• Title/Summary/Keyword: $Sb_2S_3$

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M-Zn (M = Sb, V, and Nb) Substituted Strontium Hexaferrites with Enhanced Saturation Magnetization for Permanent Magnet Applications

  • Sapoletova, Nina;Kushnir, Sergey;Ahn, Kyunghan;An, Sung Yong;Choi, Moonhee;Kim, Jae Yeong;Choi, Changhak;Wi, Sungkwon
    • Journal of Magnetics
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    • v.21 no.3
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    • pp.315-321
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    • 2016
  • M-Zn (M = Sb, V, Nb) substituted M-type strontium hexaferrites were prepared by a ceramic method. The phase composition, morphology and magnetic properties were studied by x-ray diffractometry, scanning electron microscopy and vibrating sample magnetometry. Saturation magnetization increases with a substitution up to 75.0 emu/g (2.5 % higher compared to unsubstituted hexaferrite) and then decreases with a further substitution. A coercive field of substituted hexaferrite powders with highest saturation magnetization is more than 3 kOe. Substituted strontium hexaferrite powders prepared in this work are a rare example of high $M_S$ compositions without doping rare-earth elements and would be a promising candidate for a permanent magnet application.

Consolidation of Thermal Electric Material Powder by MPC Process and Thermal Electric Properties (MPC 공정에 의한 열전반도체 분말의 성형 및 열전특성)

  • Yun, J.S.;Koo, J.M.;Kim, T.S.;Hong, S.J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.454-456
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    • 2009
  • N-Type $SbI_3$ doped $95%Bi_2Te_3+5%\;Bi_2Se_3$ compounds were newly fabricated by the combination of gas atomization process and Magnetic Pulsed Compaction process. The thermoelectric properties of the MPCed bulks according to consolidation temperatures were investigated by a combination of microscopy, XRD and thermoelectric property testing. The microstructure of MPCed bulk shows homogeneous and fine distribution through consolidated bulks due to the high solidification of compound powders. The research presented the challenges toward the successful consolidation of thermoelectric powder using magnetic pulsed compaction (MPC) and analysis of thermoelectric properties of the consolidated bulks.

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1차원 무기 반도체 신 물질 재료의 연구 개발 동향

  • Ryu, Hak-Gi
    • Ceramist
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    • v.21 no.2
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    • pp.29-37
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    • 2018
  • In order to overcome the problems of existing low-dimensional materials (carbon nanotubes, graphene, transition metal dichalcogenides, etc) researches on new 1D materials have been studied. In the case of $LiMo_3Se_3$ and $Mo_6S_{9-x}I_x$, continuous researches have been carried out for 3D bulk synthesis and atomic scale dispersion. Recently, quantum confinement effect of $LiMo_3Se_3$ and bio-stability of $Mo_6S_{9-x}I_x$ have been proven and various applications have started to be studied. In addition, device application results using new 1D materials such as $Sb_2Se_3$ (optoelectronic devices using the property of effectively reducing exciton decay due to no dangling bond) and $VS_4$ (electrochemical energy storage using the space between 1-D nanostructures) have been reported very importantly. Therefore, it can be claimed that it has reached a very important time to find and synthesize new 1D materials and to report various characteristics not existing.

The Effect of Metallic Oxides on the Formation Rates and Rigidities of the Elastic Sodium Alginate-$CaSO_4{\cdot}1/2H_2O$ Gel. (Sodium Alginate-$CaSO_4{\cdot}1/2H_2O$ 彈性體의 生成速度 및 彈性에 미치는 金屬酸化物의 影響)

