• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.79-79
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• 2012

A high temperature and a low temperature plasma process technologies were developed and demonstrated for synthesis, hybrid formation, surface treatment and CVD engineering of nano powder. RF thermal plasma is used for synthesis of spherical nano particles in a diameter ranged from 10 nm to 100 nm. A variety of nano particules such as Si, Ni, has been synthesized. The diameter of the nano-particles can be controlled by RF plasma power, pressure, gas flow rate and raw material feed rate. A modified RF thermal plasma also produces nano hybrid materials with graphene. Hemispherical nano-materials such as Ag, Ni, Si, SiO2, Al2O3, size ranged from 30 to 100 nm, has been grown on graphene nanoplatelet surface. The coverage ranged from 0.1 to 0.7 has been achieved uniformly over the graphene surface. Low temperature AC plasma is developed for surface modification of nano-powder. In order to have a three dimensional and lengthy plasma treatment, a spiral type of reactor has been developed. A similar plasma reactor has been modfied for nano plasma CVD process. The reactor can be heated with halogen lamp.

• Journal of the Korean Vacuum Society
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• v.8 no.4B
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• pp.507-513
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• 1999

8mol%-yttria-stabilized zirconia(YSZ) thin films as oxygen ion conductor were deposited by rf-magnetron sputtering, and the oxygen gas sensors with the structure of $SiO_2$ substrate/Ni-NiO mixed reference layer/Pt/YSZ/Pt were fabricated and their oxygen sensing properties were investigated. The steady-state electro-motive force (EMF) values were measured as a function of oxygen partial pressure ($PO_2;form 1.013\times10^3 \textrm{Pa \;to}\; 1.013\times10^5$Pa) and operating temperature ($300^{\circ}C$ to $700^{\circ}C$). The fabricated YSZ oxygen sensor showed the best oxygen sensing properties at 50$0^{\circ}C$. However, oxygen sensing properties were very low at the temperature lower than 30$0^{\circ}C$ due to the lack of oxygen ion mobility and at the temperature higher than $700^{\circ}C$ due 새 intermixing of materials between the layers. Especially, the YSZ sensor operating at $500^{\circ}C$ and oxygen partial pressure above $1.565\times10^4$Pa showed the oxygen sensing properties close to the values predicted by ideal Nernst equation.

• Journal of the Korean Chemical Society
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• v.31 no.6
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• pp.503-508
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• 1987

The protonation constants of 3,4 : 9,10-dibenzo-1,12-diaza-5,8-dioxacyclotetradecane $(NenOenH_4)$ and stability constants of its transition metal complexes have been determined by the potentiometric titration in 1 : 1 dioxane-water mixture with 0.1 ionic strength at $25^{\circ}C.$ For a given anion system, the stabilitv constants of the complexes are in the order of $Mn^{2+}<\;Co^{2+}\;< Ni^{2+}\;<\;Cu^{2+}\;>\;Zn^{2+}$, which accords with the Williams-Irving series.

• Clean Technology
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• v.23 no.2
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• pp.158-162
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• 2017

$FeCl_3$ solution has been used as an etchant for metal etching such as Fe, Cu, Al and Ni. In the etching process, $Fe^{3+}$ is reduced to $Fe^{2+}$ and the etching efficiency is decreased. Waste $FeCl_3$ etchant has environmental, economic problems and thus the regeneration of the etching solution has been required. In this study, HCl was mixed with the $FeCl_2$ solution and then, $H_2O_2$, $NaClO_3$ were added into the mixed solution to oxidize the $Fe^{2+}$. During the oxidation process, oxidation-reduction potential (ORP) was measured and the relationship between ORP and oxidation ratio was investigated. The ORP is increased with increasing the concentration of $H_2O_2$ and $NaClO_3$, and then the ORP is decreased with oxidation progress. Such a behavior was in good agreement with Nernst's equation. Also, the oxidation efficiency was about 99% when a sufficient amount of HCl and $H_2O_2$, $NaClO_3$ were added.

• Progress in Superconductivity and Cryogenics
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• v.5 no.3
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• pp.11-14
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• 2003

The detailed conditions of dc-sputtering for depositions of yttria-stabilized ZrO$_2$ (YSZ) films were investigated, while the films were grown on the CeO$_2$ template layers on biaxially textured Ni-tapes. The window of oxygen pressures for proper growth of YSZ films, which was dependent on sputtering powers, was determined by sufficient oxidations of the YSZ films and the de-oxidation of the target surface, which was required for rapid sputtering. The window turned out to be fairly wide under certain values of argon pressure. When the sputtering power was raised, the deposition rate increased without narrowing the window. The fabricated YSZ films showed good texture qualities and surface morphologies.

