• Title/Summary/Keyword: $PP_2$

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Studies for the Sustainable Management of Oyster Farms in Pukman Bay, Korea: Estimate of Primary Production

  • Jeong, Woo-Geon;Cho, Sang-Man;Lee, Sang-Jun
    • Fisheries and Aquatic Sciences
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    • v.12 no.2
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    • pp.111-117
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    • 2009
  • To develop sustainable management strategies for oyster farms in Pukman Bay, Korea, we estimated primary production using a numerical model. Because oysters are filter feeders, estimations of primary production (PP) are essential in developing management strategies. The daily PP ranged from 0.07 to 1.5 gC/$m^2$/d and showed significant spatial variations. The spatial distribution of PP was strongly associated with hydrodynamic features, and distinct patterns were observed in three different regions. In the inner bay, high PP was directly influenced by urban and agricultural sewage. The middle part of the bay had low PP, whereas PP in the outer area was high. PP was relatively low during the main oyster growth season, from late autumn to early winter. These findings represent important information for developing a management model for oyster farms in Pukman Bay.

Study on the Non-isothermal Crystallization Kinetics of Branched Polypropylene (분지형 폴리프로필렌의 비등온결정화 거동 연구)

  • Yoon, Kyung-Hwa;Shin, Dong-Yup;Kim, Youn-Cheol
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.245-250
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    • 2012
  • Branched polypropylenes (PP) with long chain branch were prepared by solid state reaction with three different branching agent of 0.3 wt% content. The chemical structures, non-isothermal crystallization behavior and complex viscosity of the branched PP were investigated by FTIR, DSC, optical microscope, and dynamic rheological measurement. The chemical structure of the branched PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no distinct change in melting temperature in case of PP-D-0-3 and PP-F-0-3, but PP-H-0-3 indicated a decrease in melting temperature. The decrease in melting temperature was interpreted by the fact that the degradation reaction of PP was more dominant than branched reaction, and confirmed by a decrease in complex viscosity. The non-isothermal crystallization behavior of the branched PP was analyzed using by Avrami equation. The Avrami exponent of PP was 3, and the values of the branched PP with DVB and FS were below 3. The activation energy of PP calculated by Kissinger method was 25 kJ/mol, and there were no big difference in activation energies of the branched PPs compared to PP.

Mechanical and thermal properties of Homo-PP/GF/CaCO3 hybrid nanocomposites

  • Parhizkar, Mehran;Shelesh-Nezhad, Karim;Rezaei, Abbas
    • Advances in materials Research
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    • v.5 no.2
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    • pp.121-130
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    • 2016
  • In an attempt to reach a balance of performances in homo-polypropylene based system, the effects of single and hybrid reinforcements inclusions comprising calcium carbonate nanoparticles (2, 4 and 6 phc) and glass fibers (10 wt.%) on the mechanical and thermal properties were investigated. Different samples were prepared by employing twin-screw extruder and injection molding machine. In morphological studies, the uniform distribution of glass fibers in PP matrix, relative adhesion between glass fibers and polymer, and existence of nanoparticles in polymer matrix were observed. $PP/CaCO_3$ (6 phc) as compared to pure PP and PP/GF had superior tensile and flexural strengths, impact resistance and deformation temperature under load (DTUL). $PP/GF/CaCO_3$ (6 phc) composite displayed comparable tensile and flexural strengths and impact resistance to neat PP, while its tensile and flexural moduli and deformation temperature under load (DTUL) were 436%, 99% and $26^{\circ}C$greater respectively. The maximum impact resistance was observed in $PP/CaCO_3$(6 phc). The highest DTUL was perceived in PP hybrid nanocomposite containing 10 wt.% glass fiber and 4 phc $CaCO_3$ nanoparticle.