  • Shin, Hong-Dae;Huh, Yeonn;Kim, Uun-Sik
    • Journal of the Korean Chemical Society
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    • v.9 no.1
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    • pp.16-22
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    • 1965
  • The time-lag-effect of alkali salts on the gelation of sodium alginate-$CaSO_4{\cdot}$1/2 $H_2O$ is compared with Miyake's data, and then the formation rate of the elastics measured by the continuous method (an improved Schwedoff's method) and the change of rigidity with metallic oxides are studied as follows: (1) The gelation processes of sodium alginate and $CaSO_4{\cdot}$1/2 $H_2O$-aqueous sol are studied by measuring, continuously the increases of tensions ofsamples. (2) The time-lag-effect of $Na_3PO_4$ on the formation rate of the elastic gel is larger than that of $Na_2CO_3$, but the difference between the effects of the two alkali salts on the rate is found not so greater than predicted in Miyake's data. (3) Any regularities of the effect on the rate by metallic oxides are not observed. The increasing effects of the rates of $SiO_2$ and MgO are relatively large, and that of ZnO is relatively small. However, $Al_2O_3$, $Sb_2O_3$ and $TiO_2$show some decreasing effects. As a result it is noted that the regularities do not depend on the effect of oxide species and their amounts. (4) It is not found proportionality between the rigidity and the gelation rate. However, the increasing effect of the rigidity with the addition of metallic oxides can be observed. The rigidity increasing rate of MgO is the largest of them.

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Effects of Cervi cornu parvum and Soahbohyul - tang combined with Cervi cornu parvum on LPS-induced fever pattern differences in rabbits, and learning and memory in rats (발열 상태에서 투여된 녹용(鹿茸)과 소아보혈탕(小兒補血湯) 가(加) 녹용(鹿茸)이 발열 양상의 변화 및 학습과 기억에 미치는 영향)

  • Choi Hyuk-Yong;Lee Jin-Yong;Kim Deok-Gon
    • The Journal of Pediatrics of Korean Medicine
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    • v.14 no.1
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    • pp.9-38
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    • 2000
  • It has been widely said in Korea that early administrations of Cervi cornu parvum (deer antler) to febrile infants affect brain functions. Traditional Oriental Medicine states that the head is easily affected by fever and only an excess of heat causes headaches. Traditional Oriental Medicine also states that Cervi cornu parvum cannot be used in febrile conditions. With the aim of investigating different febrile response to LPS, experiments using intravenous injection of LPS have been carried out on Cervi comu parvum(CCP) and Soahbohyul - tang combined with Cervi comu parvum(SB-CCP) administered rabbits. Experiments were also conducted to evaluate the effects of early administration of CCP on learning and memory in 3 week old rats with LPS fever. These were evaluated by using the Morris water maze and the radial arm maze. Changes in body weight were also observed during this period. The results of these experiments are as follows. 1. In the experiments with febrile rabbits, the CCP and SB-CCP administered group showed statistically significant reductions of fever (p<0.05). 2. In the experiments with febrile rabbits, CCP and SB-CCP administered rabbits resulted in the tendency of lower body temperatures and shorter fever periods than the control group. 3. There were no differences of mean body weight and fever patterns among the 4 groups in the experiments on young rats with LPS fever. 4. There was no statistical difference of mean response latencies among the rats in Group I (DDW administered), GroupIII (CCP administered), and groupIV (SB-CCP administered) in the Morris water maze. However, Group Ⅱ (the scopolamine administered group) showed delayed latencies on the second day of the first session (p<0.05), and the second and third day of the second session (p< 0.05). 5. There were no statistical differences of mean response latencies among the rats in Group I, III and Ⅳ in the radial arm maze, but Group Ⅱ showed delayed latencies on the first and third day of the first session (p<0.05). 6. There was no influence from the administration of CCP and SB-CCP on the general behavior of the rats in Irwin´s test. These results suggest that Cervi cornu parvum and Soahbohyul - tang combined with Cervi comu parvum have anti-pyretic actions on LPS fever. The results also suggest that these drugs have no influence on learning and memory in young rats with LPS fever in the Morris water maze and the radial arm maze.

