• 제목/요약/키워드: $S_A/{\delta}_B$

검색결과 483건 처리시간 0.031초

산소 결핍된 TiO2-δ:Ni 박박의 자기적 성질 연구 (Study on Magnetic Properties of TiO2-δ:Ni Thin Films)

  • 박영란;김광주;김철성
    • 한국자기학회지
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    • 제16권3호
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    • pp.168-172
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    • 2006
  • 졸-겔(sol-gel) 방법을 이용하여 제작된 산소결핍(oxygen vacancy)들을 내포하는 Ni 도핑된 루타일(rutile) 구조의 $TiO_{2-{\delta}}$ 박막들에 대하여 그 자기적 성질 및 관련된 전자구조적 성질에 대하여 조사분석 하였다. $TiO_{2-{\delta}}$:Ni 박막들에서 상온 강자성이 관측되었으며 Ni 도핑량이 증가할수록 포화 자화량($M_s$)이 점차 감소하여 6 at% 이상에서 일정한 값으로 유지되었다. 이와 같은 Ni 도핑량 6 at% 이하에서의 강자성 현상은 산소결핍 자리에 속박된 전자를 매개로 그 주위에 존재하는 불순물 이온들의 자기 능률들이 강자성 정렬을 이루게 되는 자기 폴라론(magnetic polaron)의 형성에 의한 것으로 해석된다. 소량의 Ni 도핑 시 각 이온당 최대 $3.7{\mu}_B/Ni$의 큰 $M_s$ 값이 나타났으며 6 at% 이상에서의 일정한 $M_s$ 값은 Ni cluster 형성에 의한 것으로 해석된다. 이와 같은 Ni cluster의 존재는 시료들에 대한 Hall 측정 결과 나타난 Ni 도핑량 증가에 따르는 p-n 전도성 전이를 설명하여 줄 수 있다.

SUBGRADIENT ESTIMATES FOR A NONLINEAR SUBELLIPTIC EQUATION ON COMPLETE PSEUDOHERMITIAN MANIFOLD

  • Han, Yingbo;Jiang, Kaige;Liang, Mingheng
    • 대한수학회보
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    • 제55권1호
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    • pp.175-186
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    • 2018
  • Let (M, J, ${\theta}$) be a complete pseudohermintian (2n+1)-manifold. In this paper, we derive the subgradient estimate for positive solutions to a nonlinear subelliptic equation ${\Delta}_bu+au{\log}u+bu=0$ on M, where $a{\leq}0$, b are two real constants.

단일과대하중에 의한 피로균열전파의 지연거동 (Retardation of Fatigue Crack Propagation by Single Overloading)

  • 김상철;함경춘;강동명
    • 한국안전학회지
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    • 제7권1호
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    • pp.20-29
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    • 1992
  • Effects of strain hardening exponents on the retardation behavior of fatigue crack propagation are experimentally investigated. The retardation of fatigue crack propagation seems to be induced by the crack closure at crack tip. The phenomenon of crack closure becomes remarkable with the increment of strain hardening exponent and magnitude of percent peak load. The ratio of crack growth increment(a$\_$d//w$\_$d/) is influenced by a single overloading (a$\_$d/) and estimated plastic zone size (W$\_$d/=2r$\_$y/) is increased according with the increasing of strain ha.dening exponents. The number of retarded crack growth cycles were (N$\_$d/) decreased as the baseline stress intensity factor .ange( K$\_$b/) was increased. Within the limitation of these experimental results obtained under the single overload, an empirical relation between crack retardation ratio (Nd/N*), strain hardening exponent (n) and percent peak load (%PL) has been proposed as; Nd/N*= exp [PL $.$ PL$.$A(n)+B(n) ] where, A(n)=${\alpha}$n+${\beta}$, B(n)=${\gamma}$n+$\delta$, PL=%PL/100 and ${\alpha}$=0.78, ${\beta}$=0.54, ${\gamma}$=0.58 and $\delta$=-0.01, It is interesting to note that all these constants are identical for materials such as aluminum(A3203), steel(S4SC), steel(SS41) and stainless steel(SUS316) used in this experimental study.

