• Title/Summary/Keyword: $NaHCO_3$ and $NaNO_3$

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수리지화학 및 통계학적 방법을 이용한 지하수의 해수영향 분석

  • 조춘희;이현구;김통권;고경석
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.431-433
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    • 2004
  • 해수 영향을 받은 연구지역 지하수의 특성을 수리지화학적 분석과 다변량 통계분석방법을 이용하여 고찰하였다. 수리지화학 분석 결과, 연구지역 지하수는 크게 해수와 경작 등에 의한 인간활동의 영향을 받고 있음을 알 수 있었다. Cl, Na, Mg, Ca, HCO$_3$, NO$_3$, SO$_4$, K, SiO$_2$, Sr의 농도값을 이용하여 군집분석과 주성분 분석 결과, 연구지역의 지하수는 해수의 영향을 나타내는 Na, Cl에 의해 크게 영향을 받으며 3개의 그룹으로 나누어지고, 각 그룹별로 다른 특성을 보여줌을 알 수 있었다.

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Model for Ionic Species Estimation in Soil Solutio (토양용액의 이온조성 추정모델)

  • Kim, Yoo-Hak;Yoon, Jung-Hui;Jung, Beung-Gan;Kim, Min-Kyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.3
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    • pp.213-236
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    • 2001
  • The ionic composition of soil solution is related to a nutrient uptake by plant. Many models for estimating ionic composition of solution have been developed, and most of them have been used for calculating a content of mineral and ionic species in a geochemical point of view. An approximation model considering both cation and anion in soil solution was developed. Variables such as pH, Eh, EC, cations(K, Ca, Mg. Na, Fe, Mn, Al, $NH_4{^+}$), anions(Si, S, P, CY, $NO_3{^-}$, $HCO_3{^-}$ and chemical equilibria of ionic species in soil solution were input into Excel sheet. The activities of soluble ion, ionpairs and complexes of input element were estimated by Newton-Raphson method using conditional equilibrium constant calculated by Davies equation and special models. Equilibrium contents of insoluble minerals and complexes were also calculated.

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Study on the Interpretation of the Features Affacting to the N-supplying Capability of Field Soils to Corn in Pennsylvania (Pennsylvania주 옥수수재배지(栽培地) 토양(土壤)의 질소공급능력(窒素供給能力)에 영향(影響)을 미치는 요인분석(要因分析))

  • Hong, Soon-Dal
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.1
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    • pp.26-37
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    • 1992
  • Fifty-five field experiments were conducted in order to find out some useful indices for the prediction of N-supplying capability(NSC) of soils under cultivation of corn in Pennsylvania over 3 years from 1986. Contents of $NO_3-N$, absorbance at 200 nm of the extract from soil with 0.01M $NaHCO_3$ were identified to be used as indices before planting. Methods for the estimation of organic nitrogen available later in the growing season(KCLA-N, PBBA-N, UV260 nm absorbance of $NaHCO_3$ extract) were not to be used as good indices individually, but when those are combined together with inorganic $NO_3-N$ showed a highly significant correlationship with the NSC. The year of an even distribution of rainfall, 1987, gave the highest significant correlationship between NSC and the indices. For soils of the same texture with slightly different physical properties, combined indices obtained from physico-chemical factors improved the degree of predictability when the grades of soil slope, depth of Ap were considered at the same time. More futher researches such as this need to be done before any conclusive result can be drawn.

