• Title/Summary/Keyword: $Nb_2_O3$

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The Aerosol Characteristics of Utrasonic Nozzle on the Driving Circuits (구동회로에 따른 초음파 노즐의 분무 특성)

  • 이수호;민석규;윤광희;류주현;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1005-1009
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    • 2001
  • The application of the ultrasonic nozzle has been extended because it is possible atomization of liquid material. In this study, the driving characteristics of the ultrasonic nozzle on the driving circuit were investigated. And the characteristics of the ceramic oscillator were investigated for the temperature stability. The ceramic oscillator were made the Pb[(Sb$\sub$1/2/,Nb$\sub$1/2/)$\sub$0.035/-(Mn$\sub$1/3/Nb$\sub$2/3/)$\sub$0.065/- (Zr$\sub$x/Ti$\sub$l-x/)$\sub$0.9/]O$_3$with mole ratio of Zr/Ti. The ceramis oscillator were need the curie temperature of the over 300[$^{\circ}C$] for the temperature stability. When the Zr/Ti ratio was 49/51, it's curie temperature is 322[$^{\circ}C$] and the electromechanical coupling factor(k$\sub$p/) and mechanical quality factor(Q$\sub$m/) showed the values of 0.555, 1,214, respectively The resonance frequency of ceramic oscillator were from 40KHz to 45KHz. So that, the driving circuit were made a possibility that the frequency are variable. The driving current of ultrasonic nozzle showed the value of maximum 80[mA]. Also, The surface temperature of ceramic oscillator showed 80[$^{\circ}C$] at driving time 10[min]. We knew that the ultrasonic nozzle had stabile driving above 10[min.].

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The Design and Driving Characteristics of Piezoelectric Ceramic Oscillator for Spraying of Liquid Material (액체 연료의 분무를 위한 압전 세라믹 진동자의 설계 및 동작 특성)

  • Lee, S.H.;Seok, J.Y.;Ryu, G.H.;Kim, H.G.;Kim, J.G.;Yoo, J.H.;SaGong, G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.686-689
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    • 2002
  • The application of the ultrasonic nozzle has been extended because it is possible atomization of liquid material. In this study, the characteristics of the ultrasonic nozzle and ceramic oscillator were investigated. The oscillator for the ultrasonic nozzle were made piezoelectric ceramic of $Pb[(Sb_{1/2}Nb_{1/2})_{0.035}-(Mn_{1/3}Nb_{2/3})_{0.065}-(Zr_{0.49}Ti_{0.51})_{0.90}]O_3$. The electromechanical coupling factor$(k_p)$ and mechanical quality factor$(Q_m)$ showed the values of 0.555, 1,214 respectively when the Zr/Ti ratio was 49/51. Moreover, this oscillator will have the temperature stability because it's curie temperature is $322[^{\circ}C]$. The driving current of ultrasonic nozzle showed the value of 80[mA] when the driving time was 10[min.]. Also, The surface temperature of ceramic oscillator showed $80[^{\circ}C]$ at driving time 10[min.] We knew that the ultrasonic nozzle had stabile driving above 10[min.].

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Phase Transition of $TiO_2$ prepared by HPPLT (저온균일침전법에 의해 제조된 $TiO_2$의 상변화)

