• 한국전기전자재료학회논문지
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• 제21권11호
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• pp.1019-1023
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• 2008

Photoluminescence properties of $SrTiO_3$:Sm red phosphors synthesized by solid state reaction method were studied under 254 nm excitation. Emission bands at 576 nm and 616 nm in heavily $Sm^{3+}$ ion doped $SrTiO_3$:Sm phosphors were observed, which were attributed to $^4G_{5/2}\rightarrow{^6}H_{5/2}$ and $^4G_{5/2}\rightarrow{^6}H_{7/2}$ transition of $Sm^{3+}$, respectively. The $Sm^{3+}$ ion concentration exhibiting the maximum emission intensity in the $SrTiO_3$:Sm was 30 mol%. The luminescence caused by $Sm^{3+}$ in the $SrTiO_3$:Sm phosphors was interpreted by the energy transfer between $Sm^{3+}$ ions.

• E2M - 전기 전자와 첨단 소재
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• 제10권8호
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• pp.819-829
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• 1997

The microwave dielectric materials of the BaO-Nd$_2$O$_3$-TiO$_2$and BaO-(Sm, Nd)$_2$O$_3$-TiO$_2$system were synthesized by conventional ceramic processing and sintered 1220 to 140$0^{\circ}C$ for 2 hours respectively. Their crystallization and dielectric properties were examined. In the BaO-Nd$_2$O$_3$-TiO$_2$ and BaO-(Sm, Nd)$_2$O$_3$-TiO$_2$system. Nd$_2$Ti$_2$O$_{7}$ and (Sm, Nd)$_2$Ti$_2$O$_{7}$ were observed as a second phase respectively. The maximum relative dielectric constant were 79,99 for the BaO-Nd$_2$O$_3$-TiO$_2$system and 105.07 for the BaO-(Sm,Nd)$_2$O$_3$-TiO$_2$system and their Q-value were over 2000 at 3GHz.GHz.

• 한국결정성장학회지
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• 제14권2호
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• pp.68-72
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• 2004

Sm 원소가 첨가된 $(Sm/Y)_{1.8}Ba_{2.4}Cu_{3.4}O_{7-x}$[이하 (Sm/Y)1.8] 고온초전도체를 국부용융성장법을 이용해 대기 중에서 용융성장실험을 하였다. 초기 (Sm/Y)1.8 초전도체 시편은 rubber 몰드를 이용해 냉간정수압성형(CIP) 과정을 거쳐 길이 방향 원통형상으로 제조되었다. 이렇게 얻어진 (Sm/Y)1.8 초전도체는 용융온도 및 성장속도에 따라 광학현미경, TEM그리고 SQUID magnetometer를 이용해 미세구조 및 초전도특성을 평가하였다. 이 결과 (Sm/Y)1.8 초전도체의 최적의 용융온도 및 성장속도는 $1085^{\circ}C$에서 3.5mm/hr로 나타났다. 특히 일방향으로 용융성장된 (Sm/Y)1.8 초전도체의 광학현미경 및 TEM에 의하 미세구조 관측 결과, 초전도상인 (Sm/Y)123 matrix내에 비초전도상인 (Sm/Y)211 inclusions이 균질하게 분포되어 있는 것이 관측되었다. 초전도특성을 평가한 결과 용융성장된 (Sm/Y)1.8초전도체는 90K에서 임계온도가 시작되어 77K이상의 온도에서 포화되는 특성을 보였다.

• 한국재료학회지
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• 제11권1호
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• pp.39-43
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• 2001

