• 제목/요약/키워드: $S_{N}2$ mechanism

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QoS guaranteed IP multicast admission control mechanism (품질 보장형 IP 멀티캐스트 수락 제어 메커니즘)

  • Song, kang-ho;Rhee, wooo-Seop
    • Proceedings of the Korea Contents Association Conference
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    • 2008.05a
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    • pp.51-55
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    • 2008
  • Request High-Images, High-quality, duplex transmission, BcN Voice telephone, Broadcast, Data internet service came to be all possible and demolished original communication service area. Also, The quality is guaranteed stablely to new business and ISP the requirement comes to become a multicasting quality guarantee mechanism which there is the reliability for a information communication and High-quality multimedia service. Like this, a multicast mechanism to be guaranteed must become air control End-to-End QoS for a service supply, a transmission delay a packet loss or requirement which the user requests guarantee and multicast Path-NET which there is the reliability must be provided. Therefor, we proposed IP base multicast new join the present the multicast mechanism of Probing packet foundation which there is the efficiently a linking acceptance, we used ns-2 simulator for the performance evaluation of the proposed.

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Fluorescence quenching of 5-methyl-3-phenyl-2-[s-oxadiazol-2'-thione-5'-yl] indole by $CCl_4$ and aniline in different solvents

  • H M, Suresh-Kumar;R S, Kunabenchi;J S, Biradar;N N, Math;J S, Kadadevaramath
    • Journal of Photoscience
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    • v.10 no.3
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    • pp.225-229
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    • 2003
  • The fluorescence quenching of 5-methyl-3-phenyl-2-[s-oxadiazol-2'-thionen5'-yl] indole by carbon tetrachloride ($CCl_4$) and aniline in different solvents viz., dioxane, benzene, toluene, methanol, propanol has been carried out at room temperature to understand the role of quenching mechanisms. The Stern-Volmer plots have been found to be linear. As probability of quenching per encounter 'p' is less than unity, and the activation energy for quenching 'E$_{a}$' is greater than the activation energy of diffusion 'E$_{d}$', it is inferred that the fluorescence of quenching mechanism is not due to material diffusion alone.e.e.

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Flame Behaviors of Counterflow Nonpremixed Flame Perturbed by a Vortex (와동에 의해 교란된 대향류 비예혼합화염의 화염거동)

  • Oh, Chang-Bo;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.57-63
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    • 2004
  • A two-dimensional direct numerical simulation was performed to investigate the flame behaviors of $CH_4/N_2$-Air counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman's detailed reaction mechanism are adopted in this calculation. The results showed that an initially flat stagnation plane, on which an axial velocity was zero, was deformed into a complex-shaped plane, and an initial stagnation point was moved far away from a vortex head when the counterflow field was perturbed by the vortex. It was noted that the movement of stagnation point could alter the species transport mechanism to the flame surface. It was also identified that the altered species transport mechanism affected the distributions of the mixture fraction and the scalar dissipation rate.

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Structure-Reactivity Relationship of Benzyl Benzenesulfonates. Part 4. Application of Correlation Interaction Coefficients

  • 여수동;정덕영;박종환;김성홍;황규탁
    • Bulletin of the Korean Chemical Society
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    • v.19 no.4
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    • pp.434-436
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    • 1998
  • The mechanism of nucleophilic displacement was studied by using three variable systems of ${\rho}_X,\; {\rho}_Y,\; and {\rho}_Z$ obtained from the change of substituent X, Y, and Z for the reaction of (Z)-substituted benzyl (X)-benzensulfonates with (Y)-substituted thiobenzamides in acetone at 45 ℃. The results ${\rho}_Z$<0 and ${\rho}_YZ$>${\rho}_XZ$ indicate that this reaction series proceeded via a dissociative $S_N2$ mechanism. The prediction of the movement of TS by using the sign of ${\rho}_XZ{\cdot}{\rho}_{YZ}$ accorded with the Hammond postulate.

