• Title/Summary/Keyword: $S_A/{\delta}_B$

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Photocurrent study on the splitting of the valence band and growth of $CdGa_2Se_4$ single crystal thin film by hot wall epitaxy (Hot Wall epitaxy(HWE)법에 의한 $CdGa_2Se_4$ 단결정 박막의 성장과 가전자대 갈라짐에 대한 광전류 연구)

  • Park, Chang-Sun;Hong, Kwang-Joon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.5
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    • pp.179-186
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    • 2007
  • Single crystal $CdGa_2Se_4$ layers were grown on a thoroughly etched semi-insulating GaAs(100) substrate at $420^{\circ}C$ with the hot wall epitaxy(HWE) system by evaporating the polycrystal source of $CdGa_2Se_4$ at $630^{\circ}C$. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of single crystal $CdGa_2Se_4$ thin films measured with Hall effect by van der Pauw method are $8.27{\times}10^{17}cm^{-3},\;345cm^2/V{\cdot}s$ at 293 K, respectively. The photocurrent and the absorption spectra of $CdGa_2Se_4/SI$(Semi-Insulated) GaAs(100) are measured ranging from 293 K to 10 K. The temperature dependence of the energy band gap of the $CdGa_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation $E_g(T)=2.6400eV-(7.721{\times}10^{-4}eV/K)T^2/(T+399K)$. Using the photocurrent spectra and the Hopfield quasicubic model, the crystal field energy(${\Delta}cr$) and the spin-orbit splitting energy(${\Delta}so$) far the valence band of the $CdGa_2Se_4$ have been estimated to be 106.5 meV and 418.9 meV at 10 K, respectively. The three photocurrent peaks observed at 10 K are ascribed to the $A_{1^-},\;B_{1^-},\;and\;C_{11}-exciton$ peaks.

Solidification Cracking Behavior in Austenitic Stainless Steel Laser Welds (Part 2) -Effects of δ-ferrite Crystallization and Solidification Segregation Behavior on Solidification Cracking Susceptibility- (오스테나이트계 스테인리스강 레이저 용접부의 응고균열 거동 (Part 2) - δ 페라이트 정출 및 응고편석 거동에 따른 응고균열 민감도 변화 -)

  • Chun, Eun-Joon;Lee, Su-Jin;Suh, Jeong;Kang, Namhyun;Saida, Kazuyoshi
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.61-69
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    • 2016
  • A numerical simulation of the solid/liquid coexistence temperature range, using solidification segregation model linked with the Kurz-Giovanola-Trivedi model, explained the mechanism of the BTR shrinkage (with an increase in welding speed) in type 310 stainless steel welds by reduction of the solid/liquid coexistence temperature range of the weld metal due to the inhibited solidification segregation of solute elements and promoted dendrite tip supercooling attributed to rapid solidification of laser beam welding. The reason why the BTR enlarged in type 316 series stainless welds could be clarified by the enhanced solidification segregation of impurity elements (S and P), corresponding to the decrement in ${\delta}-ferrite$ crystallization amount at the solidification completion stage in the laser welds. Furthermore, the greater increase in BTR with type 316-B steel was determined to be due to a larger decrease in ${\delta}-ferrite$ amount during welding solidification than with type 316-A steel. This, in turn, greatly increases the segregation of impurities, which is responsible for the greater temperature range of solid/liquid coexistence when using type 316-B steel.

Phase Transformation and Reversible Shape Memory Effect of Ti-Ni-Cu Alloys (Ti-Ni-Cu 합금의 상변태 및 가역형상기억효과)

  • Hong, S.W.;Lee, O.Y.;Kim, D.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.3
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    • pp.149-156
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    • 1992
  • Transformation behavior and reversible shape memory effct of Ti-Ni-Cu alloys with various Cu content has been investigated by means of electrical resistivity measurement, differential scanning calorimetry. X-ray diffraction and strain gage sensor. The transformation sequence in Ti-Ni-Cu alloys substituted by Cu for Ni up to 5at.% occurs to $B2{\leftrightarrow}B19^{\prime}$ and it proceeds in two stages by addition of 10 at.%Cu. i.e. $B2{\leftrightarrow}B19{\leftrightarrow}B19^{\prime}$. But the content of Cu increases up to 20at.%, it has been transformed in one stage ; $B2{\leftrightarrow}B19$. The shape change of Ti-40Ni-10Cu alloy which was constrain aged in circular form bended in $B2{\leftrightarrow}B19$ transformation but it spreaded out in $B19{\leftrightarrow}B19^{\prime}$ transformation. The amount of reversible shape change (${\Delta}{\varepsilon}$) of Ti-47Ni-3Cu alloy constrain aged at $400^{\circ}C$ after solution treatment has a maximum value of about $5.6{\times}10^{-3}$, but that of cold rolled and constrain aged specimens exhibits a little value independent of Cu concentrations.