Nanocrystalline Fe-Sm-O thin films were prepared by RF magnetron reactive sputtering method in $Ar+O_2$mixed atmosphere with the $O_2$content of 5%. The compositions of the thin films were changed by changing the number of $Sm_2O_3$ chips. The best soft magnetic properties of the thin film with the composition of $Fe_{83.4}Sm_{3.4}O_{13.2}$ were saturation flux density of 18 kG, coercivity of 0.82 Oe and effective permeability about 2,600 at 0.5~100 MHz, respectively. The electrical resistivity of Fe-Sm-O thin films was increased with increasing the amount of Sm and O elements which combined each other, the electrical resistivity of$Fe_{83.4}Sm_{3.4}O_{13.2}$ thin film was $130{\mu}{\Omega}cm$. In case of the small amount of Sm and O elements, the microstructures of Fe-Sm-O thin films showed a precipitated phase of $Sm_2O_3$ on the ${\alpha}-Fe$ phase. With the increase of the amount of Sm and O elements, the microstructures of the Fe- Sm-O thin films were changed into a mixed structure of ${\alpha}-Fe$ crystal-phase and Sm-oxide amorphous phase. The Fe-Sm-O thin films with Fe content in the range of 72~94 at% exhibited the quality factor (Q = $\mu$′/$\mu$") of 7~75 up to 50 MHz.

• Progress in Superconductivity
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• 제11권2호
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• pp.141-146
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• 2010

Phase stability diagram and boundary of a- and c-axis orientation of $SmBa_2Cu_3O_{7-y}$ (SmBCO) thin films grown by pulsed laser deposition (PLD) were reported with studies based on x-ray diffraction [1]. Four different samples are systematically analyzed: normal c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$, a-axis oriented $SmBa_2Cu_3O_{7-y}$, c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ with $Sm_2BaCuO_5$ phase, and a mixture with c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ and anomalously long-c tetragonal $SmBa_2Cu_3O_x$. Raman scattering spectroscopy equipped with polarization analysis elucidates the crystal orientation and the origin of the growth of the materials. It indicates that the technique can be used for quality control of conductor manufacturing processes as well as for enhancement of the materials properties.

• Transactions on Electrical and Electronic Materials
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• 제5권2호
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• pp.81-85
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• 2004

High T$\_$c/ (Sm/Y)$\_$1.8/Ba$\_$2.4/Cu$\_$3.4/O$\_$7-$\delta$/ ［(Sm/Y)］ superconductor, a combination of Y and Sm(50% each), was systematically investigated by the zone melt growth process. A sample prepared by this method showed well-textured microstructure, and (Sm/Y)$_2$BaCuO$\_$5/［(Sm/Y)211］inclusions were uniformly dispersed in large (Sm/Y)Ba$_2$Cu$_3$O$\_$y/ ［(Sm/Y)123］matrix. The sample showed a sharp superconducting transition at 91 K. The magnetization measurements of the (Sm/Y)1.8 sample exhibited the enhanced flux pinning, compared with Y$\_$1.8/Ba$\_$2.4/Cu$\_$3.4/O$\_$7-$\delta$/(Y1.8) sample without Sm. Critical current densities of (Sm/Y) 1.8 sample was 3.5${\times}$10$^4$A/$\textrm{cm}^2$ at 1 T and 77 K.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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• pp.94-97
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• 2002

Phase transitions of the $Sm_{2}(MoO_{4})_{3}$ single crystal were studied through thermal analysis, x-ray methods and SEM/EDS. $Sm_{2}(MoO_{4})_{3}$ undergoes the ferroelastic and ferroelectric phase transition at $198^{\circ}C$. With increasing temperature, the second phase transition occurs at $928^{\circ}C$. From TG analysis, the mass loss of $Sm_{2}(MoO_{4})_{3}$ exhibits an anomalous behavior at about $650^{\circ}C$ and the curves increased monotonically to $1132^{\circ}C$. SEM and EDS show that the escape of ${MoO_{4}^{2-}$ tetrahedra from the lattice of $Sm_{2}(MoO_{4})_{3}$ increase above $928^{\circ}C$, so $Sm_{2}(MoO_{4})_{3}$ has a very rough surface and internal cracks.