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The Effects Sodium Bicarbonate Intake on Blood Variables During High Intensity Exercise of Sprinter (단거리 달리기선수의 고강도 훈련 시 중탄산염 섭취가 혈액변인에 미치는 영향)

  • Kim, In-Dong;Kim, Jae-Joong;Park, Jeong-Beom
    • Journal of Industrial Convergence
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    • v.19 no.4
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    • pp.65-74
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    • 2021
  • The purpose of this study was to investigate the effect of bicarbonate intake on blood variables during high-intensity training of sprinters. 30 male/female elites with more than 3 years of experience that are registered to S city as a sprinter was categorized into three groups: control group, training group, and HCO3- and training group. Training group and HCO3- and training group went through a high-intensity exercise program (80-90% HR max) which escalated every 2-3 weeks, for 90 minutes at a time, 5 days a week, 8 weeks in total. HCO3- and Training group took in 300mg of bicarbonate per one kilogram of body weight, in 90 minutes before the start of the high-intensity exercise program, once a day for 8 weeks. As a result of the study, the effect of bicarbonate intake on blood variables during high-intensity training of sprinters showed a positive effect on the increase of pH and the decrease of lactic acid in HCO3- and training group. Also, the increase of Ca2+, Na+, K+ was shown in training group and HCO3- and training group, whereas there were no indications of significant change in Mg2+ in all three groups. It can be confirmed that the intake of bicarbonate during high-intensity training shows effective changes in the increase of pH and the decrease in lactic acid among changes in blood variables. Therefore, it can be seen that the intake of bicarbonate during high-intensity exercise is effective in improving exercise capacity.

Groundwater quality in the Shallow Aquifer nearby the Gubong gold-mine Tailings (구봉 금광산의 광미 인근지역의 천부지하수 수질특성)

  • Woo, N.-C.;Choi, M.-J.
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.3
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    • pp.148-154
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    • 1998
  • Gubong gold-mine, previously one of the largest gold mines in Korea, is located at the mid-west of the South Korea. In the areas nearby the mine, the shallow groundwater was the major source for domestic and farming water-supply. Soil contamination by Cd, Cu, Pb and Zn was previously known in this area. This study is objected to identify quality of the shallow groundwater, possibly affected by the mine tailings. Samples were collected from a nearby stream, shallow groundwater and seepage from the tailings. Chemical analysis for the water quality includes major cations such as Na, K, Ca, and Mg, anions as F, Cl, NO$_3$, SO$_4$, HCO$_3$, and trace elements as Al, Cr, Mn, Fe, Ni, Cu, Zn, Cd, Pb, Se, As, Hg. Water types could be drawn into four groups from the plots of Piper, Stiff diagrams and cluster analysis. SAR-Conductivity plot indicates the water does not pose either alkalinity or salinity hazards for irrigation. Major contaminant in groundwater appeared to be arsenic, released from arsenopyrites in tailings by oxidation. Dredging of buried railing materials could stimulate the release of arsenic from the sediments to the groundwater.

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온양 지역 온천수의 수질 특성 : 천부 지하수와 혼합 비율 분석

  • 정복선;구민호;김형수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.199-203
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    • 2001
  • 온양온천지구의 13개 온천공에서 채취한 온천수의 수질 자료를 이용하여 심부 온천수와 천부 지하수의 혼합비를 추정하였다. 온천수의 pH, EC, 및 주요 이온의 농도는 40~54$^{\circ}C$의 범위를 나타내는 온천수의 온도와 뚜렷한 선형의 비례관계를 나타내며, 수온이 낮아질수록 천부 지하수의 수질 특성에 가까워지는 특성을 보인다. pH, $K^{+}$, F$^{-}$, 및 Si는 온도와 정(+)의 비례관계를, $Ca^{2+}$, $Mg^{2+}$, Cl$^{-}$, HCO$_3$$^{-}$, SO$_4$$^{2-}$ , NO$_3$$^{-}$ 및 EC는 부(-)의 비례관계를 나타낸다. 온천수의 온도와 수질과의 이러한 상관성은 수질 특성이 상이한 고온의 심부 온천수와 저온의 천부 지하수가 각 온천공에서 서로 다른 비율로 혼합되어 나타난 결과로 해석된다. 최고 온도를 나타내는 온천수와 온천지구 내 지하수의 수질을 끝 성분(end member)으로 가정하고 혼합비를 계산한 결과, 온천지구에서 현재 채수되는 온천수에는 20% 내외의 천부 지하수가 혼합되고 있는 것으로 나타났다. 온천수와 지하수의 수질 자료를 파이퍼 다이어그램에 도시한 결과 $Na^{+}$-HCO$_3$$^{-}$의 유형을 나타내는 13개 온천수는 전체적으로 직선 상에 분포하는 경향을 보였으며, $Ca^{2+}$-HCO$_3$$^{-}$의 유형을 나타내는 지하수는 직선의 연장선상에 분포하여 온천수와 지하수의 혼합이 일어나고 있음을 보여준다. 온천공 수질 검층 결과, 심도 145m를 경계로 지하수와 온천수가 상하부에 부존되어 있으며, 경계부에서 혼합이 발생하고 있는 것으로 추정된다.

