• 한국세라믹학회지
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• 제31권3호
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• pp.330-336
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• 1994

High strength cement composites (W/C=0.1) were prepared by using various blending materials such as SiC whisker and white carbon (hydrated silica: SiO2·nH2O). The effect of various blending materials on the microstructure and strength of the hardened cement paste were investigated in the view of fracture mechanics. The plain specimen showed 101 MPa of flexural strength, 81 GPa of Young's modulus and 1.32 MPam1/2 of fracture toughness. When the blending materials were added to the composites, their values were enhanced to about 110∼138 MPa, 95∼146 GPa and 1.32∼1.87MPam1/2 respectively. The improvement of the mechanical strength for the hardened cement paste may be due to the removal of macropores, the reduction of total porosity, pozzolanic reaction and the increase of various fracture toughening effect.

• E2M - 전기 전자와 첨단 소재
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• 제6권4호
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• pp.311-317
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• 1993

발열체 소자에 있어서 발열체의 방사스펙트럼과 피가열체의 흡수스펙트럼을 일치시키는 문제는 효과적인 가열을 위하여 매우 중요한 연구과제이다. 본 연구는 재료의 합성기술과 열처리기술을 이용하여 PTC 서머스터의 R-T특성은 그대로 유지시키면서 원적외선 방사특성을 증대시키기 위한 것이다. 이를 위하여 BaTiO$_{3}$+1.67Al$_{2}$O$_{3}$+3.75SiO$_{2}$+1.25TiO$_{2}$을 기본조성으로 하고 여기에 첨가제로서 Sb$_{2}$O$_{3}$와 MnO$_{2}$를 선정하여 이의 첨가량과 소결온도 그리고 소결온도구배를 파라메터로한 시편을 제작하였으며 각 시편의 IR특성과 R-T특성등을 측정 검토한 결과 파장 4.5-14.5[.mu.m]범위에서 방사율 0.8이상의 고효율 원적외선 방사특성을 얻었다.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2005년도 동계학술연구발표회 및 2차 아시안포럼
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• pp.141-141
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• 2005

• E2M - 전기 전자와 첨단 소재
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• 제7권4호
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• pp.306-311
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• 1994

In this study, the influence of the powder sintering, the 2nd sinteiing and the grinding time on the Superconducting properties in the Bi(Pb)SiCaCuO Superconductor has been studied. From the analysis of SEM and XRD patterns, it was known that the sample prepared by the process of powder sintering has a porous microstructure with the critical temperature(Tc) below 77K, while the sample prepared by the 2nd sintering has a highly oriented microstructure with the Tc above 100K. The Critical Current Density(Jc) of the sample prepared by the 2nd sintering was better than the sample prepared by the process of powder sinteiing, but it's Jc, was low in practical use. Also, the effect of grinding time from 0[min] to 120[min] was investigated. As the grinding time is increased, the samples degraded from high-Tc phase to low-Tc phase and nonsuperconducting phases.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.157-160
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• 2001

Three sets of ZnO ceramic devices (reference samples with Matsuoka\`s composition; added 7o MgO, A1$_2$O$_3$, SiO$_2$) have been prepared by the conventional mixed oxide route. These additives were determined by the factors of valences and ionic radiuses. DC accelerated degradation test was performed for analysis of degradation characteristics versus the various additives. The conditions of DC degradation test were 115${\pm}$2$^{\circ}C$ for 12h. Using XRD and SEM, the Phase and microstructure of samples were analyzed respectively. E-J analysis was used to determine ${\alpha}$. Frequency analysis was accomplished to understand the relationship between R$\sub$g/ and $R_{b}$ with the electric stress at the equivalent circuit.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2009년도 춘계학술대회 논문집
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• pp.192-193
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• 2009

CrN 코팅막은 고온에서 치밀한 Cr2O3 확산방지막을 형성함으로 $800^{\circ}C$까지 기계적성질을 유지할 수 있다. 본 실험에서는 Ar, N2, 그리고 $O_2$ 가스 분위기에서 AIP(Arc Ion Plating) 기법에 의해 다양한 조성의 Cr-O-N 박막을 Si(200)과 AISI 304 기판 위에 증착되었다. Cr-O-N 코팅막은 47.4at% 미만의 산소함량을 포함 할 때까지 B1구조를 유지하였고 코팅막 내 산소함량 24.6at%에서는 강한 XRD peak intensification을 나타내었다. 47.4at%에서는 결정상을 전혀 찾아볼 수 없는 전이구조를 나타내었고, 그 이상의 산소함량에서는 Cr22O3 결정상을 나타내었다. Cr-O(17at%)-N 조성의 코팅막에서는 (200)배향의 Grain 크기 증가 및 압축잔류응력이 증가하였으나, 그 이상의 산소함량에서는 점차 감소하였다. Cr-O(24.6at%)-N 조성의 코팅막이 가장 높은 경도를 나타내었고, 산소함량이 증가할수록 점차 향상된 마찰특성을 보였다.