  • Hwang, Du-Seon;Lee, Nam-Hui;Lee, Gang;Kim, Seon-Jae
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.208-208
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    • 2003
  • 저온균일침전법(HPPLT)으로 제조된 TiO$_2$나노분말은 10$0^{\circ}C$이하의 온도에서 rutile상을 얻을 수 있다. 또한, rutile에서 anatase로의 상변화는 합성시간, 가열속도, 반응온도 그리고 음이온 첨가에 의해 일어난다고 보고되어졌지만, 금속양이온들에 의한 상변화는 알려진 바가 없다. 따라서, 다양한 양이온을 첨가하여 저온균일침전법에서 TiO$_2$의 상변화가 어떻게 일어나는지를 조사하였다. 출발원료인 TIC1$_4$를 사용하여 가수분해하여 0.67M의 TiOCl$_2$을 얻었다. 얻어진 TiOCl$_2$ 수용액에 각각 0.01M의 금속염화물(ZrOCl$_2$, NiCl$_2$, CuCl$_2$, FeCl$_3$, AlCl$_3$ 그리고 NbCl$_{5}$)을 첨가한 후 반응기에 넣고 10$0^{\circ}C$에서 4시간동안 가열하였다 가열한 후 얻어진 침전물에 NaOH 수용액을 이용하여 PH 7-8로 중화한 후 증류수로 Cl$^{-}$이온이 제거될 때까지 충분히 세척하였다. 세척된 침전물을 105$^{\circ}C$에서 24h동안 건조하여 분말을 얻었고, rutile에서 anatase로의 상변화특성을 관찰하기 위하여 XRD, SEM, TEM, ICP 분석을 실시하였다.

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Geochemical and Nd-Sr Isotope Studies for Foliated Granitoids and Mylonitized Gneisses from the Myeongho Area in Northeast Yecheon Shear Zone (예천전단대 북동부 명호지역 엽리상 화강암류와 압쇄 편마암류에 대한 지구화학 및 Nd-Sr 동위원소 연구)

  • Kim, Sung-Won;Lee, Chang-Yun;Ryu, In-Chang
    • Economic and Environmental Geology
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    • v.41 no.3
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    • pp.299-314
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    • 2008
  • The NE-trending Honam shear zone is a broad, dextral strike-slip fault zone between the southern margin of the Okcheon Belt and the Precambrian Yeongnam Massif in South Korea and is parallel to the trend of Sinian deformation that is conspicuous in Far East Asia. In this paper, we report geochemical and isotopic(Sr and Nd) data of mylonitic quartz-muscovite Precambrian gneisses and surrounding foliated hornblende-biotite granitoids near the Myeongho area in the Yecheon Shear Zone, a representative segment of the Honam Shear Zone. Foliated hornblende-biotite granitoids commonly plot in the granodiorite field($SiO_2=61.9-67.1\;wt%$ and $Na_2O+K_2O=5.21-6.99\;wt%$) on $SiO_2$ vs. $Na_2O+K_2O$ discrimination diagram, whereas quartz-muscovite Precambrian orthogneisses plot in the granite field. The foliated hornblende-biotite granitoids are mostly calcic and calc-alkalic and are dominantly magnesian in a modified alkali-lime index(MALI) and Fe# [$=FeO_{total}(FeO_{total}+MgO)$] versus $SiO_2$ diagrams, which correspond with geochemical characteristics of Cordilleran Mesozoic batholiths. The foliated hornblende-biotite granitoids have molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 0.89 to 1.10 and are metaluminous to weakly peraluminous, indicating I type. In contrast, Paleoproterozoic orthogneisses have peraluminous compositions, with molar ratios of $Al_2O_3/(CaO+Na_2O+K_2O)$ ranging from 1.11 to 1.22. On trace element spider diagrams normalized to the primitive mantle, the large ion lithophile element(LILE) enrichments(Rb, Ba, Th and U) and negative Ta-Nb-P-Ti anomalies of foliated hornblende-biotite granitoids and mylonitized quartz-muscovite gneisses in the Yecheon Shear Zone are features common to subduction-related granitoids and are also found in granitoids from a crustal source derived from the arc crust of active continental margin. ${\varepsilon}_{Nd}(T)$ and initial Sr-ratio ratios of foliated hornblende-biotite granitoids with suggest the involvement of upper crust-derived melts in granitoid petrogenesis. Foliated hornblende-biotite granitoids in the study area, together with the Yeongju Batholith, show not changing contents of specific elements(Ti, P, Zr, V and Y) from shear zone to the area near the shear zone. These results suggest that no volume changes and geochemical alterations in fluid-rich foliated hornblende-biotite granitoids may occur during deformation, which mass transfer by fluid flow into the shear zone is equal to the mass transfer out of the shear zone.