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The Analgesic Effect and Its Mechanism of Electroacupuncture in the Type II Collagen-induced Arthritis Rats : Mediation by Serotonergic Receptors (전침자극(電鍼刺戟)의 Collagen 유발 관절염(關節炎) 동물(動物)모델에 대한 진통효과(鎭痛效果) 및 기전(機轉)에 관한 연구(硏究) -Serotonergic Mechanism을 중심으로-)

  • Ryu, Seong-Ryong;Baek, Yong-Hyeon;Park, Dong-Suk
    • Journal of Acupuncture Research
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    • v.23 no.3
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    • pp.77-90
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    • 2006
  • Objectives : To evaluate the analgesic effect of electroacupuncture on Choksamni (ST36) in the collagen-induced arthritis rats and investigate the role played by serotonergic receptor subtypes $(5-HT_{1A},\;5-HT_{1B},\;5-HT_4)$ in the antinociceptive effect of electroacupuncture in the thermal hyperalgesia test. Methods : Immunization of male Sprague-Dawley rats with bovine type II collagen emulsified in incomplete Freund's adjuvant, followed by booster injection 14 days later induced collagen-induced arthritis (CIA). The thermal hyperalgesia was evaluated weekly with tail flick latency (TFL). In the fourth week after first immunization. EA stimulation (2Hz, 0.07mA, 0.3ms) was delivered into Choksamni for 20 minutes. We measured the analgesic effect of EA with TFL afer intraperitoneal injection of normal saline, WAYl00635, SB216641 and GR125487. Results : TFLs were gradually decreased in CIA as time elapsed after the immunization of arthrogenic collagen and the maximum value was reached from third to fifth week. EA stimulation on ST36 inhibited chronic inflammatory pain induced by CIA. The analgesic effect of EA was inhibited by pretreatment of $5-HT_{1A}$. antagonist (WAYl00635), $5-HT_{1B}$ antagonist (SB216641) and $5-HT_4$ antagonist (GR125487). Conclusion : Electroacupuncture has the analgesic effect on chronic inflammatory pain and its mechanism was mediated by $5-HT_{1A}$, $5-HT_{1B}$ and $5-HT_4$.

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Realization of p-type Conduction in Antimony Doped ZnO Thin Films by PLD (PLD를 이용한 Antimony가 도핑된 p 형 ZnO 박막의 구현)

  • Bae, Ki-Ryeol;Lee, Dong-Wook;Elanchezhiyan, J.;Lee, Won-Jae;Bae, Yun-Mi;Shin, Byoung-Chul;Kim, Il-Soo;Shan, F.K.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.10
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    • pp.814-820
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    • 2009
  • Antimony (Sb) doped ZnO thin films (0.1 at.%) were deposited on sapphire (0001) substrates at various temperatures (200 - 600$^{\circ}C$) by using pulsed laser deposition technique. All the thin films have been characterized by X-ray diffractometer, atomic force microscopy and spectrophotometer to investigate their structural, morphological and optical properties, respectively. Hall measurements were also carried out to identify the electrical properties of the thin films. These thin films were constituted in wurtzite structure with the preferential orientation of (002) diffraction plane and had as high as 80% optical transmission in the visible range. The bandgap energy also was determined by spectrophotometer which was around 3.28 eV. Hall measurements results revealed that the Sb dope ZnO thin film (0.1 at.%) grown at $500^{\circ}C$ exhibited p-type conduction with a carrier concentration of $8.633\times10^{16}\;cm^{-3}$, a mobility of $1.41\;cm^2/V{\cdot}s$ and a resistivity of $51.8\;\Omega{\cdot}cm$. We have successfully achieved p-type conduction in antimony doped ZnO thin films with low doping level even though the electrical properties are not favorable. This paper suggests the feasibility of p-type doping with large-size-mismatched dopant by using pulsed laser deposition.

