• 제목/요약/키워드: $Q_{10}$ coefficient

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BNKZ치환된 (Na,K)NbO3계 세라믹스의 미세구조 및 압전 특성 (Microstructure and Piezoelectric Properties of (Na,K)NbO3 System Ceramics Substituted with BNKZ)

  • 한종대;류주현
    • 한국전기전자재료학회논문지
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    • 제30권10호
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    • pp.637-640
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    • 2017
  • In this study, $(1-x)(Na_{0.52}K_{0.443}Li_{0.037})(Nb_{0.883}Sb_{0.08}Ta_{0.037})O_3-x(Bi_{0.5}(Na_{0.7}K_{0.3})_{0.5}ZrO_3$ ceramics were fabricated by BNKZ substitution using a conventional solid-state method to develop excellent lead-free piezoelectric ceramics for piezoelectric actuators; their dielectric and piezoelectric properties were then investigated. All specimens were in the orthorhombic phase. $NKL-NSTO_3$ ceramics with x=0.01 showed excellent piezoelectric properties. The density (${\rho}$), piezoelectric charge constant ($d_{33}$), planar piezoelectric coupling coefficient ($k_p$), mechanical quality factor ($Q_m$), and dielectric constant (${\varepsilon}_r$) had optimized values of $4.56g/cm^3$, 208 pC/N, 0.43, 96, and 975, respectively.

Various Partial Charge Schemes on 3D-QSAR Models for P-gp Inhibiting Adamantyl Derivatives

  • Gadhe, Changdev G.;Madhavan, Thirumurthy;Kothandan, Gugan;Lee, Tae-Bum;Lee, Kyeong;Cho, Seung-Joo
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1604-1612
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    • 2011
  • We developed three-dimensional quantitative structure activity relationship (3D-QASR) models for 17 adamantyl derivatives as P-glycoprotein (P-gp) inhibitors. Eighteen different partial charge calculation methods were tested to check the feasibility of the 3D-QSAR models. Best predictive comparative molecular field analysis (CoMFA) model was obtained with the Austin Model 1-Bond Charge Correction (AM1-BCC) atomic charge. The 3D-QSAR models were derived with CoMFA and comparative molecular similarity indices analysis (CoMSIA). The final CoMFA model ($q^2$ = 0.764, $r^2$ = 0.988) was calculated with an AM1-BCC charge and electrostatic parameter, whereas the CoMSIA model ($q^2$ = 0.655, $r^2$ = 0.964) was derived with an AM1-BCC charge and combined steric, electrostatic, hydrophobic and HB-acceptor parameters. Leave-five-out (LFO) cross-validation was also performed, which yielded good correlation coefficient for both CoMFA (0.801) and CoMSIA (0.656) models. Robustness of the developed models was checked further with 1000 run bootstrapping analyses, which gave an acceptable correlation coefficient for CoMFA (BS-$r^2$ = 0.997, BS-SD = 0.003) and CoMSIA (BS-$r^2$ = 0.996, BS-SD = 0.018).

3D-QSAR Studies on Chemical Features of 3-(benzo[d]oxazol-2-yl)pyridine-2-amines in the External Region of c-Met Active Site

  • Lee, Joo Yun;Lee, Kwangho;Kim, Hyoung Rae;Chae, Chong Hak
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3553-3558
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    • 2013
  • The three dimensional-quantitative structure activity relationship (3D-QSAR) studies on chemical features of pyridine-2-amines in the external region of c-Met active site (ER chemical features of pyridine-2-amines) were conducted by docking, comparative molecular field analysis (CoMFA), and topomer CoMFA methods. The CoMFA model obtained the partial least-squares (PLS) statistical results, cross-validated correlation coefficient ($q^2$) of 0.703, non cross-validated correlation coefficient ($r^2$) of 0.947 with standard error of estimate (SEE) of 0.23 and the topomer CoMFA obtained $q^2$ of 0.803, $r^2$ of 0.940, and SEE of 0.24. Further, the test set was applied to validate predictive abilities of models, where the predictive $r^2$ ($r{^2}_{pred}$) for CoMFA and topomer CoMFA models were 0.746 and 0.608, respectively. Each contribution of ER chemical features of pyridine-2-amines to the inhibitory potency showed correlation coefficients, $r^2$ of 0.670 and 0.913 for two core parts, 3-(benzo[d]oxazol-2-yl)pyridine-2-amine and 3-(1-(2,6-dichloro-3-fluorophenyl)ethoxy) pyridine-2-amine, respectively, with corresponding experimental $pIC_{50}$.

