• Title/Summary/Keyword: $P_2O_5$

Search Result 7,243, Processing Time 0.038 seconds

Structure and thermal properties of $SnO_2-B_2O_3-P_2O_5$ glasses ($SnO_2-P_2O_5-B_2O_3$ 유리구조 및 열적 특성)

  • An, Yong-Tae;Choi, Byung-Hyun;Ji, Mi-Jung;Ko, Young-Soo;Kim, Hyung-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.06a
    • /
    • pp.91-91
    • /
    • 2008
  • $SnO_2-B_2O_3-P_2O_5$ system were prepared by melt-quenching technique in the compositional series containing 50, 55 aod 60mol.% of $SnO_2$. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5-25mol.% of $B_2O_3$. For these glasses, thermal expansion coeffient($\alpha$), glass transition temperature(Tg), and glass softening temperature(Ts), were determined. The values a decrease with increasing $B_2O_3$ content, while Tg and Ts increased. The reason for the observed changes is local structure of the glasses. Local structure of the glasses was investigated by Raman and FT-IR measurements, suggesting that the number of bridging oxygens decreased whereas the non-bridging oxygen concentration increased with increasing $SnO_2$ content in the glasses.

  • PDF

Fabrication and Characteristics of $Al_2O_{3p}$/AC8A Composites by Pressureless Infiltration Process (무가압함침법에 의한 $Al_2O_{3p}$/AC8A 복합재료의 제조 및 특성)

  • 김재동;고성위;정해용
    • Composites Research
    • /
    • v.13 no.6
    • /
    • pp.1-8
    • /
    • 2000
  • The fabrication Process of $Al_2O_{3p}$/AC8A composites by pressureless infiltration technique and the effects of additive Mg content and volume fraction of particulate reinforcement on mechanical and wear properties were investigated. It was found that the bending strength decreased with increasing volume fraction of $Al_2O_{3p}$ particles. Whereas hardness increased with volume fraction of $Al_2O_{3p}$ particles. The decrement of strength in case of high volume fraction of $Al_2O_{3p}$ particles was attributed to high porosity level. In terms of additive Mg content, $Al_2O_{3p}$/AC8A composites containing around 5~7wt% of additive Mg indicated the highest strength, and hardness values increased with additive Mg contents. Wear resistance of AC8A alloy were improved by reinforcement of $Al_2O_{3p}$ particles especially at high sliding velocity. Wear property of $Al_2O_{3p}$/AC8A composites and AC8A alloy exhibited different aspects. $Al_2O_{3p}$/AC8A composites indicated more wear loss than AC8A alloy at slow velocity region. However a transition point of wear loss was found at middle velocity region which shows the minimum wear loss and wear loss at high velocity region exhibited almost same value as at slow velocity region, whereas wear loss of AC8A alloy almost linearly increased with sliding velocity. It was found that $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 20% exhibited abrasive wear surface regardless of sliding velocity and $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 40% showed slightly adhesive wear surface at low sliding velocity, and it progressed to severe wear as increasing the sliding velocity.

  • PDF

Influence of $K_{2}O$ - Fertilizer Application on Growth, Yield and Lodging of Paddy Rice

  • Kwon Byung-Sun
    • Plant Resources
    • /
    • v.8 no.1
    • /
    • pp.32-35
    • /
    • 2005
  • This study was conducted to investigate the influence of $K_{2}O$ fertilizer application on growth, yield and lodging resistance of rice. Culm length and panicle length were lowest at the treatment of fertilizer level, $N-P_{2}O_{5}-K_{2}O=16-8-8$ plot but number of panicle, percentage of fruitful culm, $1{\ell}$ grain weights of paddy rice and brown rice, 1,000 grains weight of brown rice, brown rice ratio, yields of paddy rice and brown rice were highest at the treatment of fertilizer level, $N-P_{2}O_{5}-K_{2}O=16-8-8$ kg/10a plot. Bending moment, breaking strength and lodging index were lowest at the treatment of fertilizer level, $N-P_{2}O_{5}-K_{2}O=16-8-8$ kg/10a plot. Judging from the results reported above, an optimum fertilizer level of rice for lodging resistance is most likely be $N-P_{2}O_{5}-K_{2}O=16-8-8$ kg/10a treatment.