Synthesis of Amin-type Anion Exchanger from Acrylic Acid Grafted Polypropylene Nonwoven Fabric and Its Ion-exchange Property(II) (아크릴산 그라프트 폴리프로필렌 부직포로부터 아민형 음이온 교환체의 합성 및 이온교환특성(II))

  • Na, Choon-Ki;Park, Hyun-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.9
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    • pp.775-782
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    • 2009
  • PP-g-AA-Am nonwoven fabric, which possess anionic exchangeable function, was prepared by chemical modification of carboxyl (-COOH) group of PP-g-AA nonwoven fabric to amine ($-NH_2$) group using diethylene triamine (DETA). Its adsorption characteristics for anionic nutrients including isotherm, kinetics and co-anions were studied by batch adsorption experiments. Adsorption equilibriums of $PO_4$-P on PP-g-AA-Am fabric were well described by the Langmuir isotherm model, and their adsorption energies were ranged 10.3 kJ/mol indicating an ion-exchange process as primary adsorption mechanism. The adsorption selectivity of PP-g-AA-Am nonwoven fabric for anions under competition with each other was in following order: $SO_4\;^{2-}$>$PO_4\;^{3-}$>$NO_3\;^-$>$NO_2\;^-$. Also, all results obtained from this study indicate that the $PO_4$-P removal capacity of PP-g-AA-Am nonwoven fabric was extremely superior to that of PA308 anion-exchange resin.

Estimation of Optimum PP Fiber Content for the Spalling Control of High Strength Reinforced Concrete Columns (고강도 철근콘크리트 기둥의 폭열제어를 위한 최적의 PP섬유함유량 산정)

  • Kim, In Ki;Yoo, Suk Hyeong;Shin, Sung Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.2
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    • pp.155-163
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    • 2007
  • High Strength Concrete (HSC) has weakness that in a fire, it is spalled and brittles. The phenomenon of spalling is made by water vapor's (resulting from evaporation in the material at over $100{^{\circ}C}$)' being confined in watertight concrete. As the concrete strength increases, the degree of damage caused by the spalling becomes more serious because of the permeability. It is reported that the polypropylene(PP) fiber has an important role in protecting concrete from spalling and the optimum dosage of PP fiber is 0.2%. This study was conducted on the nonreinforced concrete specimens. The high-temperature behavior of high-strength reinforced concrete columns with various concrete strength and various dosage of PP fibers was investigated in this study. The results show that the ratio of unstressed residual strength of columns increases as the concrete strength increases and the ratio of unstressed residual strength of columns increases as the dosage of PP fiber increases from 0% to 0.2%, however, the effect of fiber dosage on residual strength of column barely changes above 0.2%.

Preparation and Physical Properties of Silicone Softner for PP Finish (PP 가공용 실리콘 유연제의 제조와 물성연구)

  • Im, Wan-Bin;Yang, In-Mo;Jung, Choong-Ho;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.2
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    • pp.117-122
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    • 2002
  • A silicone softner (SS-5), a permanent press (PP) finish, was prepared by blending silicone oil KF-96 (as a lubricating component) and beef tallow hardened oil (as a softening component) which was synthesized from fatty polyamide salts. The prepared SS-5 and the PP finishing resin were applied to PP finishing cotton cloth and P/C gingham sample by one-bath method. The properties such as crease recovery, tear strength, and bending resistance were tested. The samples treated with SS-5 and PP finishing resin showed improved properties when comparing with the untreated ones, with the ones treated only with PP finishing resin, with ones treated with commercial PP finishing softners and PP finishing resin. The grades of fabric samples treated with 3% SS-5 were fifth grade in the bending resistance test.

Effect of Styrene and Maleic Anhydride Content on Properties of PP/Pulp Composites and Reactive Extrusion of Random PP (랜덤 PP의 반응압출 및 PP/Pulp 복합체 특성에 대한 스티렌과 무수말레인산 함량의 영향)