Expression of nitric oxide synthase isoforms and N-methyl-D-aspartate receptor subunits according to transforming growth factor-β1 administration after hypoxic-ischemic brain injury in neonatal rats (신생 백서의 저산소 허혈 뇌손상에서 Transforming Growth Factor-β1 투여에 따른 Nitric Oxide Synthase 이성체와 N-methyl-D-aspartate 수용체 아단위의 발현)

  • Go, Hye Young;Seo, Eok Su;Kim, Woo Taek
    • Clinical and Experimental Pediatrics
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    • v.52 no.5
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    • pp.594-602
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    • 2009
  • Purpose : Transforming growth factor (TGF)-${\beta}1$ reportedly increases neuronal survival by inhibiting the induction of inducible nitric oxide synthase (NOS) in astrocytes and protecting neurons after excitotoxic injury. However, the neuroprotective mechanism of $TGF-{\beta}1$ on hypoxic-ischemic (HI) brain injury in neonatal rats is not clear. The aim of this study was to determine whether $TGF-{\beta}1$ has neuroprotective effects via a NO-mediated mechanism and N-methyl-D-aspartate (NMDA) receptor modulation on perinatal HI brain injury. Methods : Cortical cells were cultured using 19-day-pregnant Sprague-Dawley (SD) rats treated with $TGF-{\beta}1$ (1, 5, or 10 ng/mL) and incubated in a 1% O2 incubator for hypoxia. Seven-day-old SD rat pups were subjected to left carotid occlusion followed by 2 h of hypoxic exposure (7.5% $O_2$). $TGF-{\beta}1$ (0.5 ng/kg) was administered intracerebrally to the rats 30 min before HI brain injury. The expressions of NOS and NMDA receptors were measured. Results : In the in vitro model, the expressions of endothelial NOS (eNOS) and neuronal NOS (nNOS) increased in the hypoxic group and decreased in the 1 ng/mL $TGF-{\beta}1-treated$ group. In the in vivo model, the expression of inducible NOS (iNOS) decreased in the hypoxia group and increased in the $TGF-{\beta}1$-treated group. The expressions of eNOS and nNOS were reversed compared with the expression of iNOS. The expressions of all NMDA receptor subunits decreased in hypoxia group and increased in the $TGF-{\beta}1$-treated group except NR2C. Conclusion : The administration of $TGF-{\beta}1$ could significantly protect against perinatal HI brain injury via some parts of the NO-mediated or excitotoxic mechanism.

Two Stage Process Mechanism of Silica Adsorption by Soil in Adsoption Kinetics (토양의 규산 흡착 카이네틱에서 2단계 흡착 기작)

  • Lee, Sang-Eun;Jung, Kwang-Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.2
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    • pp.107-112
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    • 1996
  • To clarify the mechanism of silica adsorption to soil, kinetic study using continuous stirred-flow method was conducted with the Luisiana soil at three pH levels (pH 5.0, 6.5, and 8.0). Silica adsorption increased continuously without showing the maximum adsorption for long enough experimental time. Kinetic curve of silica adsorption could be divided into two stage processes. The first stage process was fitted well to the following equation with highly significant correlation coefficient : $$R_{ad}=K_a*(Q_{OH}^S)^n$$ where, $R_{ad}$ is silica adsorption rate($Si\;{\mu}mal/min$). $Q_{OH}^S$ is the negative charge sites on the soil surface created by alkali titration, and $K_a$ and n are constants. The "n" value of the first stage process was 1.1. This value indicates that the silica adsorption is accomplished by the monodendate ligand bonding. The second stage process was fitted well to the following equation : $$R_{ad}=K_b*(pH)$$ where, $K_b$ is a constant. The equation indicates that the silica adsorption is not proportional to the $OH^-$ ion concentration. Rather, the increasing pattern of silica adsorption rate with the increase of $OH^-$ ion concentration would decrease exponentially.