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냉매의 소결금속관 표면에서의 비등 열전달에 관한 실험적 연구 (Experimental Study on Boiling Heat Transfer of the Tubes with Sintered Metal Surface for Freon-11)

  • 박찬준;문병수;서정윤
    • 대한설비공학회지:설비저널
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    • 제10권3호
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    • pp.220-227
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    • 1981
  • The purpose of this paper is to investigate the potential ability of sintered metal tube to promote heat transfer. In the experiment for Freon - 11, the boiling heat transfer on the sintered metal tube of bronze element is investigated and compared with that of the bronze tube (bare tube) atmospheric pressure. The experimental results are obtained as follows : 1) For sintered metal tubes of bronze element with particle diameters which ranges from $79({\mu})\;to\;461({\mu})$ and bare tube, boiling characteristic curves are expressed as : a) Sintered metal tube $$q{\propto}{\Delta}T^{1.05\~1.373}$$ b) Brae tube $$q{\propto}{\Delta}T^{3.096}$$ 2) Compared with that of the bare tube at low temperature difference$({\Delta}T_{sat})$, boiling heat transfer coefficient of the sintered bronze tube are relatively high. 3) There is tendency that curves of boiling heat transfer coefficients of sintered ·bronze tube and bare tube approach each other at rather high temperature difference. It is due to the increasing rate of the former heat transfer coefficient along with temperature difference is smaller than that of the latter. 4) Referring to particle diameter, optimum condition, i. e. , maximum heat transfer coefficient is found to be at approximately 2 mm thickness of sintered layer with $D_p=150({\mu})$.

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Transition State Characterization of the Low- to Physiological-Temperature Nondenaturational Conformational Change in Bovine Adenosine Deaminase by Slow Scan Rate Differential Scanning Calorimetry

  • Bodnar, Melissa A.;Britt, B. Mark
    • BMB Reports
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    • 제39권2호
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    • pp.167-170
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    • 2006
  • Bovine adenosine deaminase undergoes a nondenaturational conformational change at $29^{\circ}C$ upon heating which is characterized by a large increase in heat capacity. We have determined the transition state thermodynamics of the conformational change using a novel application of differential scanning calorimetry (DSC) which employs very slow scan rates. DSC scans at the conventional, and arbitrary, scan rate of $1^{\circ}C/min$ show no evidence of the transition. Scan rates from 0.030 to $0.20^{\circ}C/min$ reveal the transition indicating it is under kinetic control. The transition temperature $T_t$ and the transition temperature interval ${\Delta}T$ increase with scan rate. A first order rate constant $k_1$ is calculated at each $T_t$ from $k_1\;=\;r_{scan}/{\Delta}T$, where $r_{scan}$ is the scan rate, and an Arrhenius plot is constructed. Standard transition state analysis reveals an activation free energy ${\Delta}G^{\neq}$ of 88.1 kJ/mole and suggests that the conformational change has an unfolding quality that appears to be on the direct path to the physiological-temperature conformer.

ON BONNESEN-STYLE ALEKSANDROV-FENCHEL INEQUALITIES IN ℝn

  • Zeng, Chunna
    • 대한수학회보
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    • 제54권3호
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    • pp.799-816
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    • 2017
  • In this paper, we investigate the Bonnesen-style Aleksandrov-Fenchel inequalities in ${\mathbb{R}}^n$, which are the generalization of known Bonnesen-style inequalities. We first define the i-th symmetric mixed homothetic deficit ${\Delta}_i(K,L)$ and its special case, the i-th Aleksandrov-Fenchel isoperimetric deficit ${\Delta}_i(K)$. Secondly, we obtain some lower bounds of (n - 1)-th Aleksandrov Fenchel isoperimetric deficit ${\Delta}_{n-1}(K)$. Theorem 4 strengthens Groemer's result. As direct consequences, the stronger isoperimetric inequalities are established when n = 2 and n = 3. Finally, the reverse Bonnesen-style Aleksandrov-Fenchel inequalities are obtained. As a consequence, the new reverse Bonnesen-style inequality is obtained.

