• 정보와 통신
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• 제34권2호
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• pp.20-26
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• 2017

본고에서는 사물인터넷 시대에 다양한 지능형 서비스를 제공하기 위한 Sensing Data들을 수집하고, 이를 분석하여 새로운 응용 분야에 적용할 수 있는 Platform 에 대해서 알아본다. 구체적으로, 최근 해외의 주요 4가지 사례를 가지고 기업 및 개인에게 다양한 형태로 서비스를 제공하는 Platform에 대해 자세히 알아보며, 여러 분야의 글로벌 기업에서 다양한 서비스로 활용 되고 있다는 동향을 파악할 수 있다. 이것을 바탕으로 국내에서도 사물인터넷을 통한 다양한 산업분야의 정보들과 해외의 다양한 산업의 Data들을 통합하고 관리할 수 있는 체계적인 지능형 Platform에 대해 알아본다.

• Journal of Electrochemical Science and Technology
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• 제9권4호
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• pp.282-291
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• 2018

The pristine fluorine-doped $SnO_2$ (abbreviated as FTO) inverse opal (IO) was developed using a 410 nm polystyrene bead template. The nanolayered copper tungsten oxide ($CuWO_4$) was decorated on the FTO IO film using a facile electrochemical deposition, subsequently followed by annealing at $500^{\circ}C$ for 90 min. The morphologies, crystalline structure, optical properties and photoelectrochemical characteristics of the FTO and $CuWO_4$-decorated FTO (briefly denoted as $FTO/CuWO_4$) IO film were investigated by field emission scanning electron microscopy, X-ray diffraction, UV-vis spectroscopy and electrochemical impedance spectroscopy, showing FTO IO in the hexagonally closed-pack arrangement with a pore diameter and wall thickness of about 300 nm and 20 nm, respectively. Above this film, the $CuWO_4$ was electrodeposited by controlling the cycling number in cyclic voltammetry, suggesting that the $CuWO_4$ formed during 4 cycles (abbreviated as $CuWO_4$(4 cycles)) on FTO IO film exhibited partial distribution of $CuWO_4$ nanoparticles. Additional distribution of $CuWO_4$ nanoparticles was observed in the case of $FTO/CuWO_4$(8 cycles) IO film. The $CuWO_4$ layer exhibits triclinic structure with an indirect band gap of approximately 2.5 eV and shows the enhanced visible light absorption. The photoelectrochemical (PEC) behavior was evaluated in the 0.5 M $Na_2SO_4$ solution under solar illumination, suggesting that the $FTO/CuWO_4$(4 cycles) IO films exhibit a photocurrent density ($J_{sc}$) of $0.42mA/cm^2$ at 1.23 V vs. reversible hydrogen electrode (RHE, denoted as $V_{RHE}$), while the FTO IO and $FTO/CuWO_4$(8 cycles) IO films exhibited a $J_{sc}$ of 0.14 and $0.24mA/cm^2$ at $1.23V_{RHE}$, respectively. This difference can be explained by the increased visible light absorption by the $CuWO_4$ layer and the favorable charge separation/transfer event in the cascading band alignment between FTO and $CuWO_4$ layer, enhancing the overall PEC performance.

• Bulletin of the Korean Chemical Society
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• 제23권1호
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• pp.81-85
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• 2002

A new di-N-cyanoethylated 14-membered tetraaza macrocycle 1,8-bis(2-cyanoethyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane $(L^2)$ and its nickel(II) complex $[NiL^2(OAc)]^+$ have been prepared. The square-planar complex $[NiL^2](C IO_4)_2$ can be prepared by addition of $HClO_4$ to a hot aqueous solution of $[NiL^2(OAc)]^+$ The Ni-N (tertiary amino group) bond distances $(2.008{\AA})$ of $[NiL^2](C IO_4)_2$ are relatively long, and the complex exhibits a d-d transition band at unusually long wavelength (ca. 515 nm). The complex $[NiL^2](C IO_4)_2$ rapidly reacts with acetate ion or ethylenediamine (en) to produce $[NiL^2(OAc)]^+$ or [Ni(en)_3]^{2+}$, respectively, and is readily decomposed in NaOH (0.01 M) solution. The chemical properties of $[NiL^2]^{2+}$ as well as its synthetic procedure are quite different from those for other related 14-membered tetraaza macrocyclic complexes. Effects of the N-cyanoethyl and C-methyl groups on the properties of $L^2$.