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DERIVATIONS OF A WEYL TYPE NON-ASSOCIATIVE ALGEBRA ON A LAURENT EXTENSTION

  • Choi, Seul-Hee
    • Bulletin of the Korean Mathematical Society
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    • v.43 no.3
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    • pp.627-634
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    • 2006
  • A Weyl type algebra is defined in the book ([4]). A Weyl type non-associative algebra $\={WP_{m,n,s}}$ and its restricted sub-algebra $\={WP_{m,n,s_{\gamma}}}$ are defined in various papers ([1], [12], [3], [11]). Several authors 0nd all the derivations of an associative (Lie or non-associative) algebra in the papers ([1], [2], [12], [4], [6], [11]). We find all the non-associative algebra derivations of the non-associative algebra $\={WP_{0,2,0_B}$, where $B=\{{\partial}_0,\;{\partial}_1,\;{\partial}_2,\;{\partial}_{12},\;{\partial}^2_1,\;{\partial}^2_2\}$.

Basic and Mechanical Properties by Film Type to Minimize the Sound Pressure Level of PTFE Laminated Vapor-permeable Water-repellent Fabrics (PTFE(Polytetrafluoroethylene) 라미네이팅 투습발수직물의 총음압 최소화를 위한 필름 타입 별 기본 특성과 역학 특성)

  • Lee, Kyu-Lin;Lee, Jee-Hyun;Jin, Eun-Jung;Yang, Youn-Jung;Cho, Gil-Soo
    • Fashion & Textile Research Journal
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    • v.14 no.4
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    • pp.641-647
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    • 2012
  • This study investigates the sound properties of fabric frictional sound (SPL, ${\Delta}L$, ${\Delta}f$) according to the film type of PTFE laminated vapor-permeable water-repellent fabrics in order to understand the relationship between SPL and the basic properties of fabrics such as layer, yarn type, and thickness of fiber. This study accesses their mechanical properties and determines how to control them to minimize SPL. Eight PTFE laminated water-repellent fabrics, composed of four different film types (A, B, C, D) and with two different fabrics, were used as test specimens. Frictional sounds generated at 1.21m/s were recorded by using a fabric sound generator and SPLs were analyzed through Fast Fourier Transformation (FFT). The mechanical properties of fabrics were measured by KES-FB. The SPL value was lowest at 74.4dB in film type A and highest as 85.5dB in type D. Based on ANOVA and post-hoc test, specimens were classified into less Loud Group (A, B) and Loud Group (C, D). It was shown that SPL was lower when 2 layer (instead of 3 layer), filament yarn than staple, and thin fiber than thick were used. In Group I, shearing properties (G, 2HG5), geometrical roughness (SMD), compressional properties (LC, RC) and weight (W) showed high correlation with SPL however, elongation (EM) and shear stiffness (G) did with SPL in Group II.

A Predistortion Linearizer Using the In-phase Modulator (동 위상 변조기를 이용한 전치왜곡 선형화기)

  • Kim, Eel-Kou;Jeon, Ki-Kyung;Kim, Young;Youn, Young-Chul
    • Journal of Advanced Navigation Technology
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    • v.10 no.1
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    • pp.41-47
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    • 2006
  • In this paper, a predistortion linearizer using the in-phase modulator is proposed. The harmonic generator of the proposed predistorter extracts a second harmonic signals. These signals are divided in-phase and quadrature-phase signals, and then amplifying each signals using variable gain amplifier. An in-phase modulator, modulate fundamental signal with second harmonic signals, generates the predistortion intermodulation distortion (IM) signals and controls amplitude and phase of them with modulation factors. As a result, this predistorter is suppressed intermodulation distortion signals of power amplifier effectively. The proposed linearizer has been implemented to operate in Cellular-band. The test results show that the third order IM is cancelled more than 20dB in case of CW 2-tone signals with ${\Delta}f$=1MHz. Also, it's improved the adjacent channel power ratio (ACPR) more than 7dB for IS-95 CDMA 1FA signals.