한국의 저서성 대형무척추동물 생태점수 개선 (Revision of Ecological Score of Benthic Macroinvertebrates Community in Korea)

  • 공동수;박영준;전용락
    • 한국물환경학회지
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    • 제34권3호
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    • pp.251-269
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    • 2018
  • In 1997, the environmental score (Q) corresponding the tolerance value of Korean benthic macroinvertebrate species and the related biotic score, the ecological score of benthic macroinvertebrates (ESB) were proposed; ESB was similar to Beck's biotic index or Chandler's biotic score. This study was carried out to revise the Q values of individual species and the assessment scheme of ESB based on the taxonomic performance and ecological information accumulated since then. The original ESB was renamed as TESB (total ESB), and AESB (average ESB) was newly proposed. AESB is calculated by dividing the TESB (for a given station) by the number of species present in the sample. In this study, TESB showed a positively skewed distribution, while AESB showed a negatively skewed distribution. The correlation between TESB and the concentration of $BOD_5$ was a little stronger than that of the original ESB. TESB showed a very strong correlation (correlation coefficient r = 0.98) with Margalef's species richness, of which correlation coefficient was higher than that of AESB (r = 0.85). AESB showed a strong correlation (r = -0.79) with the concentration of $BOD_5$, while TESB showed a weaker correlation (r = -0.67). Applying TESB and AESB together in an assessment of the environment may be comprehensive because the physical and chemical states of the environment can be evaluated together. AESB is less dependent on the sample size, while TESB tends to increase as the sample size increases. In the evaluation of the environment using TESB, it is necessary to standardize the methods on monitoring.

배추 용수량에 관한 연구 (Study on The Water Requirements of Chinese Cabbage.)

  • 김현철;정두호
    • 한국농공학회지
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    • 제16권2호
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    • pp.3430-3437
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    • 1974
  • .It is very importaut to know the water consumption of crops in planning irrigation works and practicing suitable soil moisture management. For the purpose of making it clear that how much water be consumed to cultivate the Chinese cabbage, Chamber method has been applied. Main equipments in the transpiration chamber are flowers, manometer and electric thermograph. The chamber made of vynyl plate has a small entrance at the base and an exit at the top, and the ventilation in the chamber was carried out by a flower through the entrance and exit. Air-flow adjusted by an orifice manometer enters the chamber from the outside over the crop canopy through the pipe like a chimney and finally goes out to the outside. Two sets which consist of a pair of dry and wet bulb made by thermistor are installed in the entrance and exit tube, and record air temperature automatically. Evapotranspiration amount is computed from the air-flow quantity and difference in absolute humidity between at the entrance and exit of the chamber by the following equation: ET=(X2-X1)${\times}$Q where ET=evapotranspiration amount X1=absolute humidity at the entrance(g/㎥) X2=absolute humidity at the exit(g/㎥) Q=air-flow quantity(㎥) This study was carried out at the upland farm of the Institute of Agriculture Engimeering and Utilization, Suwon, Korea. from 1971 to 1973. The results obtained in this experiment are as follows: 1. The total amount of evapotranspiration of Chinese Cabbage that is cultivated in autumn is 408.1mm during growth period. 2. Chinese cabbage rapidly grows up in the second ten days of September, 40th to 50th days after seeding. At the same time, the maximum amount of evaportranspiration of Chinese cabbage is 61.6mm/10 days 3. The correlation between Pan-evaporation and evapotranspiration is high, coefficient of correlation r=0.88**, and can be shown as The following regression equation: ET=0.913E+20.273 4. Evapotranspiration is closely related with meteorological factors: r=0.85**, for insolation, r=0.76** for air temperature, respectively. 5. The percentage of evapotranspiration amount, at the beginning of growth stage, gradually increases in proportion as the Chinese Cabbage grows but is largely affected by meteorological factors after the green cover formation. 6. By Blaney and Griddle formula, evaportranspiration coefficient "K" are within from 0,85 to 1.27.