Double magnetic entropy change peaks and high refrigerant capacity in Gd1-xHoxNi compounds in the melt-spun form

  • Jiang, Jun-fan;Ying, Hao;Feng, Tang-fu;Sun, Ren-bing;Li, Xie;Wang, Fang
    • Current Applied Physics
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    • 제18권12호
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    • pp.1605-1608
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    • 2018
  • $Gd_{1-x}Ho_xNi$ melt-spun ribbons were fabricated by a single-roller melt spinning method. All the compounds crystallize in an orthorhombic CrB-type structure. The Curie temperature ($T_C$) was tuned between 46 and 99 K by varying the concentration of Gd and Ho. A spin reorientation (SRO) transition is observed around 13 K. Different from $T_C$, the SRO transition temperature is almost invariable for all compounds. Two peaks of magnetic entropy change (${\Delta}S_M$) were found. One at the higher temperature range was originated from the paramagnet-ferromagnet phase transition and the other at the lower temperature range was caused by the SRO transition. The maximum of ${\Delta}S_M$ around $T_C$ is almost same. The other maximum of ${\Delta}S_M$ around SRO transition, however, had significantly positive relationship with x. It reached a maximum about $8.2J\;kg^{-1}\;K^{-1}$ for x = 0.8. Thus double large ${\Delta}S_M$ peaks were obtained in $Gd_{1-x}Ho_xNi$ melt-spun ribbons with the high Ho concentration. And the refrigerant capacity power reached a maximum of $622J\;kg^{-1}$ for x = 0.6. $Gd_{1-x}Ho_xNi$ ribbons could be good candidate for magnetic refrigerant working in the low temperature especially near the liquid nitrogen temperature range.

BSCCO계 초전도체에서 서냉 열처리에 의한 2차상 석출 (The Precipitation of Second Phases by Annealing Heat Treatment in the $(Bi,Pb)_2$${Sr_2}{Ca_2}{Cu_3}{O_{10}}$ Superconductor System)

  • 이상희;김철진;유재무
    • 한국세라믹학회지
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    • 제37권12호
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    • pp.1212-1220
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    • 2000
  • Bi-2223 초전도체계에서 석출물을 flux-pinning center로 이용할 수 있는지 가능성을 타진하기 위하여 $Bi_{1.8}$P $b_{0.4}$S $r_{2}$C $a_{2.2}$C $u_3$ $O_{8}$ 조성을 가진 Bi-2223/Ag 선재를 반응온도, 산소분압, 시간 등을 변화시키면서 열처리를 행하였다. 열처리 후 석출물들은 XRD, SEM, TEM, EDS로 분석하였다. Bi-2223 모상내의 (Ca, Sr)$_2$(Pb,Bi) $O_4$, B $i_{0.5}$ P $b_3$S $r_2$C $a_2$Cu $O_{12+}$$\delta$/ (3221)와 같은 2차상들의 크기와 분포는 2223 입자들의 연결성을 파괴하지 않고 열처리 조건에 의해서 조절할 수 있었다. 서냉 열처리가 된 시편은 임계전류밀도( $J_{c}$)값이 증가하였는데, 이는 2223 입자내 나노미터 크기로 형성된 석출물들이 flux-pinning sites로 작용한 것으로 추정된다.다.

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프로테옴 분석에 의한 Bacillus subtilis PyrR 돌연변이체의 특성 (Characterization of a PyrR-deficient Mutant of Bacillus subtilis by a Proteomic Approach)