• 대한금속재료학회지
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• 제50권8호
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• pp.575-582
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• 2012

Medium carbon steel was aluminized by hot dipping into molten Al or Al-1 at% Si baths. After hot-dipping in these baths, a thin Al-rich topcoat and a thick alloy layer rich in $Al_5Fe_2$ formed on the surface. A small amount of FeAl and $Al_3Fe$ was incorporated in the alloy layer. Silicon from the Al-1 at% Si bath was uniformly distributed throughout the entire coating. The hot dipping increased the microhardness of the steel by about 8 times. Heating at $700-1000^{\circ}C$, however, decreased the microhardness through interdiffusion between the coating and the substrate. The oxidation at $700-1000^{\circ}C$ in air formed a thin protective ${\alpha}-Al_2O_3$ layer, which provided good oxidation resistance. Silicon was oxidized to amorphous silica, exhibiting a glassy oxide surface.

• Carbon letters
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• 제6권2호
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• pp.71-78
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• 2005

Anti-oxidation coatings are the key technique for carbon/carbon (C/C) composites used as the thermal structural materials. The microstructure and oxidation behavior of several kinds of high-performance ceramic coatings for C/C composites prepared in Northwestern Polytechnical University were introduced in this paper. It showed that the ceramic coatings such as SiC, Si-$MoSi_2$, SiC-$MoSi_2$, $Al_2O_3$-mullite-SiC and SiC/yttrium silicate/glass coatings possessed excellent oxidation resistance at high temperatures, and some of these coatings were characterized with excellent thermal shock resistance. The SiC-$MoSi_2$ coating system has the best oxidation protective property, which can effectively protect C/C composites from oxidation up to 1973 K. In addition, the protection and failure reasons of some coatings at high temperature were also provided.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.39-40
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• 2006

The relationship between the powder particle size change and a mechanical property of the Metal Injection Molding (MIM) product was examined in detail. The XRD results indicate that the diffraction peaks of BCC appeared in compacts of powder particle size of 4 to $10{\mu}m$ as well as the bulk SUS630. However, the diffraction peaks from both BCC and FCC were observed in the compact with powder size less than $3{\mu}m$. TEM observation revealed that the powder with those BCC/FCC two phase structure have a finely dispersed $SiO_2$ precipitates. Because the Si is ferrite stabilizing element, decrease of Si composition in the matrix phase by the $SiO_2$ precipitation resulted in formation of the retained austenite. Therefore, controlling the elements such as Si as well as oxygen decrease is very important to obtain a normal microstructure in ultra-fine powder $(<3{\mu}m)$ injection molding.

• 한국표면공학회지
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• 제55권3호
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• pp.143-155
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• 2022

Ceramic oxide layers successfully were formed on the surface of cast Al alloys with high Si contents using plasma electrolytic oxidation (PEO) process in electrolytes containing Na₂SiO₃, NaOH, and additives. The microstructure of the oxide layers was systematically analyzed using scanning electron microscopy (SEM), cross-sectional transmission electron microscopy (TEM), X-ray diffraction patterns (XRD), and energy X-ray dispersive spectroscopy (EDS). XRD analysis indicated that the PEO untreated high-silicon Al alloys (i.e., 17.1 and 11.7 wt.% Si) consist of Al, Si and Al₂Cu phases whereas Al₂Cu phase selectively disappeared after PEO treatment. PEO process yielded an amorphous oxide layer with few second phases including γ-Al₂O₃ and Fe-rich phases. The corrosion behaviors of high-silicon Al alloys treated by PEO process were investigated using electrochemical impedance spectroscopy (EIS) and other electrochemical techniques (i.e., open circuit potential and polarization curve). Electroanalytical studies indicated that high-silicon Al alloys treated by PEO process have greater corrosion resistance than high-silicon alloys untreated by PEO process.