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Coercivity Enhancement of Sintered Nd-Fe-B Magnets by Grain Boundary Diffusion with DyH3 Nanoparticles

  • Liu, W.Q.;Chang, C.;Yue, M.;Yang, J.S.;Zhang, D.T.;Liu, Y.Q.;Zhang, J.X.;Yi, X.F.;Chen, J.W.
    • Journal of Magnetics
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    • 제18권4호
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    • pp.400-404
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    • 2013
  • Grain boundary diffusion technique with $DyH_3$ nanoparticles was applied to fabricate Dy-less sintered Nd-Fe-B permanent magnets with high coercivity. The magnetic properties and microstructure of magnets were systematically studied. The coercivity and remanence of grain boundary diffusion magnet were improved by 60% and reduced by 7% compared with those of the original magnet, respectively. Meanwhile, both the remanence temperature coefficient (${\alpha}$) and the coercivity temperature coefficient (${\beta}$) of the magnets were improved after diffusion treatment. Investigation shows that Dy is preferentially enriched as (Nd, Dy)$_2Fe_{14}B$ phase in the surface region of the $Nd_2Fe_{14}B$ matrix grains indicated by the remarkable enhancement of the magneto-crystalline anisotropy field of the magnet. As a result, the magnet diffused with a small amount of Dy nanoparticles possesses enhanced coercivity without remarkably sacrificing its magnetization.

Annual and spatial variabilities in the acorn production of Quercus mongolica

  • Noh, Jaesang;Kim, Youngjin;Lee, Jongsung;Cho, Soyeon;Choung, Yeonsook
    • Journal of Ecology and Environment
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    • 제44권4호
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    • pp.229-240
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    • 2020
  • Background: Genus Quercus is a successful group that has occupied the largest area of forest around the world including South Korea. The acorns are an important food source for both wild animals and humans. Although the reproductive characteristics of this genus are highly variable, it had been rarely studied in South Korea. Therefore, in Seoraksan and Odaesan National Parks (i) we measured the acorn production of Quercus mongolica, an overwhelmingly dominant species in South Korea, for 3 years (2017-2019), (ii) evaluated the spatial-temporal variation of acorn production, and (iii) analyzed the effects of oak- and site-related variables on the acorn production. Results: The annual acorn production of Q. mongolica increased 36 times from 1.2 g m-2 in 2017 to 43.2 g m-2 in 2018, and decreased to 16.7 g m-2 in 2019, resulting in an annual coefficient of variation of 104%. The coefficient of spatial variation was high and reached a maximum of 142%, and the tree size was the greatest influencing factor. That is, with an increase in tree size, acorn production increased significantly (2018 F = 16.3, p < 0.001; 2019 F = 8.2, p < 0.01). Elevation and slope also significantly affected the production in 2019. However, since elevation and tree size showed a positive correlation (r = 0.517, p < 0.001), the increase in acorn production with increasing elevation was possibly due to the effect of tree size. The acorn production of Odaesan for 3 years was 2.2 times greater than that of Seoraksan. This was presumed that there are more distribution of thick oak trees and more favorable site conditions such as deep soil A-layer depth, high organic matter, and slower slopes. Conclusion: As reported for other species of the genus Quercus, the acorn production of Q. mongolica showed large spatial and annual variations. The temporal variability was presumed to be a weather-influenced masting, while the spatial variability was mainly caused by oak tree size.

약물의 염전성 부정맥 유발 예측 지표로서 심장의 전기생리학적 특징 값들의 검증 (Verification of Cardiac Electrophysiological Features as a Predictive Indicator of Drug-Induced Torsades de pointes)