Study on Improvement Method and Performance Analysis About Occupied Existing Roadside Barriers in Expressway (고속도로에서 공용중인 노측용 차량방호울타리의 성능분석 및 개선방안에 관한 연구)

  • Joo, Jae-Woong;Jang, Dae-Young;Ha, Jong-Moon;Park, Je-Jin
    • International Journal of Highway Engineering
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    • v.13 no.4
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    • pp.9-17
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    • 2011
  • It is possible to set up the Roadside Barrier which is suitable for Performance Evaluation Criteria by domestic standard. But a number of section of expressway roadside have old guardrail that was installed before reform the guideline. These poor performance guardrails threaten driver's life. There is lots of difficult problem to change old guardrails that are installed 2,777km in expressway of whole road side at the same time. Especially budget problem. The purpose of study is to develop performance improvement guardrails by the minimum reinforcement. In this study, guardrail improvement method(SB1, 3, 5 grade) is developed through crash simulation using LS-DYNA 3D and vehicle crash test. And it's expected not only to decrease of collision accident but to increase safe level. Of course one thing that can't be missing is to reduce a lot of budget of guardrail change.

Environmental analysis on Waste Catalyst Recycling Technology using Life Cycle Assessment (전과정평가를 통한 폐촉매 재활용 기술의 환경성 분석)

  • Ahn, Joong Woo;Pak, Jong-Jin
    • Resources Recycling
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    • v.27 no.1
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    • pp.64-73
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    • 2018
  • This study aims to analysis the environmental impact on waste catalyst recycling technology using entire life cycle assessment. Environmental impacts consist of the five categories of impacts: global warming, resource depletion, acidification, eutrophication, and photochemical oxide production. The waste catalyst recycling presently have a GWP 3.53 ton $CO_2$ equivalent/ton, a ADP 0.017 ton Sb equivalent/ton, a AP 0.051 $SO_2$ equivalent/ton, a EP 0.0092 $PO{_4}^{3-}$ equivalent/ton, a 0.0019 ton $C_2H_4$ equivalent/ton. The smelting reduction process is the greatest contributor to all categories of environmental impacts in waste catalyst recycling. Electricity used in the smelting reduction process is the major contributor of all impact categories.

Tensile Strengths of Demineralized Dentin derived from Self-Priming Adhesives (Self-Priming Adhesives를 침투시킨 탈회 상아질의 인장강도)

  • Lee, Hye-Yun;Yoon, Mi-Ran;Lee, Rin;Lee, Jeong;Lee, Kwang-Won
    • Journal of Dental Rehabilitation and Applied Science
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    • v.22 no.2
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    • pp.181-191
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    • 2006
  • The objectives of this study were to evaluate the tensile strength of resin-infiltrated demineralized dentin according to the demineralization time, and to evaluate the tensile strength of hybrid layer that is formed by infiltrating different priming adhesives or primer/adhesive into demineralizd dentin matrix. Seventy five hour-glass shaped dentin specimens were prepared in mid-coronal dentin from extracted human molars. Thirty specimens were distributed into three groups according to demineralization time - 2 hours, 4 hours and 8 hours. Each specimen was placed in primer/adhesive of All-Bond 2 for 5 hours of infiltration. Another forty-five specimens of them were demineralized in 37% phosphoric acid for 4 hours. They were randomly assigned to three experimental groups - AB, SB and OS - to designate All-Bond 2, Single Bond and One-Step. Each specimen was placed in one of three different adhesives for 5 hours of infiltration. The specimens were visible light-cured for 5 minutes, and then stored for 24 hours in distilled water at $37^{\circ}C$. After that, microtensile bond strength for each specimen was measured, and the fractured surfaces were then observed by SEM. The data were statistically analysed by one-way ANOVA and Tukey's multiple comparison test and Bonferroni's multiple comparison test. The results were as follows; 1. Tensile strength of the group demineralized for 4 hours was significantly higher than that of groups demineralized for 2 hours and 8 hours (P < .01). 3. Tensile strength of the AB group was significantly higher than that of the SB group and OS group (P < .01).