  • Lee, Jong Won;Kim, Ji Hyun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.318-323
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    • 2014
  • In order to analyze the effect of maleic anhydride (MAH) content and styrene monomer (SM)/MAH mole ratio on reactive extrusion of maleic anhydride grafted random polypropylenes (MAH-g-rPP), MAH-g-rPPs were prepared by using a twin screw extruder. MAH contents were 0.5, 1.0, 3.0, and 5.0 phr and SM/initiator mole ratio was 0.0, 1.0, and 2.0. Dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C = O) stretching peak at $1700cm^{-1}$ from FT-IR spectrum. The degree of graft reaction increased up to 3.0 phr MAH and showed the optimum value at 1.0 SM/MAH mole ratio from the area ratio of C = O and C-H stretching peak. Thermal and crystallization properties of MAH-g-rPP and PP/MAH-g-rPP/pulp composites were investigated by DSC, TGA, XRD, and POM. There was a decrease in non-isothermal crystallization temperature of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for the fractured surface of PP/MAH-g-PP/pulp composites, MAH content of 1.0 wt% and SM/MAH mole ratio of 1.0 were the optimum formulation as the compatibilizer. The rheological properties of the composites were measured by dynamic Rheometer to compare the processability of the composites with and without compatibilizer. The power law index showed slightly low value at the composites with compatibilizer.

An Experimental Study of Spalling Characteristics of High-Strength Reinforced Concrete Columns with PP Fibers (PP 섬유를 함유한 고강도 철근콘크리트 기둥의 폭열 특성에 관한 실험적 연구)

  • Sin, Sung-Woo;Yu, Suk-Hyeong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.2
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    • pp.83-90
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    • 2006
  • A spalling is defined as the damages of concrete exposed to high temperature during the fire by causing cracks and localized bursting of small pieces of concrete. It is reported that spalling is caused by the vapor pressure and polypropylene(PP) fiber has an important role in protecting from spalling. The characteristics of fire resistance of high-strength reinforced concrete columns with various concrete strength and various contents of PP fiber were investigated in this study. In results, the ratio of unstressed residual strength of columns increases as the concrete strength increases and the ratio of unstressed residual strength of columns exposed to fire decreases as the content of PP fiber increases from 0% to 0.2%.

Optimum PP Fiber Dosage for the Control of Spalling of High Strength Reinforced Concrete Columns

  • Yoo, Suk-Hyeong;Shin, Sung-Woo;Kim, In-Ki
    • International Journal of Concrete Structures and Materials
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    • v.18 no.2E
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    • pp.103-109
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    • 2006
  • Spalling is defined as damages to concrete exposed to high temperature during fire, causing cracks and localized bursting of small pieces of concrete. As the concrete strength increases, the degree of damage caused by spalling becomes more serious due to impaired permeability. It is reported that polypropylene(PP) fiber has an important role in protecting concrete from spalling, and the optimum dosage of PP fiber is 0.2%. However, this study was conducted on non-reinforced concrete specimens. The high-temperature behavior of high-strength reinforced concrete columns with various concrete strength and various quantity of PP fibers is investigated in this study. The results revealed that the ratio of unstressed residual strength of columns increased as the concrete strength increased and as the quantity of PP fiber increased from 0% to 0.2%. However, the effect of PP fiber quantity on residual strength of column was barely above 0.2%.

Effect of Ar+ Ion Irradiation of Polymeric Fiber on Interface and Mechanical Properties of Cementitious Composites

  • Seong, Jin-Wook;Lee, Seung-Hun;Kim, Ki-Hwan;Beag, Young-Whoan;Koh, Seok-Keun;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.430-434
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    • 2004
  • The values of fracture energy and mechanical flexural strength of Fiber Reinforced Cement (FRC) with polypropylene (PP) fiber modified by Ion Assisted Reaction (JAR), by which functional groups were grafted on the surface of PP fiber, was improved about 2 times as those of fracture energy and flexural strength of cement reinforced by untreated PP fiber. PP fiber was irradiated in O$_2$ environment by Ar$\^$+/ ion. The contact angle of PP treated by IAR decreased largely when compared with untreated PP. From this result, we expected that surface energy and interfacial adhesion force of treated PP fiber increased. The strain hardening occurred in the strain-stress curve of FRC including PP treated by IAR when compared with that of FRC with untreated PP. These enhanced mechanical properties might be due to strong interaction between hydrophilic group on modified PP fiber and hydroxyl group in cement matrix. This hydrophilic group on surface modified PP fiber was confirmed by XPS analysis. We clearly observed hydration products that were fixed at modified PP fiber due to the strong adhesion force of interface in cement reinforced modified PP by SEM (Scanning Electron Microscopy) study.