• Title/Summary/Keyword: $OH^-$

Search Result 66,821, Processing Time 0.074 seconds

Analysis of General Ingredient and Amino Acid Contents in Silkworm Feces with Different Extracting Methods and Collecting Time (추출 방법 및 채취 시기를 달리한 잠분추출물의 일반성분 및 아미노산 함량 분석)

  • Sohn, Bong-Hee;Chung, Wan-Tae;Kang, Pil-Don;Ryu, Kang-Sun;Jung, I-Yeon;Kim, Yong-Soon;Kim, Kee-Young;Kim, Mi-Ja;Chung, In-Sick
    • Journal of Sericultural and Entomological Science
    • /
    • v.49 no.2
    • /
    • pp.43-46
    • /
    • 2007
  • Analysis of general ingredients and amino acid content in dried silkworm feces which were extracted with hot water, EtOH, MeOH for developing new income source of rearing farm, seeking high additive value material and industrialization of silkworm feces. In the analysis of general ingredient content by extracting solution, raw protein and ash contents were increased with MeOH, EtOH, hot water. And raw fat showed higher contents by the order of EtOH > MeOH > hot water. The inorganic matter content showed a little difference among collection times of silkworm feces. Hot water was most effective extracting solution for total amino acid, and no significant difference between EtOH and MeOH. According to the time, there were no significant difference in amino acid contents. When extracted with hot water, Glu content was highest content and order of others is Asp > Gly > Ala > Leu > Thr > Ser among 18 amino acids.

Atmospheric Effects on Corrosion of Iron in Borate Buffer Solution (Borate 완충용액에서 철의 부식에 대한 대기의 영향)

  • Kim, Hyun-Chul;Kim, Younkyoo
    • Journal of the Korean Chemical Society
    • /
    • v.56 no.6
    • /
    • pp.673-678
    • /
    • 2012
  • Using potentiodynamic and linear polarization method, the atmospheric effect on the corrosion of iron in borate buffer solution was investigated. The corrosion of iron was heavily influenced by the degree of oxygen concentration. The supply of reduction current was increased by the reduction of dissolved oxygen, and the corrosion potential of iron was shifted to the positive side. The $OH^-$ ion, which was produced through the reduction of either water or oxygen, significantly increased the $OH^-$ ion concentration inside of the electrical double layers of iron electrode, and facilitated the adsorption of $OH^-$ ion on the surface of the iron electrode. The adsorption of $OH^-$ ion on the iron electrode can be explained either by Langmuir isotherm or by Temkin logarithmic isotherm.

A Study on the Effects of $TiO_2$ and $Al(OH)_3$ for ZnO Ceramic Varistor (ZnO Ceramic Varistor에 미치는 $TiO_2$$Al(OH)_3$의 영향)

  • 안영필;김복희
    • Journal of the Korean Ceramic Society
    • /
    • v.19 no.4
    • /
    • pp.287-292
    • /
    • 1982
  • Nonohmic properties of ZnO ceramics with various small amounts of additives were studied in relation to experimental methods, additive contant and sintaring temperature. The kinds of additives used to following chemicals were basic additives ($0.5Bi_2O_3$, $0.3BaCO_3$, $0.5MnCO_3$, $0.5Cr_2O_3$, $0.1KNO_3$), $TiO_2$ and $Al(OH)_3$. Expecially, this study has focused on the effectsof $TiO_2$ and $Al(OH)_3$ in ZnO ceramics with the basic additives. SEM studies indicated that the addition of TiO2 promoted grain growth but retarded grain growth with the addition of $Al(OH)_3$. Also, in the case of calcination of ZnO with $TiO_2$ and ZnO with $Al(OH)_3$ previously, grain size of ZnO with $TiO_2$ was larger and that of ZnO with Al(OH)3 was smaller in comparison to the case with out calcination. From the viewpoint of nonohmic exponent and nonohimic resistance, electrical characteristics of ZnO, $TiO_2$ and the basic additives was more effective than that of ZnO, $Al(OH)_3$ and the basic additives. Nonohmic exponent and nonohmic resistance of ZnO, $TiO_2$ and the basic additives was 11-13 and 40-65 respectively.