• Journal of Microbiology and Biotechnology
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• 제14권4호
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• pp.658-664
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• 2004

To find a new utilization of rice bran, nine higher fungi were examined for the production of exo-biopolymer with macrophage stimulating activity from rice bran. Among the exo-biopolymers produced from submerged cultures, Lentinus edodes showed the highest activity, followed by Grifola frondosa, Schizophyllum commune, and Coriolus versicolor. L. edodes also had the most potent macrophage stimulating activity in a liquid culture rather than in a solid culture. In order to improve rice bran utilization and the yield of exo-biopolymer with macrophage stimulating activity, the treatment of Rapidase effectively increased the macrophage stimulating activity (about 30% increase), whereas the other enzymes (Econase, Viscozyme, Ultraflo, Celluclast, and Thermylase) treatments did not increase the macrophage stimulating activity. Exo-biopolymer with macrophage stimulating activity from L. edodes contained mainly neutral sugars (58.7%) with considerable amounts of uronic acid (32.2%) and a small amount of proteins (9.1%). Component sugars of exo-biopolymer consisted of mainly arabinose, galactose, glucose, mannose, and xylose (0.95:0.81:0.96:1.00:0.39, respectively). When the exo-biopolymer was treated with $NaIO_4, NaClO_2$, and pronase, the $NaClO_2$ treatment and pronase digestion had little effect, whereas $NaIO_4$ oxidation significantly decreased the macrophage stimulating activity (47.6% reduction at $100\mug/ml$). Therefore, the carbohydrate moiety in exo-biopolymer from L. edodes plays an important role in the expression of the macrophage stimulating activity.

• 한국식품과학회지
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• 제33권1호
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• pp.135-141
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• 2001

십전대보탕의 10가지 구성 천연물을 열수추출하여 장관면역 활성을 비교 검토한 결과, 창출(Atractylodes lancea DC., ALR)과 인삼(Panax ginseng C.A. Meyer, PG)에서는 높은 활성을 나타내었으나 약한 활성을 갖는 황기(Astragalus membranacues, ASR)와 당귀(Angelica aculiloba Kitagawa, AR)를 제외하고는 어떤 생약에서도 거의 활성을 갖지 않았다. 한편 이러한 활성을 가진 생약(ALR, PG와 ASR) 중에서도 특히 ALR만이 종류, 생산지 및 육종조건에 관계없이 항상 일정하게 높은 활성을 보여주어 창출의 열수추출물 획분(ALR-0)이 십전대보탕의 장관면역 활성에 중요하게 관여하는 시료로 선정되었다. ALR-0 획분은 다시 용매별로 분획되어 메탄올-가용성 획분(ALR-1), 메탄올-불용성/에탄올-가용성 획분(ALR-2) 및 조다당 획분(ALR-3)으로 조제되었으며 이들의 활성을 측정한 결과, 단지 ALR-3 획분만이 Peyer's patch를 통한 골수세포의 증식을 활성화시키는 장관면역 활성을 시료농도에 의존적으로 나타내었으며 그 외의 획분에는 활성이 거의 없었다. 한편 ALR-3 획분을 $NaIO_4,\;NaClO_2$ 및 pronase로 처리한 후 활성을 측정한 결과, 모든 처리군에서 활성이 감소되었으며 특히 periodate 산화에 의해 심한 활성감소를 보였다. 이러한 결과를 토대로 십전대보탕의 장관면역 활성은 10종의 생약 중에서도 특히 창출이 중요하게 활성에 관여하는 것으로 보이며 다양한 용매별 분획을 통해 저분자보다는 에탄올에 침전된 고분자가 주요 함유물질인 조다당 획분이 장관면역 활성에 관여하는 것으로 추정되었다. 또한 periodate 산화에 의해 활성이 크게 감소되는 것으로 보아 주로 다당류가 창출의 장관면역에 중요한 활성물질인 것으로 생각된다.

• 한국식품영양학회지
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• 제20권4호
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• pp.349-355
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• 2007

Periodate-oxidized soluble starch was reacted with papain at pH 4.0, pH 7.0, and pH 9.7, and an oxidized soluble starch-papain conjugate was produced. When compared with native papain, the specific activity decreased to 60%, in both the modified papain reacted with 0.4% $NaBH_4$ and in the modified papain not reacted with $NaBH_4$. The specific activity decreased to 70% in the modified papains reacted with 1.5% $NaBH_4$ and 4.0% $NaBH_4$, respectively. The reduction by $NaBH_4$ did not have an effect in the thermal stability of either the modified or nonmodified papain. An activity of 54.7% remained in the papain modified at pH 4.0, which was incubated at $80^{\circ}C$ for 40 min. The papains modified at pH 7.0 and pH 9.7 and incubated for 40 min at two different temperatures, respectively, were stable to $60^{\circ}C$, and at $80^{\circ}C$ their activities at 56.3% and 44.1 %, respectively. The modified papain's thermal stability pattern was similar to that of native papain, with no increase in its statbility. In the range of pH $2.0{\sim}13.0$, the stability of the papain modified at pH 4.0 decreased greatly between pH $3.0{\sim}5.0$, but it was similar to the native papain at other pH values. The stability of the papain modified at pH 7.0 showed a similar pattern to the native papain at pH $2.0{\sim}6.0$, while its stability increased when moving into the alkali pH range. The papain modified at pH 9.7 also had increased stability, when moving into the alkali range. The results of Hammerstein milk casein, which was reacted with the papains modified at pH 4.0, pH 7.0, and pH 9.7, respectively, and analyzed by FPLC, showed different peaks according to the different modification pHs, and the greatest peak differences were observed with the modification at pH 9.7.