  • 유예담;정다운;;임기무
    • 대한의용생체공학회:의공학회지
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    • 제43권1호
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    • pp.19-26
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    • 2022
  • The Comprehensive in vitro Proarrhythmic Assay(CiPA) project was launched for solving the hERG assay problem of being classified as high-risk groups even though they are low-risk drugs due to their high sensitivity. CiPA presented a protocol to predict drug toxicity using physiological data calculated based on the in-silico model. in this study, features calculated through the in-silico model are analyzed for correlation of changing action potential in the near future, and features are verified through predictive performance according to drug datasets. Using the O'Hara Rudy model modified by Dutta et al., Pearson correlation analysis was performed between 13 features(dVm/dtmax, APpeak, APresting, APD90, APD50, APDtri, Capeak, Caresting, CaD90, CaD50, CaDtri, qNet, qInward) calculated at 100 pacing, and between dVm/dtmax_repol calculated at 1,000 pacing, and linear regression analysis was performed on each of the 12 training drugs, 16 verification drugs, and 28 drugs. Indicators showing high coefficient of determination(R2) in the training drug dataset were qNet 0.93, AP resting 0.83, APDtri 0.78, Ca resting 0.76, dVm/dtmax 0.63, and APD90 0.61. The indicators showing high determinants in the validated drug dataset were APDtri 0.94, APD90 0.92, APD50 0.85, CaD50 0.84, qNet 0.76, and CaD90 0.64. Indicators with high coefficients of determination for all 28 drugs are qNet 0.78, APD90 0.74, and qInward 0.59. The indicators vary in predictive performance depending on the drug dataset, and qNet showed the same high performance of 0.7 or more on the training drug dataset, the verified drug dataset, and the entire drug dataset.

Influence of Sustain Pulse-width on Electrical Characteristics and Luminous Efficiency in Surface Discharge of AC-PDP

  • Jeong, Yong-Whan;Jeoung, Jin-Man;Choi, Eun-Ha
    • Transactions on Electrical and Electronic Materials
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    • 제6권6호
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    • pp.276-279
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    • 2005
  • Influences of sustain pulse-width on electrical characteristics and luminous efficiency are experimentally investigated for surface discharge of AC-PDP. A square pulse with variable duty ratio and fixed rising time of 300 ns has been used in the experiment. It is found that the memory coefficient is significantly increased at the critical pulse-width. And the wall charges and wall voltages as well as capacitances are experimentally measured by Q- V analysis method along with the voltage margin relation, in terms of the sustain pulse-width in the range of $1{\mu}s$ to $5{\mu}s$ under driving frequency of 10 kHz to 180 kHz. And the luminous efficiency is also experimentally investigated in above range of sustain pulse-width with driving frequency of 10 kHz to 180 kHz. It is noted that the luminous efficiency for 10 kHz and 180 kHz are 1.29 1m/W and 0.68 1m/W respectively, since the power consumption for 10 kHz is much less than that for 180 kHz. It has been concluded that the optimal sustain pulse-width is in the range of $2.5 {\~}4.5{\mu}s$ under driving frequency range of 10 kHz and 60 kHz, and in the range of $1.5 {\~} 2.5{\mu}s$ under driving frequency range of 120 kHz and 180 kHz based on observation of memory coefficient, and wall voltage as well as luminous efficiency.

Ultrasonic Velocity and Absorption Measurements in an Aqueous Solution of Poly(sodium 4-styrenesulfonate)

  • Rae Jong-Rim
    • Macromolecular Research
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    • 제12권6호
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    • pp.559-563
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    • 2004
  • Both the ultrasonic velocity at 3 MHz and the absorption coefficient in the frequency range from 0.2 to 2 MHz were measured for aqueous solutions of poly(sodium 4-styrenesulfonate) over the concentration range from 5 to $25\%$ (by weight). The pulse echo overlap method was employed to measure the ultrasonic velocity over the temperature range from 10 to $90^{\circ}C;$ the high-Q ultrasonic resonator method was used for the measurement of the absorption coefficient at $20^{\circ}C.$ The velocities exhibited their maximum values at ca. 55, 59, 63, 67, and $71^{\circ}C.$ for the 25, 20, 15, 10, and $5\%$ solutions, respectively. The velocity increased with respect to the poly(sodium 4-styrene-sulfonate) concentration at a given temperature. A study of the concentration dependence of the both the relaxation frequency and amplitude indicated that the relaxation at ca. 200 kHz is related to structural fluctuations of the polymer molecules, such as the segmental motions of the polymer chains and that the relaxation at ca. 1 MHz resulted from the proton transfer reactions of the oxygen sites of $SO_3.$ Both the absorption and the shear viscosity increase upon increasing the polymer concentration, but they decrease upon increasing the temperature.