  • PDF

OH Emission toward Embedded YSOs

  • Yun, Hyeong-Sik;Lee, Jeong-Eun;Je, Hyerin;Lee, Seokho;Evans, Neal J. II;Wampfler, S.F.
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.38 no.2
    • /
    • pp.64.1-64.1
    • /
    • 2013
  • High energy photons and mechanical energy produced by the process of star formation result in copious FIR molecular and atomic lines, which are important coolants of the system. Photons thermally or mechanically induced could dissociate water in the dense envelope to change relative abundances among the species O, OH, and H2O. Here we analyze OH emission lines toward embedded young stellar objects (YSOs) observed as part of the Herschel open time key program, 'Dust, Ice, and Gas In Time (DIGIT)' in order to study the physical conditions of associated gas and the energy budget loaded on the OH line emission. According to our analysis of the Herschel/PACS spectra, OH emission peaks at the central spaxel in most of sources, but several sources show spatially extended emission structures. In the extended emission sources, the distribution of OH emission is correlated with that of [OI] emission and extended along the outflow directions. Considering the diversity of source properties, ratios between detected OH lines are relatively constant among sources. In addition, each OH line has strong correlation with bolometric luminosity. For detail analyses with rotation diagram and non-LTE LVG model, we present the results from GSS30-IRS1 and Elias29.

  • PDF

The Study of Generation of Adduct and Fragment Ions by LC/TSP/MS (LC/TSP/MS에 의한 이온종들의 생성에 관한 연구)

  • Kim, Yunje
    • Analytical Science and Technology
    • /
    • v.9 no.1
    • /
    • pp.1-12
    • /
    • 1996
  • The thermally labile compounds with hydroxyl group generate the [${MNH_4}^+$] ion, [$MH^+$] and [$MH^+-OH$] ion by ion-molecule reaction in LC/TSP/MS. But these ions create the trouble in the estimation of molecular weight of an unknown compound because the margin of [${MNH_4}^+$] ion and [$MH^+$] ion is same to that of [$MH^+$] ion and [$MH^+-OH$] ion. If it is compensated for the results by using of the $CF_3COOD+NH_4OH$ LC eluent, the molecular weight of analyte will be able to be confirmed. And this study was tried to recognize whether the fragment ions of thermally labile compound are generated by electron impact or by thermal degradation in ion source.

  • PDF

Sintering of $\alpha{\;}-{\;}Al_2O_3$ with NaOH (가성소다를 이용한 $\alpha{\;}-{\;}Al_2O_3$의 소결반응)

  • 김재용;이진수;서완주;박수길;엄명헌
    • Journal of environmental and Sanitary engineering
    • /
    • v.15 no.1
    • /
    • pp.95-101
    • /
    • 2000
  • This study was investigated to the reaction of alumina sintering with alkaline. The soluble $NaAlO_2$ was made after the commercial ${\alpha}-Al_2O_3$ was calcinated with NaOH. The reaction of alumina was carried out to be based on the effects of calcination temperature, time, and the mixing ratio of ${\alpha}-Al_2O_3/NaOH$. The alumina was calcined over $500^{\circ}C$ with NaOH powder after it was sieved with 170/270 mesh. The calcined alumina with NaOH powder was dissolved into $25^{\circ}C$ distilled water and filtrated, and HCI was added to adapt pH 6.5~7.5. The residue was separated with vacuum pump for filtration after it was adapted to proper pH, and aluminum compound was precipitated with $Al(OH)_3$. The investigation was carried out with the variables; the calcination temperature($500-900^{\circ}C$), the calcination time (30~90 min), and the concentration of HCI when leaching(0.5~3.0N) respectively. In this investigation, the main product of ${\alpha}-Al_2O_3$ and NaOH was $NaAlO_2$ and the maximum conversion ratio was 91.4% under the optimum conditions as followed ; the ratio of NaOH/${\alpha}-Al_2O_3$ was 1.5 and the calcination conditions were $800^{\circ}C$ and 90 min.

  • PDF

Fine Structure and Physical Properties of Cotton Fibers and their Fabrics Treated with Liquid Ammonia, NaOH, and NaOH/Liquid Ammonia (액체암모니아, 수산화나트륨, 수산화나트륨/액체암모니아 처리한 면의 미세구조 및 물성)