Design of Piezoelectric Acoustic Transducer (압전세라믹 발음체의 설계)

  • 홍성원
    • Journal of the Microelectronics and Packaging Society
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    • v.2 no.1
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    • pp.69-75
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    • 1995
  • 압전세라믹스를 제조하여 발음체 소자의 두께 직경등의 칫수 변화에 따른 압전발을 체 소자의 전기적 특성 및 압전세라믹스와 금속진동판의 상관관계를 조사하고 공명용 수지 case등을 고려하여 공진 주파수에서 효율좋은 음을 발생시킬수 있는 압전발음체를 설계하였 다. 본 실험에서 사용딘 압전세라믹스 (Pb0.95Sr0.05)(Zr0.53Ti0.47)O3+0.8wt%Nb2O5의 특성은 전 기기계 결합계수(KP)가 69%이며 기계적 품질계수(Qm)은 87 비유전율은 2100 tan$\delta$는 0.016이었다. 금속진동판의 공진주파수는 사용되는 재료의 stiffness와 관계가 있고 주파수 -impedance 특성은 재질의 음속, 밀도, Young율 등에 크게 의존하였다. 주파수 대역 2.0~ 2.2khz에서 공진시키기 위한 공명체의 설계에서 압전세라믹스의 외경과 두께가 각각 14mm, 0.1mm 이고 금속진동판의 그것이 각각 20mm, 0.1mmdlfEo 공명기는 방음공의 직경이 3.0mm, cavity의 직경이 18.5mm, cavity의 높이가 4.5mm의 구조로 설계되었을때가 최적조 건이었다.

Electrical Characteristics of the High Power Piezoelectric transformer Using PSN-PZT system ceramics (PSN-PZT계 세라믹스를 이용한 고출력 압전 트랜스포머의 전기적 특성)

  • 이용우;류주현;윤광희;정회승;서성재;김종선
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.4
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    • pp.286-293
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    • 2000
  • In this paper we investigated the structural dielectric and piezoelectric properties of 0.03Pb(Sb$\_$1/2//Nb$\_$1/2/)-0.97Pb(Zr$\_$0.495//Ti$\_$0.505/)O$_3$+0.5 wt% excess PbO + wt% MnO(X=0, 0.1, 0.3, 0.5, 0.7) ceramics to develop the high-power piezoelectric transformer. The piezoelectric transformers with dimension of 27.5$\times$27.5$\times$2.5[mm$^3$]were fabricated and their electrical properties were measured. Maxima of piezoelectric properties such as electro-mechanical coupling factor of 0.534 and mechanical quality factor of 1487 were obtained for the PSN-PZT with 0.3wt% MnO. voltage step-up ratios of piezoelectric transformers at 500[Ω]and no load were 0.78, 12.82, respectively. The maximum efficiency of piezoelectric transformer was 98.6% at 800[Ω]. While the 14W fluorescent lamp were driven by the piezoelectric transformer for more than 20[min], increment of temperature in the piezoelectric transformer was 7[$\^{C}$].

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Transparent Nano-floating Gate Memory Using Self-Assembled Bismuth Nanocrystals in $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMN) Pyrochlore Thin Films

  • Jeong, Hyeon-Jun;Song, Hyeon-A;Yang, Seung-Dong;Lee, Ga-Won;Yun, Sun-Gil
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.20.1-20.1
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    • 2011
  • The nano-sized quantum structure has been an attractive candidate for investigations of the fundamental physical properties and potential applications of next-generation electronic devices. Metal nano-particles form deep quantum wells between control and tunnel oxides due to a difference in work functions. The charge storage capacity of nanoparticles has led to their use in the development of nano-floating gate memory (NFGM) devices. When compared with conventional floating gate memory devices, NFGM devices offer a number of advantages that have attracted a great deal of attention: a greater inherent scalability, better endurance, a faster write/erase speed, and more processes that are compatible with conventional silicon processes. To improve the performance of NFGM, metal nanocrystals such as Au, Ag, Ni Pt, and W have been proposed due to superior density, a strong coupling with the conduction channel, a wide range of work function selectivity, and a small energy perturbation. In the present study, bismuth metal nanocrystals were self-assembled within high-k $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMN) films grown at room temperature in Ar ambient via radio-frequency magnetron sputtering. The work function of the bismuth metal nanocrystals (4.34 eV) was important for nanocrystal-based nonvolatile memory (NVM) applications. If transparent NFGM devices can be integrated with transparent solar cells, non-volatile memory fields will open a new platform for flexible electron devices.