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Field Validation of a Sampling and Analytical Method Developed for Preventing Airborne Hexavalent Chromium Collected on PVC Filter from Reduction (PVC 여과지에서의 환원 방지를 위해 개발된 공기중 6가 크롬 측정방법의 현장 평가)

  • 신용철;백남원
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.109-116
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    • 2002
  • The purpose of this study was to evaluate a new sampling and analytical method for the determination of airborne hexavalent chromium, Cr(Ⅵ), in a field plating operation. The procedures of this new method (Shin & Paik's Method) are as the following: Airborne hexavalent chromium is collected on polyvinyl chloride (PVC) filter according to the National Institute iota Occupational Safety and Health (NIOSH) Method 7600, and the filler sample is placed in a screw-capped vial and soaked with 2% NaOH/3% Na₂CO₃ solution immediately after sampling. The Cr(Ⅵ) sample is analyzed by ion chromatography/visible spectrophotometry (IC/VS) according to the U.S. Environmental Protection Agency (EPA) Method 218.6. The airborne Cr(Ⅵ) concentrations measured by this method were compared with those determined by three reference methods: One (NIOSH/EPA Method) consisted of sampling airborne Cr(Ⅵ) on PVC filters and storing the sample filters in strew-capped vials according to the NIOSH method, and analyzing Cr(Ⅵ) in samples using IC/VS according to the EPA method. The second method (Impinger Method/NaHCO₃) consisted of absorbing airborne Cr(Ⅵ) into 0.02 M NaHCO₃ solution in midget impinger, and analyzing the Cr(Ⅵ) in samples using IC/VS. The third method was the OSHA Method ID-215. Using these four different methods, lour replicates of air samples were collected at an electroplating process and analyzed simultaneously. Two-way ANOVA and paired t-test were used to test difference among values determined by the methods. There was no significant difference and a strong correlation (r²:0.99) between Cr(Ⅵ) concentrations measured by the Shin & Paik's Method and an impinger method (p>0.05). However, Cr(Ⅵ) concentrations determined by Shin & Paik's Method were significant1y different from those by the NIOSH/EPA Method (p<0.05) or the OSHA method (p<0.05). The Cr(Ⅵ) concentrations of Shin & Paik's Method were significantly higher than those of the NIOSH/EPA Method or the OSHA method. This result indicated that the Shin & Paik's Method may prevent Cr(Ⅵ) losses caused by reduction and give more reliable results of airborne Cr(Ⅵ) concentrations in work environments.

Microbial Safety and Quality of Fresh Carrot Juice Prepared with Different Environmentally-Friendly Washing Methods (친환경 세척제의 처리 방법을 달리하여 착즙한 당근 주스의 미생물 안전성 및 품질)