  • 배소영;이문철;김홍성;이영희;김경환
    • Textile Coloration and Finishing
    • /
    • v.6 no.2
    • /
    • pp.47-54
    • /
    • 1994
  • Cotton fiber, NaOH-mercerized cotton fiber, cotton fabric, and NaOH-mercerized cotton fabric have been treated by liquid ammonia at -33.4$^{\circ}C$. The fine structures, bending properties, tensile strengthes, shrinkages for laundering, and wrinkle recoveries were studied. The treatment of cottons with liquid ammonia brought about the transition of crystal lattice ; transforming cellulose I crystal of original cotton to cellulose I and III crystal, and cellulose II crystal of mercerized cotton to cellulose II and III crystals. The degree of crystallinities were decreased in the order of liquid ammonia>NaOH/liquid ammonia>NaOH-treated cotton. However moisture regain and water absorbency for liquid ammonia-treated cotton were lower than that of NaOH-treated cotton because of a difference in swelling actions of the agents. It seems caused by intermicrofibrillar pores produced in swelling processes. The bending rigidity and bending hysteresis were decreased remarkly by liquid ammonia treatment. Therefore softness and dimensional stability were improved. The liquid amminia and NaOH/liquid ammonia-treated cottons moreover show excellent properties in tensile strength, anti-shrinkage for laundering, and wrinkle recovery.

  • PDF

Preparation of PVC-Al(OH)3 Beads Immobilized Al(OH)3 with PVC and their Adsorption Characteristics for Fluoride Ions from Aqueous Solution (Al(OH)3를 PVC로 고정화한 PVC-Al(OH)3 비드의 제조와 수중의 불소 이온의 흡착 특성)

  • You, Hae-Na;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
    • /
    • v.23 no.5
    • /
    • pp.887-893
    • /
    • 2014
  • In order to remove fluoride ions from aqueous solution, PVC-$Al(OH)_3$ beads were prepared by immobilizing $Al(OH)_3$ with polyvinyl chloride (PVC). The prepared PVC-$Al(OH)_3$ bead was characterized by using SEM, EDS and Zeta potential. Dependences of pH, contact time and initial fluoride concentration on the adsorption of fluoride ions were studied. The optimal pH was in the range of 4~10. The adsorption was rapid during the initial 12 hr, and equilibrium was attained within 72 hr. The adsorption rate of fluoride ions by PVC-$Al(OH)_3$ beads obeyed the pseudo-second-order kinetic model. The maximum adsorption capacity obtained from Langmuir isotherm model was found to be 62.68 mg/g.

Solvolysis of 3-Chloro-1,2-benzisothiazole-1,1-dioxide (pseudosaccharin chloride (3-Chloro-1,2-benzisothiazole-1,1-dioxide (pseudosaccharin chloride)의 가용매 분해반응)

  • In-Sun Koo;Jeong-Ja Kim;Yong-Jin Yoon;Ikchoon Lee
    • Journal of the Korean Chemical Society
    • /
    • v.30 no.3
    • /
    • pp.296-300
    • /
    • 1986
  • The pseudo-first order rate constants have been obtained for the solvolysis of pseudo-saccharinechloride in MeOH-$H_2O$, EtOH-$H_2O$, MeOH-MeCN and MeOH-$(Me)_2$CO solvents mixtures at various temperatures. Values of n and m in the Kivinen and Grunwald-Winstein plots, respectively, have been determined and the Taft's solvatochromic parameters were obtained; based on these solvent effect parameters as well as on the activation parameters it was concluded that reaction proceeds via an $S_N2$ mechanism.

  • PDF

Effect of processing Conditions on $3,400cm^{-1}$ -OH Peak in IR Transmitting Heavy Metal Fluoride Glasses (적외선 투과성 플루오르화 중금속 유리의 $3,400cm^{-1}$ -OH 흡수에 미치는 가공조건의 영향)

  • ;C. T Moynihan
    • Journal of the Korean Ceramic Society
    • /
    • v.21 no.3
    • /
    • pp.231-238
    • /
    • 1984
  • Heavy metal fluoride glasses exhibit considerable promise as high transparency materials from the UV to the IR. These glasses are prepared by fusion of the mixture of metal fulorides($ZrF_4$, $BaF_2$, $LaF_3$ etc) at 800-1, 00$0^{\circ}C$ under the inert$(N_2)$ or reactive ($CCl_4$, $Cl_2$) atmosphere following the casting into glass on cooling. Infrared absorption at the 3, 400 cm-1 -OH peak has been measured as a function of thickness for several ZrF-$BaF_2$-LaF and $HfF_4$-$BaF_2$-$LaF_3$ glasses to separate contributions from bulk and surface -OH. For glasses melted under $CCl_4$ reactive atmosphere the peak is due almost entirely to surface-OH. and melting in a closed reactor was best for removing -OH. In ambient atmosphere the -OH peak exhibited no time dependence over a 30 d period indicating a very small rate of surface attack by atmospheric H2O. Removal of -OH absorption processing was generally easier and more complete for the $BaF_2$/ThF4-glasses than for the $ZrF_4$-or $HfF_4$-based glasses.

  • PDF