• Biomolecules & Therapeutics
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• 제5권2호
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• pp.107-109
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• 1997

For metabolic study of pinusolide, a naturally occurring platelet activating factor antagonist, a synthetic method for preparation of radiolabeled pinusolide was studied. Pinusolide was first oxidized with $OsO_4/NaIO_4 $to 17-nor-8-oxo compound (2), which was subsequently converted to pinusolide by treatment with the Lombardo reagent $(Zn/CH_2Br_2/TiCI_4)$. The Wittily reaction was unsuccessful in the latter carbonyl methylenation of 2.

• 멤브레인
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• 제10권3호
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• pp.155-162
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• 2000

공급수가 원판틀형 모듈에 잘 분포될 수 있는 역삼투형 하우징(HY)을 개발하여 설계 제작하였으며 상용화된 Rochem(RC)시스템과 투과성능을 비교하였다. 자체 개발한 HY시스템은 RC시스템에 비하여 투과유속이 약간 떨어지는 반면, NaCl 배제율은 전반적으로 높았다 원판틀형 모듈인 type A, B, C에 대한 투과유속 및 배제율을 NaCl, sucrose 및 butanol 수용액으로 측정하였다. NaCl 및 sucrose의 경우, type C, A, B의 순으로 투과성능이 우수하였으나 butanol의 경우는 type B, C, A 순이었다. Type A에 대한 type C의 butanol 투과유속은 농도가 감소할수록 그리고 28 bar 범위내에서 운전압력이 증가할수록 향상되었다.

• Elastomers and Composites
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• 제14권1호
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• pp.7-12
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• 1979

Graft copolymerization of methlymethacrylate(MMA) onto sodium alginate(SA) aqueous solution by sodium metaperiodate$(NaIO_4)$ as an initiator was carried out with the variation of the reaction time, the reaction temperature and the concentrations of initiator and monomer. The results obtained were as follows: 1. SA was easily separated from the reaction mixture of homopolymer, graft polymer and sodium alginate ungrafted by the treatment of concentrated boiling $Na_3PO_4$, solution with the small amount of $Na_2SO_3$ to the mixture and then isolated as the acid form by acidifying the salts solution containing SA. 2. The amount of graft polymer was larger than that of homopolymer below $70^{\circ}C$ whereas above $70^{\circ}C$ the amount of homopolymer was larger. 3. The sum of each amount of graft polymer ana homopolymer was always increased with increase of the reaction time, the reaction temperature and the concentrations of initiator and monomer. 4. With increase of the concentration of initiator, the graft efficiency was increased below $70^{\circ}C$ while decreased above $70^{\circ}C$. 5. Graft copolymerization of MMA onto SA in aqueous solution was carried out without initiator.

• 인터넷정보학회논문지
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• 제18권1호
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• pp.27-35
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• 2017

가까운 미래에는 빅데이터의 많은 부분을 IoT 데이터가 차지할 것이라는 전망이 나오고 있다. 그에 따라, IoT 데이터의 많은 부분을 차치하는 센서 데이터에 관한 관심과 연구 또한 활발하게 진행되고 있다. 여러 분야에서 활용되고 있는 센서 데이터는 분석할 때 실제와는 다른 값인 이상치를 포함하게 되면 정확한 분석이 어려우며, 왜곡된 결과가 도출되어 활용할 수 없는 경우가 생긴다. 따라서 본 논문에서는 정확한 결과를 도출하기 위해 수집된 원자료를 분석하기 전에 이상치 탐지 및 제거를 하였다. 또한, 점점 늘어나고 있는 대용량의 데이터를 빠르게 처리하기 위해 메모리 접근방식인 스파크를 사용한 분산처리환경에서 처리하였다. 맵리듀스 기반의 이상치 탐지 및 제거는 총 4단계로 나누어 구현하였으며, 각 단계를 매퍼와 리듀스로 구현하였다. 제안한 기법의 평가를 위해서 3가지 환경에서 비교하였으며, 그 결과 이상치 탐지 및 제거를 하고자 하는 데이터의 용량이 커질수록 스파크를 이용한 분산처리환경에서의 처리가 가장 빠르다는 결과를 얻었다.