  • PDF

Application Of $P_2O_5$-ZnO-RO System With Glass Network Former to Transparent Dielectric ($P_2O_5$-ZnO-RO계에 유리형성제 첨가에 의한 투명유전체의 응용)

  • 차명룡;전재삼;정병해;김형순
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.03a
    • /
    • pp.213-213
    • /
    • 2003
  • 저온소성 가능하며 저 융점유리인 고 투과율의 Pb-free 조성으로서 PDP(Plasma Display panel)의 투명유전체에 응용하고자 P$_2$O$_{5}$-ZnO-RO 계인 인산염 유리의 열적, 광학적성질을 연구하였다. 이 삼원계인 인산염유리계를 PDP의 투명 유전체에 응용하기에는 열적특성에서 문제점이 제기되어, (30-50)P$_2$O$_{5}$ - (20-50)ZnO - (15-45) RO (mol%)계에 유리망목형성제인 A1$_2$O$_3$, SiO$_2$, B$_2$O$_3$등을 첨가하여 열적성질 및 소성후 투광성 등을 조사하였다. 열적특성은 DTA와 TGA를 이용하여 유리전이점(Tg) 및 선팽 창계수(CTE)와 연하점(Ts) 을 측정하였으며, 투광성은 500-58$0^{\circ}C$에서 1시간동안 소성하여 UV-visible spectrometer을 이용하였다 그 결과로, 380-46$0^{\circ}C$의 Tg와 8-$10^{-6}$K의 CTE 및 70-80%의 광투과율을 나타내었다. 이러한 결과는 P$_2$O$_{5}$-ZnO-RO계는 PDP의 투명유전체에 적용하기에는 상당히 높거나 낮은 Tg를 형성하였지만 유리형성제를 수 mol%을 첨가함으로써 적절한 Tg점과 높은 투과율을 얻을 수 있었다.수 있었다.

  • PDF

Preparation and Dissolution Properties of the Trace Elements doped ${K_2}O$-CaO-${P_2}{O_5}$ Glasses (미량원소함유 ${K_2}O$-CaO-${P_2}{O_5}$유리의 제조 및 용출 특성)

  • Lee, Hoi-Kwan;Kang, Won-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.6 no.2
    • /
    • pp.144-148
    • /
    • 2005
  • At the previous papers, we showed that ${K_2}O$-CaO-${P_2}{O_5}$ glasses had a solubility in air so that they could be used for glass fertilizer. In this work, we fabricated the Eco-glass fertilizer containing trace elements of B, Mg, Zn, Fe, Cu, Co, Mo, the needed micronutrients for plants to grow, by a melt-quenching process. The dissolution properties in these glasses were investigated with a pH meter and an ICP analyzer. The trace elements doped glasses showed similar behavior in dissolutions and stability properties with the mother glass without containing trace elements. In addition, the dissolution amount of each trace elements depends on the mother glass composition and the quantity of each trace elements, which determine the dissolving velocity of chemical elements.

  • PDF

Fabrication and Characterization of LPCVD $P_2O_5-SiO_2$ Films for Inegrated Optics (1) -LPCVD of TEOS and TMPite (LPCVD $P_2O_5-SiO_2$ 집적광학박막의 제작 및 특성 연구(1) -TEOS와 TMPite의 LPCVD-)

  • 정환재
    • Korean Journal of Optics and Photonics
    • /
    • v.4 no.3
    • /
    • pp.266-275
    • /
    • 1993
  • We made $P_2O_5-SiO_2$ films on silicon for integrated optics application by low pressure chemical vapor deposition using TEOS (tetraethylorthosilicate) and TMPite (trimethylphosphite) and studied the deposition characteristics. The activation energy of the reaction was changed from 54.6 kcal/mole to 39.2 kcal/mole by incorporating the TMPite into the reaction of TEOS. The deposition rate and the P concentration of films increased in proportion to the flow of TMPite. As the deposition temperature increased, the deposition rate of the films increased but the P concentration decreased. The fabricated films showed the increase of refractive index of 0.0019 per 1 wt% of P concentration. The nonuniformity of films was ${\pm}$7% in thickness and ${\pm}$0.5wt% in P concentration and we showed this'nonuniformity is due to the nonuniform transport of TMPite. The films of more than 10wt% P concentration developed phosphoric acid on its surface when exposed to air for long time.

  • PDF

Synthesis of P2O5-V2O5-ZnO Glass Frit for Laser Sealing of OLED by the Addition of Filler (필러 첨가에 의한 OLED의 레이저 실링용 P2O5-V2O5-ZnO 유리프릿의 제조)

  • Bang, Jae-Chul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.28 no.9
    • /
    • pp.571-576
    • /
    • 2015
  • In this study, we developed a lead-free $P_2O_5-V_2O_5-ZnO$ glass frit for sealing OLED using laser irradiation. The frit satisfied the characteristics required for laser sealing such as low glass transition temperature, low coefficient of thermal expansion (CTE), high water-resistance, and high absorption at the wavelength of the laser beam. Ceramic fillers were added to the glass frit in order to further reduce and match its CTE with that of the commercial glass substrate. The addition of Zirconium Tungsten Phosphate (ZWP) to the frit yielded the most desirable results, reducing the CTE to $45.4{\times}10^{-7}/^{\circ}C$, which is very close to that of the glass substrate ($44.0{\times}10^{-7}/^{\circ}C$). Successful formation of a solid sealing layer was observed by optical and scanning electron microscopy.