롬합성폐수의 pH가 0.5∼2.0일 때 폐촉매의 크롬흡착량은 2.0∼2.3g/L이며, pH가 3.0에서는 1.5g/L이었다. 폐수 중 크롬농도가 50∼500mg/L로 높아질수록 폐촉매에 흡착한 크롬누적량은 1.29∼8.56g/L로 증가하지만, 유속이 30∼80 ml/mm으로 증가하여도 크롬 흡착누적량은 2.21∼2.49 mg/L로 거의 유사하였다.

• 한국초전도ㆍ저온공학회논문지
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• 제8권2호
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• pp.11-16
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• 2006

Critical current densities were measured for a bicrystalline $(Sm_{0.8}Dy_{0.2})Ba_2Cu_3O_7$ film under various magnetic fields $({^{\rightarrow_{H}}}_a)$. The fields were varied from -0.7KOe to +0.7KOe for various orientations with respect to the film surface. The curves of the critical current densities $(J_{cb})\;vs\;{^{\rightarrow_{H}}}_a$ showed the well known butterfly-like hysteretic curves. Our data could be analyzed for the two components of field, which are normal and parallel to the film surface, respectively. We combined the effect of $H_\perp$ deduced from the data for the normal field $(\theta=90^{\circ})$ and the effect of $H_\parallel$ deduced from the data for the almost parallel field $(\theta=2^{\circ})$. Our analyses indicate that $(J_{cb})$ depends on the two components of flux density at the grain boundary. All the experimental data for various ${\theta}s$ fit well to this new formula which was obtained by multiplying the factors deduced from the field dependences of these two components.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.158-158
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• 2009

The electrophoretic deposition(EPD) technique with a wide range of novel applications in the processing of advanced ceramic materials and coatings, has recently gained increasing interest both in academic and industrial sector not only because of the high versatility of its use with different materials and their combinations but also because of its cost-effectiveness requiring simple apparatus. Compared to other advanced shaping techniques, the EPD process is very versatile since it can be modified easily for a specific application. For example, deposition can be made on flat, cylinderical or any other shaped substrate with only minor charge in electrode design and positioning[1]. The synthesis of the nano-sized Ce0.2Sm0.8O1.9(SDC)particles prepared by aurea based low temperature hydrothermal process was investigated in this study[2].When we made the SDC nanoparticles, changed the time of synthesis of the SDC. The SDC nanoparticles were characterized with field-emission scanning electron microscope(FESEM), energy dispersive X-ray analysis(EDX), and X-ray diffraction(XRD). And also we researched the results of our investigation on electrophoretic deposition(EPD) of the SDC particles from its suspension in acetone solution onto a non-conducting NiO-SDC substrate. In principle, it is possible to carry out electrophoretic deposition on non-conducting substrates. In this case, the EPD of SDC particles on a NiO-SDC substrate was made possible through the use of a adequately porous substrate. The continuous pores in the substrates, when saturated with the solvent, helped in establishing a "conductive path" between the electrode and the particles in suspension[3-4]. Deposition rate was found to increase its increasing deposition time and voltage. After annealing the samples $1400^{\circ}C$, we observed that deposited substrate.