• 한국전기전자재료학회논문지
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• 제15권3호
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• pp.269-274
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• 2002

(Sm/Y)-Ba-Cu-O system high Tc composite superconductors with/without $CeO_2$ additive were directionally grown by zone-melting process, haying large temperature gradient, In air atmosphere. Cylindrical green rods of $({Sm/y})_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(Sm/Y)1.8] composite oxides by cold isostatic pressing(CIP) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, SEM, TEM and SQUID magnetometer. The size of nonsuperconducting $({Sm/y})_2BaCuO_5$ inclusions of the melt-textured (Sm/Y)1.8 sample with CeO$_2$ additive were remarkably reduced and uniformly distributed within the superconducting (Sm/Y)1.8 matrix. Both samples, with/without $CeO_2$ additive, showed an onset Tc $\geq$ 90 K and sharp superconducting transition. The critical current density Jc value of the $CeO_2$ addictive were $1{\times}10^5A/\textrm{cm}^2$ in 77 K, 0 Tesla.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.164-164
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• 2013

최근에 희토류 이온이 치환 고용된 실리케이트계 형광체를 발광 소자, 레이저, 광전 소자에 응용하기 위한 연구에 많은 관심이 집중되고 있다. 본 연구에서는 고상 반응법을 사용하여 초기 물질 CaO (99.99% 순도), SiO2 (99.99%), RE2O3 (RE=Sm3+, Tb3+, 99.9%)을 화학 적량으로 준비하여 활성제 이온 Sm3+과 Tb3+이온의 함량비를 0, 0.01, 0.05, 0.10, 0.20 mol로 변화시켜 Ca2SiO4:RE3+ 형광체를 제조하여 그것의 발광과 흡광 특성을 조사하였다. Sm3+ 이온이 도핑된 Ca2SiO4 형광체의 경우에, 발광 스펙트럼은 Sm3+ 이온의 함량비에 관계없이 모든 시료에서 602 nm에 피크를 갖는 강한 주황색 발광 스펙트럼, 상대적으로 발광 세기가 약한 569 nm에 정점을 갖는 황색 발광과, 652 nm와 711 nm에 피크를 갖는 적색 발광 스펙트럼이 관측되었다. Sm3+ 이온의 함량비가 0.01 mol 일 때 세 영역의 발광 스펙트럼의 세기는 최대값을 나타내었다. Sm3+ 이온의 함량비가 증가함에 따라 모든 발광 스펙트럼의 세기는 순차적으로 감소하였다. 이 현상은 농도 소광 현상에 기인함을 알 수 있었다. Sm3+ 이온이 도핑된 형광체 분말의 경우에, 주 흡광 스펙트럼은 Sm3+ 이온의 함량비에 관계없이 408 nm에서 관측되었으며, 이밖에도 상대적으로 흡광 세기가 약한 349 nm, 367 nm, 476 nm에서 흡광이 발생하였다.

• 한국재료학회지
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• 제22권4호
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• pp.207-210
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• 2012

The preparation of $Sm_2O_3$ doped $CeO_2$ in Igepal CO-520/cyclohexane reverse micelle solutions has been studied. In the present work, we synthesized nanosized $Sm_2O_3$ doped $CeO_2$ powders by reverse micelle process using aqueous ammonia as the precipitant; hydroxide precursor was obtained from nitrate solutions dispersed in the nanosized aqueous domains of a micro emulsion consisting of cyclohexane as the oil phase, and poly (xoyethylene) nonylphenylether (Igepal CO-520) as the non-ionic surfactant. The synthesized and calcined powders were characterized by Thermogravimetry-differential thermal analysis (TGA-DTA), X-ray diffraction analysis (XRD), and Transmission electron microscopy (TEM). The crystallite size was found to increase with increase in water to surfactant (R) molar ratio. Average particle size and distribution of the synthesized $Sm_2O_3$ doped $CeO_2$ were below 10 nm and narrow, respectively. TG-DTA analysis shows that phase of $Sm_2O_3$ doped $CeO_2$ nanoparticles changed from monoclinic to tetragonal at approximately $560^{\circ}C$. The phase of the synthesized $Sm_2O_3$ doped $CeO_2$ with heating to $600^{\circ}C$ for 30 min was tetragonal $CeO_2$. This study revealed that the particle formation process in reverse micelles is based on a two step model. The rapid first step is the complete reduction of the metal to the zero valence state. The second step is growth, via reagent exchanges between micelles through the inter-micellar exchange.