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Fabrication of λ/2 Phase Plates for Optical Pickup Using a Proton Exchanged LiNbO$_{3}$ (양자 교환된 리튬나오베이트를 이용한 광 픽업용 λ/2 파장판 제작)

  • Son, Gyeong-Rak;Kim, Gwang-Taek;Kim, Yeong-Jo;Song, Jae-Won;Park, Gyeong-Chan;Kim, Jin-Yong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.4
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    • pp.38-44
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    • 2000
  • In this paper, we have been fabricated λ/2 phase plates lot an optical pick-up using a blue violet laser diode by employing proton exchange and wet etching in LiNbO$_{3}$. Their functions and fabrication processes are described in detail. It is established the optimal fabrication conditions through the experimental results. The device characteristics are measured by the Mach-zender interferometer which is composed of the optical components and 632.8nm He-Ne laser. The measured phase error was +5$^{\circ}$~ -6$^{\circ}$(within 3%). This phase plate could be applied an useful device to improve the resolution and the stability of the optical pick-up which has a blue violet laser diode as an optical source.

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Electro-mechanical properties of Multilayer Ceramic Actuators (적층형 세라믹 액츄에이터의 전기-기계거동)

  • 정순종;고중혁;송재성;홍원표;최원종
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.04a
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    • pp.478-481
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    • 2004
  • This study presents the combined effect of electric Held application and mechanical compressive stress loading on deformation in a multilayer ceramic actuator, designed with stacking alternatively 0.2(PbMn$\_$1/3/Nb$\_$2/3/O$_3$)-0.8(PbZr$\_$0.475/Ti$\_$0.525/O$_3$) ceramics and Ag-Pd electrode. The deformation behaviors were thought to be attributed to relative 180$^{\circ}$domain quantities which is determined by pre-loaded stress and electric field. The non-linearity of piezoelectricity and strain are dependent upon the young's modulus resulting from the domain reorientation.

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Dielectric Relaxation in PMN-PT Relaxor Ferroelectrics under Weak and Strong Electric Field (완화형 강유전체 PMN-PT계에서 약전계 및 강정계 조건에서의 relaxation 거동)

  • Park, Jae-Hwan;Kim, Yun-Ho;Park, Sun-Ja
    • Korean Journal of Materials Research
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    • v.8 no.2
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    • pp.95-98
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    • 1998
  • 완화형 강유전체인 0.9MPb*Mg$_{1}$3/Nb$_{2}$3/)O$_{3}$-0.1PbTiO$_{3}$에서 강유전-상유전 상전이에 수반되는 relaxation거동을 살펴보기위해 낮은 전계에서 측정된 유전특성과 높은 전계에서 측정된 전계유기 분극 거동 등을 조사하였다. -50-9$0^{\circ}C$의 상전이 온도범위에 걸쳐 1V/mm의 낮은 전계에서 측정된 유전특성의 온도의존성을 구하고 수 kVmm의 강전계하에서 발생된 분극의 온도의존성을 관찰하였다. 이 모든 결과들은 Vogel-Fulcher관계식에 비교적 정확하게 일치되었으며 그 결과 T$_{f}$ 는 294.6˚K로 나타났다. 본 연구결과를 통하여 Vogel-Fulcher관계식에 의한 주파수 의존성은 낮은 전계하에서의 유전특성 뿐 아니라 강전계하에서의 여러물성들도 동일하게 적용되는 것을 확인할 수 있었다.

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