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4181Overcoming the High-current Efficiency Loss Mechanism in GaN-based Light-emitting Diodes

  • Kim, Jong-Gyu
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.23.2-23.2
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    • 2011
  • This presentation will include an overview of III-Nitride LED technology, applications, key areas for future improvements, challenges such as efficiency droop. GaN-based high-power light-emitting diodes (LEDs) suffer from high-current loss mechanisms that lead to a significant decrease in internal quantum efficiency at high drive currents, a well-known phenomenon commonly referred to as efficiency droop. Although many attempts have been made to uncover this LED's darkest secret, there is still a lack of consensus on the dominant mechanism responsible for this detrimental phenomenon. In this presentation, proposed origins and corresponding solutions to the droop-causing mechanisms will be reviewed and discussed.

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$^{15}N$ NMR Relaxation Studies of Backbone Motion of the catalytic Residues in Free and Steroid-bound ${\Delta}^5$-3-Ketosteroid Isomerase

  • Lee, Hee-Cheon;Sunggoo Yun
    • Journal of the Korean Magnetic Resonance Society
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    • v.5 no.2
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    • pp.130-137
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    • 2001
  • Backbone dynamics of the catalytic residues in free and steroid-bound $\Delta$$^{5}$ -3- ketosteroid isomerase from Pseudomonas testosteroni has been examined by $^{15}$ N relaxation measurements. The relaxation data were analyzed using the model-free formalism to extract the model-free parameters (S$^2$, $\tau$$_{e}$, and R$_{ex}$). Tyr-34 and Asp-99 exhibit enhanced high-frequency (pico- to nanosecond) internal motions in the free enzyme, which are restricted upon ligand binding, while Asp-38 experiences severe restriction of the internal motions in the fee enzyme, suggesting that Tyr-14 and Asp-99 are more actively involved in the ligand binding than Asp-38. The results also indicate that the H-bond network in the catalytic cavity might be slightly strengthened upon ligand binding, which may have some implications on the enzyme mechanism.he enzyme mechanism.m.

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Shear-fatigue behavior of high-strength reinforced concrete beams under repeated loading

  • Kwak, Kae-Hwan;Park, Jong-Gun
    • Structural Engineering and Mechanics
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    • v.11 no.3
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    • pp.301-314
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    • 2001
  • The purpose of this experimental study is to investigate the damage mechanism due to shear-fatigue behavior of high-strength reinforced concrete beams under repeated loading. The relationship between the number of cycles and the deflection or strain, the crack growths and modes of failure with the increase of number of cycles, fatigue strength, and S-N curve were observed through a fatigue test. Based on the fatigue test results, high-strength reinforced concrete beams failed at 57-66 percent of static ultimate strength for 2 million cycles. The fatigue strength at 2 million cycles from S-N curves was shown as about 60 percent of static ultimate strength. Compared to normal-strength reinforced concrete beams, fatigue capacity of high-strength reinforced concrete beams was similar to or lower than fatigue capacity of normal-strength reinforced concrete beams. Fatigue capacity of normal-strength reinforced concrete beams improved by over 60 percent.

Mechanistic Change-Over in Nucleophilic Solvent Assisted Reactions

  • Sung, Dae Dong;Kim Yang Hee;Park Yoo-Mee;Ryu Zoon Ha;Lee Ickchoon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.599-605
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    • 1992
  • Rate constants of methanolyses of para-Z-substituted benzenesulfonyl chlorides have been determined in various isodielectric solvent mixtures. A third-order kinetic behavior has been observed in the methanolysis of p-nitrobenzenesulfonyl chloride in methanol-nitromethane mixture from the correlation figure of logarithms of rate constants were plotted against Y-values based on solvolyses of 1-adamantyl tosylate. $S_N1$-$S_N2$ mixing mechanisms are favored by neutral or weak electron-donating and weak electron-withdrawing substituents of p-Z-substituted benzenesulfonyl chlorides in methanol-nitrobenzene mixture. While the methanolyses of para-Z-substituted benzenesulfonyl chlorides in methanol-ethylene glycol solvent mixture are appropriate for $S_N2$ mechanism from the mechanistic criterion by means of m-values.