• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.301-308
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• 2004

The methane reforming with $CO_2$ and steam for manufacture of synthesis gas over $Ni/ZrO_2$ catalyst was investigated. Mixed reforming carried out $CO_2$ dry reforming with $O_2$ and steam for development of DME process in pilot plant. To improve a catalyst deactivation by coke formation, the mixed reforming added carbon dioxide and steam as a oxidizer of the methane reforming was suggested. The result of experiments over commercial catalyst in $CO_2$ dry reforming has shown that the catalyst activity decrease rapidly after 20 hours. In case of $NiO-MgO/Al_2O_3$ catalyst, the deactivation of 20 percent after 30 hours was occurred. The activity of Ni/C catalyst still was not decreased dramatically after 100 hours. The effect of $H_2$ reforming with steam over $Ni/CO_2$ catalyst obtained the optimal conversion of methane and carbon dioxide, and could be produced synthesis gas at ratio of $H_2/CO$ under 1.5.