• Journal of the Korean Chemical Society
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• v.36 no.6
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• pp.914-918
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• 1992

The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001M $M(NO_3)_2$ (M = $Mn^{2+}$, $Co^{2+}$, $Ni^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Sr^{2+}$, $Cd^{2+}$, $Pb^{2+}$) (2) a toluene membrane containing 0.02M ligand (DB$N_3O_2$, DB18C6) and the surfactant span 80 (sorbitan mono oleate) (3% v/v) and (3) aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of metal ions from the source phase as a function of time. Cation transport rates for various two component equimolar mixture of metal ions were determinded. $Cd^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution.

• Journal of the Korean Ceramic Society
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• v.41 no.8
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• pp.623-627
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• 2004

Phase formation and electrical conduction behavior of Ba-doped LaBaGa $O_4$ layered perovskite were studied. Orthorhombic single phase of $K_2$Ni $F_4$-type structure was observed for the composition range of 0$\leq$x$\leq$0.2 in the La$\_$1＋x/Ba$\_$1＋x/Ga $O_4$$\_$4-$\delta$/ system by X-ray analysis. In the dry atmosphere, La$\_$0.8/Ba$\_$1.2/Ga$\_$3.9/ exhibited mixed conduction of oxygen ion and hole (p-type) at high p( $O_2$). However, in water vapor containing atmosphere, it showed proton conduction due to the incorporation of water into oxygen vacancies. As the temperature decreased, the contribution of proton conductivity to the total conduction increased and proton conduction was dominant below 350$^{\circ}C$. The activation energy for proton conduction was calculated as 0.72 eV.

• Proceedings of the Korean Magnestics Society Conference
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• 2002.12a
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• pp.30-31
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• 2002

100 Gbit/in$^2$ 이상의 자기기록밀도를 달성하기 위해서는 재생헤드로 사용되고 있는 스핀밸브의 자기저항비가 10% 이상을 가지면서 열적 특성이 우수해야 한다. 현재까지 연구되어진 스핀밸브 구조 중 NiO([,2,3], $\alpha$-Fe$_2$O$_3$[4]등의 산화물 반강자성 층을 사용한 스핀밸브의 경우 기본 스핀밸브 구조를 사용하고도 이미 20% 이상의 자기저항비를 달성하였다. 이러한 높은 자기저항비는 절연층인 산화물 반강자성층과 금속 자성층 계면에서 일어나는 전자의 스펙큘라 반사(specular reflection)로부터 기인한다고 보고하고 있다.[2] (중략)

• Journal of Hydrogen and New Energy
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• v.34 no.6
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• pp.587-593
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• 2023

This research project focused on the production of hydrogen through ammonia decomposition reactions while investigating how the reactivity of this process varies when employing different catalysts. Several metal oxide supports (Al₂O₃, La₂O₃, CeO₂) were utilized as catalysts, with active metals from both the transition metal group (Co, Ni, Fe, Cr, Cu) and the noble metal group (Ru, Rh, Pd, Pt) impregnated onto these supports. Furthermore, the study examined how the reactivity evolves with changes in reaction temperature when employing the prepared catalysts. Additionally, the research delved into the distinctive activation energies associated with each of the catalysts. In this research, In the noble metal catalyst system, the order of high activity for ammonia decomposition reaction to produce hydrogen is Ru > Rh > Pt ≈ Pd. In the transition metal catalyst system, the order of high activity is Co > Ni > Fe > Cr > Cu.

• Journal of the Korean Ceramic Society
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• v.29 no.3
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• pp.177-182
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• 1992

The effect of heat-treatment temperature on the microwave absorbing properties was investigated in Ni0.8Zn0.2Fe2O4 specimens. The composite specimens were prepared by modling and curing the mixture of prereacted ferrite powder and silicone rubber. The measurement of complex permeability and permittivity was made by the reflection/transmission method. The most sensitive material constants with heat-treatment temperature is the imaginary (loss) component of permeability. The higher the heat-treatment temperature, the greater the magnetic loss. The composite specimens with high magnetic loss exhibited superior microwave absorbing properties. The quantitative estimation of microwave absorbing properties were made by plotting the observed material constants on the calculated solution map of impedance-matching.