• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.53-59
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• 2006

This study is measurement of radicals in gas & light oil diffusion flame focused on burner exit. The goal of this study is to analyse the relationship between flame chemiluminescence($OH^{\ast}$, $CH^{\ast}$, $C_2^{\ast}$) intensities and flame conditions. The investigation performed turbulent diffusion flame of commercial burner in varying the excess air ratio from 1.0 to 1.8. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The effects of excess air ratio and NOx emission characteristics on the radical emission intensities were investigated experimentally.

• Journal of the Korean Society of Industry Convergence
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• 제7권3호
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• pp.265-271
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• 2004

A light collecting probe named Multi-colored Integrated Receiving Optics (MICRO) is experimentally examined to verify its performance. For these purposes, the time-series signals of MICRO probe is compared with those of electro-static probe and light-guided probe by monitoring, for example. such as OH radical chemiluminescence. CH radical band and droplet Mie scattering In addition, the experiment was conducted by using laminar premixed Bunsen flame, turbulent premixed Bunsen flame and premixed spray flame, respectively. It was confirmed that the performance of MICRO probe was very useful and convenient to obtain the chemiluminescence signals from local regions in turbulent premixed Bunsen flame and premixed spray flame.

• Korean Journal of Animal Reproduction
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• 제15권2호
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• pp.149-155
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• 1991

본 실험은 H-Y 항원 유전자 크로닝을 위한 기초연구로서 H-Y 항원의 특성을 규명하기 위하여 친화성 크로마토그래피에 의하여 H-Y 항원을 분리·정제하였다. 정소 추출액을 항체가 결합된 column에 결합시킨 뒤 10% acetic acid로 용출시켰다. 용출된 분획을 모아 농축한 후 HPLC와 SDS-PAGE를 실시하여 H-Y 항원의 분자량은 약 6,7000달톤 임을 알 수 있었으며 isoelectric focusing에 의하여 등전점(pI)은 5.0인 것으로 측정되었다. H-Y 항원에 대한 단일클론항체와 표지항원으로는 H-Y 항원-ABEI(aminobutylethyl isoluminol)를 사용하여 H-Y 항원 정량을 위한 화학발광면역분석법을 개발하였다. 항원항체 반응후 빛의 측정은 NaOH 존재하에서 microperoxidase/H2O2를 이용한 산화반응으로 실시하여 10초간 측정한 빛의 양을 적분하였다. H-Y 항원의 농도와 빛의 양과는 역비례하였으며 감도는 11.8ng/tube 정도이었다.

• Journal of the Korean Society of Propulsion Engineers
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• 제22권1호
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• pp.28-35
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• 2018

In order to analyze the flammability limit and structure of the gaseous methane-gaseous oxygen diffusion flame formed through a shear coaxial injector, combustion experiments were carried out according to the condition of injector recess and propellant mass-flow rate. As a result, it was confirmed that stable anchored flame was observed even at the high oxygen Reynolds number as the propellant momentum flux ratio increased, and that the recess had no significant influence on the flame shape and flammability limit. The anchored flame visualized through a chemiluminescence showed the maximum OH radical emission intensity at a specific position, irrespective of the propellant injection condition, and the radical intensity was greatly reduced by the injector recess.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제33권5호
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• pp.365-372
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• 2009

The influence of combustor pressure on the local reaction characteristics of $CH_4$/air flames was investigated by measurements of local chemiluminescence intensity. Induced flow flames are often applied to the industrial boiler systems and incinerator in order to improve heat transfer and prevent exhaust gas leakage. In order to investigate combustion characteristics in the induced flow pattern, the combustor pressure index($P^*$) was controlled in the range of $0.7{\sim}1.3$ for each equivalence ratio in the present combustion system, where $P^*$ is defined as the ratio of absolute pressure to atmospheric one. Relationship between local reaction intensity and pressure index have been investigated by simultaneous $CH^*$, $C^*_2$ and $OH^*$ intensity measurements. It could be observed that flame length became longer with decreasing $P^*$ from $CH^*$ chemiluminescence intensity of axial direction. The mean value of $C^*_2$ and $CH^*$ chemiluminescence intensities, which indicates reaction intensity in the $CH_4$/air flames, decreased with decreasing pressure index for ${\Phi}{\leq}1$, but increased with decreasing pressure index for ${\Phi}$>1. $C^*_2/CH^*$ intensity ratio, which can be a good marker to demonstrate local equivalence ratio, was almost same for ${\Phi}{\leq}1$ regardless of pressure index change, while they showed high level for lower pressure index for ${\Phi}$>1 conditions.

• Analytical Science and Technology
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• 제21권1호
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• pp.20-24
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• 2008

A chemiluminescence method has been developed to determine vitamin $P_1$ in aqueous solution which is based on the enhancement of the intensity of lucigenin using lucigenin-$H_2O_2$ as chemiluminogenic system. The effects of experimental parameters such as concentrations of lucigenin, pH and concentrations of $H_2O_2$ were studied. The present method allows the determination of vitamin $P_1$ over the range $7.5{\times}10^{-6}{\sim}5.0{\times}10^{-4}mol/L$. The detection limit was $5.7{\times}10^{-7}mol/L$. The relative standard deviation was 0.75 % for 10 determinations of $7.5{\times}10^{-5}mol/L$ vitamin $P_1$. The correlation coefficient of the working curve was 0.9984 (S/N=3).

• Transactions of the Korean hydrogen and new energy society
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• 제28권2호
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• pp.181-189
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• 2017

This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.258-262
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• 2011

The laminar burning velocity in premixed Oxy-CH4 flames was studied in a lab-scale Bunsen burner. $CH^*$ chemiluminescence method and Schliren photography were used. Experimental results were compared with numerical prediction which was calculated with a CHEMKIN 3.7 package with a PREMIX code. Global equivalence ratio of oxy-CH4 mixture was varied from 0.5 to 2.0 in a laminar flow region. The laminar burning velocity was measured as 3.1 m/s for Schlieren photograph and 2.9 m/s for $CH^*$ chemiluminescence technique (angle method).

• Journal of the Korean Society of Combustion
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• 제16권3호
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• pp.33-40
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• 2011

Combustion experiments were conducted at three different fuels ($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the effects of combustor pressure (30 ~ -30 kPa) on combustion charateristics and reaction zone structure. Regardless of the fuels, emission index of CO (EICO) increased with decreasing combustor pressure, and EICO of $C_2H_4$ was mostly affected by changing combustor pressure at subatmospheric pressure. In order to observe reaction zone, $OH^*$, $CH^*$ and ${C_2}^*$ chemiluminescence intensity were measured. The sequence of the chemiluminescence intensity peak position was affected by chemical characteristics of fuels rather than changing combustor pressure. The emission zone thickness of $C_2H_4$ and $C_3H_8$, defined by the full width at half maximum (FWHM) of $CH^*$ intensity profile, were increased with decreasing combustor pressure. however, the thickness of $C_2H_4$ exhibited the opposite tendency due to the characteristics of the fuel as the bond structure.

• Transactions of the Korean Society of Mechanical Engineers B
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• 제33권5호
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• pp.343-348
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• 2009

The present study has experimentally investigated the effects of $CO_2$ diluted oxygen on the structure of swirl-stabilized flame in a lab-scale combustor. The methane fuel and oxidant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for various amount of carbon dioxide addition to the methane fuel and various swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the hot combustion zone increases at the upstream reaction zone because of an increase in the recirculation flow for an increase in swirl intensity. The hot combustion zone is also increased at the downstream zone by recirculation flow because of an increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensities of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of diluted gas in the reaction zone.