  • 설경조;조현수;김사열
    • 한국미생물·생명공학회지
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    • 제39권1호
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    • pp.9-19
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    • 2011
  • Bacillus subtilis의 pyrimidine biosynthetic (pyr) operon은 UMP의 de nove 생합성에 관여하는 enzyme들을 encode할 뿐만 아니라, 조절단백질인 PyrR도 encode한다. PyrR은 pyr mRNA-binding 조절 기능과 uracil phosphoribosyltransferase activity를 동시에 가지는 bifunctional 단백질이다. 본 연구에서는 Proteomic analysis를 이용하여 Uracil - 환경에서 DB104${\Delta}$pyrR의 단백질 패턴을 분석하여 단백질 레벨에서 PyrR 단백질의 실질적인 조절 양상을 관찰하였다. 두 균주의 세포질 단백질은 다양한 발현의 차이를 보였으며, Silver 염색된 2D-gel의 pI 4~10 사이에서는 1,300여개의 단백질이 검출되었으며, 단백질 발현 차이를 보이는 172개의 spot 중에서 42개의 단백질이 identification 되었다. 그 결과 pyr operon의 단백질(PyrAa, PyrAb, PyrB, PyrC, PyrD, and PyrF)이 모두 Up regulation이 이루어지고 있음을 확인할 수 있었으며, 이것은 단백질 레벨에서 Pyrimidine 생합성 과정이 PyrR에 의해서 정확히 Regulation 되어짐을 확인할 수 있었다. 또한 Pyrimidine 생합성의 Up regulation과 Down regulation 상태의 단백질의 패턴 양상도 분석할 수 있게 되었다. Pyrimidine의 생합성 과정은 DNA를 구성하는 기본적인 구성 요소를 생산하는 과정으로서 여러가지 Metabolism 가운데 중요한 위치를 차지하고 있다. 만약 Pyrimidine의 생합성 과정이 Over- expression된다면 다른 Metabolism의 균형에도 변화가 올 것이다. Proteomics Analysis에 이용한 DB104${\Delta}$pyrR 균주는 Pyrimidine 생합성의 조절에 관여하는 PyrR knock out 균주로서 Uracil - 환경에서는 전체적인 Pyrimidine 생합성 조절이 Up regulation이 되어지므로 Up regulation 동안 어떤 Metabolism에 영향을 주는지 관찰을 할 수 있게 되었다. 특히 Amino Acid Metabolism에 관계있는 단백질의 Up regulation이 이루어짐을 관찰할 수 있었으며 이것은 현재 각광을 받고 있는 단백질 산업에 응용함으로써 산업적으로 많은 기대를 할 수 있을 것으로 예상되어진다.

황색계 천연염료에 의한 셀룰로스, 단백질계 섬유의 염색 (The Dyeing Properties of Cellulose and Protein Fabrics by Yellow Natural Dyes)

  • 신영준
    • 한국의상디자인학회지
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    • 제19권1호
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    • pp.135-145
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    • 2017
  • In order to analysis on color difference of yellow natural dyes, I have dyed cellulose and protein fabrics. The results of experiment have been analysed by wavelength of maximum absorption, amounts of dye uptake, color difference, Hunter's value and Munsell's value. The results from these analyses are as follows : Bud of pagoda tree, Amur cork, and Curcuma showed greenish yellow color, Gardenia Jasminoides showed reddish yellow color. Barberry root showed reddish yellow color with post-mordanting method on cellulose fabric. Moreover, Dupioni silk was dyed in reddish yellow color by Barberry root and Rhubarb. In addition to Chroma index, Gardenia Jasminoides and Curcuma showed clear color overall. However, dyeing rayon and silk by Barberry root, and dyeing silk by Rhubarb showed clear color. Comparing all the results to actual dyed materials, Bud of pagoda tree had small dye uptake, and both ${\Delta}a$ and ${\Delta}b$ value were short which can't recognized the yellow color easily. Dye uptake of Amur cork and Gardenia Jasminoides was small just like Bud of pagoda tree. However, ${\Delta}b$ value order was Gardenia Jasminoides>Amur cork>Bud of pagoda tree. Therefore, Gardenia Jasminoides recognized reddish yellow because of big value of red color and yellow color. In case of Barberry root and Rhubarb which have larger dye uptake, Baberry root recognized yellow color on rayon only, and couldn't recognized yellow color on bleached cotton fabric, ramie, silk, and dupioni silk. Rhubarb recognized yellow color on rayon with pre-mordanting method only, but recognized silk and dupioni silk as brown like color. Moreover, we could not analyze color by dye uptake, Lab, and H(v/c) for Barberry root and Rhubarb. As a result, I think we need to attach color table for the research paper which handled the color of dyeing materials.

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