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${\alpha},{\omega}$-Bis[4-(4'(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes-Synthesis and Liquid Crystalline Properties of New Dimesogenic Compounds (${\alpha},{\omega}$-비스[4-(4'-(S)-(+)-2-메틸부틸비페닐-4-카르복시)페녹시]알칸 -새로운 디메소겐 화합물의 합성 및 액정성)

  • Kim, Jae Hoon;Lee, Soo Min;Jin, Jung Il
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.679-695
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    • 1998
  • A series of ${\alpha}{\omega}-bis[4-(4'-(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes$, were synthesized, and their thermal and liquid crystalline properties were studied. The chain length of the central polymethylene spacers, x, of the chiral twin compounds was varied from 3 to 12. These compounds were characterized by elemental analysis, IR and NMR spectroscopy, differential thermal analysis (DSC), and crosspolarized microscopy. All compounds were found to be enantiotropic liquid crystalline, and the values of melting $(T_m)$ and isotropization temperature $(T_i)$ as well as ${\delta}H_I$ and ${\delta}S_I$ decreased in a zig-zag fashion, revealing the so called odd-even effect as x increased. Their mesomorphic properties fell into four categories depending upon x; (a) compounds with x=3, 4 and 5 formed only a cholesteric phase on heating, while on cooling they went through two transitions of isotropic (I)-to-cholesteric (Ch) and Ch-to-smectic $A\;(S_A)$ phases before crystallization. (b) compounds with x=6, 8 and 10 exhibited only a cholesteric phase both on heating and on cooling. (c) compounds with x=7 and 9 went through three transitions of crystal $(C)-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases on heating while on cooling they went through four transitions of I-to-Ch, $Ch-to-S_A,\;S_A-to-Smectic\;C\;(S_C),\;and\;S_c-to-C$ phases in that order, and (d) compounds with x=11 and 12 went reversibly through four transitions of $C-to-S_C,\;S_C-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases.

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The Magnetic Properties of Rapidly Quenched Yttrium-Palladium-Borocarbides Ribbon

  • Kim, K.S;Yu, S.C;Moon, Y.M;Baek, J, S;Lim, W.Y
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.42-45
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    • 1996
  • We have studied the superconductivity of rapidly quenched $YPd_2B_2C$ ribbons. The superconductivity in bulk $YPd_2B_2C$ is completely suppressed by annealing as-cast ingots at hihger temperature, suggesting that the superconducting phase is metastable. The rapidly quenched sample, in the as-quenched state, shows the superconducting transition temperature of about 21 K. Form our magnetic data, the value for the upper critical field $H_c2$ (0) is estimated to be 10 T. The critical current density and the expected specific heat discontinuity $({\Delta}C/{\gamma}{T_c})$ were obtained to be about$10^8A/m^2$ at 10 Oe and 1.55, respectively.

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$Pb_{2}Sr_{2}(Y_{1-x}Ca_{x})Cu_{3}O_{8+{\delta}}$ 계 화합물의 상평형과 제조 공정

  • 정동운
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1994.11a
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    • pp.118-118
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    • 1994
  • Processings of the P $b_2$S $r_2$( $Y_{1-x}$ C $a_{x}$) C $u_3$ $O_{8+{\delta}}$ (2213)system for x=0.4-0.6 to control deleterious oxidative decomposition have been studied. Our results show that comounds are stable at both low p $O_2$ and high p $O_2$ if they are suitably oxidized. Various oxidation and deoxidation procedures have been investigated in order tp determine the optimum hole concentration in the Cu $O_2$layers for the maximum $T_{c}$. In cases x=0.5 and x=0.6, the optimum hole concentration in the 2213-phase is achieved, but with accelerated oxidative decomposition. Destite this, the maximum $T_{c}$~80-83K for the 2213-phase can be deduced when x=0.5 to 0.6 to 0.6

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Oil-Water Interface Transfer of Cefoperazone Pivaloyloxymethyl Ester (세포페라존피바로일옥시메칠에스텔의 유-수 계면 이행에 관한 연구)

  • Choi, Young-Wook;Kim, Johng-Kap
    • Journal of Pharmaceutical Investigation
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    • v.19 no.1
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    • pp.21-27
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    • 1989
  • Kinetic and thermodynamic aspects of the interface transfer of cefoperazone and its pivaloyloxymethyl ester were studied in a two-phase system composed of aqueous buffers and n-octanol by using the absolute reaction rate theory. In terms of the net thermodynamic parameters for the process, ${\Delta}S$ increased and ${\Delta}F$ decreased as the lipophilicity increased. With the increased ratio of forward $(k_f)$ to backward rate constants $(k_b)$, the ester was more lipophilic than cefoperazone, but the aqueous solubility was reduced.

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