  • Lim, Sang-Wook;Choe, Da-Jeong;Kang, Min-Jung;Kim, Jong-Hyun;Kim, Myo-Jeong;Kim, Min-Ju
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.10
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    • pp.1225-1233
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    • 2017
  • The aim of this study was to evaluate the microbial inhibitory activity and physicochemical quality of fresh carrot juice prepared with different environmentally-friendly washing methods during low temperature storage. Individual and combined treatments with sodium bicarbonate (baking soda, $NaHCO_3$) and citric acid were applied to carrots for 10 min. Tap water and 50 ppm of sodium hypochlorite (NaOCl) were used as the control. Combined treatment of 1% $NaHCO_3$ and 1% citric acid significantly reduced total aerobic counts and coliforms. In addition, combined treatment of 1% $NaHCO_3$ and 1% citric acid inhibited microbial growth for 7 days at $4^{\circ}C$ and $10^{\circ}C$ in a shelf-life study. There were no significant differences among the sanitizers in terms of $^{\circ}Brix$, acidity, pH, and color. Changes in physicochemical quality were not significantly different by sanitizer but were affected by storage temperature. These results indicate that washing with combined treatment of 1% $NaHCO_3$ and 1% citric acid is an effective method to inhibit the microbial population and maintain physicochemical quality. Therefore, combined treatment of 1% $NaHCO_3$ and 1% citric acid can be effectively used to sanitize and prepare carrot juice without affecting other properties.

Assessment of Soil Contamination and Hydrogeochemistry for Drinking Water Sites in Korea (국내 먹는샘물 개발지역의 토양 오염 평가 및 수리지구화학적 특성)

  • 이두호;전효택
    • Journal of the Korean Society of Groundwater Environment
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    • v.4 no.1
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    • pp.41-53
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    • 1997
  • Geochemical data of soil and water samples were presented in order to assess the environmental impart for drinking water sites. Microscopic observation of rock samples and physical and chemical analysis of soil and water samples were undertaken. The geology of study areas are classified into three groups such as granitic rocks, meta-sedimentary rocks and sedimentary rocks. Enrichment of heavy metals derived from those rocks is not found in this study areas. Soils were analyzed for Cu, Pb, Zn, Cd and Cr using AAS extracted by HNO$_3$+HClO$_4$ and 0.1 N HCl. Heavy metal concentrations in soils are within the range of those in uncontaminated soils. In comparison of metal contents extracted by 0.1 N HCl and HNO$_3$+HC1O$_4$, less than 10% of the heavy metals are present in the exchangeable fraction. In particular, an pollution index has been proposed to assess the degree of soil contamination. Pollution index in soils are between 0.03 and 0.47 therefore, soils are not polluted with heavy metals. Deep groundwaters within granitic rocks have been evolved into Na$\^$+/-HCO$_3$$\^$-/ type, whereas other deep groundwaters evolved into Ca$\^$2+/-HCO$_3$$\^$-/ type. The predominance of Na$\^$+/ over Ca$\^$2+/ in deep groundwaters within granitic rocks is a result of dissolution of plagioclase, but for sedimentary and meta-sedimentary rocks, dissolution of calcite is a dominant factor for their hydrogeochemistry. The pH, conductivity and contents of the most dissolved ions in the water increase with depth. Shallow groundwaters, however, are highly susceptible to pollution owing to agricultural activities, considering the fact that high contents of nitrate, chloride and potassium, and high K/Na ratio are observed in some shallow groundwaters. In a thermodynamic approach, most natural water samples are plotted within the stability fields of kaolinite and smectite. Therefore, microcline and other feldspars will alter to form clay minerals, such as kaolinite and smectite. From the modelling for water-rock interactions based on mass balance equation, models accord well with behavior of the ions and results of thermodynamic studies are derived.

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Effects of endurance exercise under hypoxia on acid-base and ion balance in healthy males

  • Nam, Sang-Seok;Park, Hun-Young
    • Korean Journal of Exercise Nutrition
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    • v.24 no.3
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    • pp.7-12
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    • 2020
  • [Purpose] This study was performed to investigate the acid-base and ion balance at rest and after exercise in healthy males under normoxia, moderate hypoxia, and severe hypoxia. [Methods] Ten healthy Korean males completed three different trials on different days, comprising exercise under normoxia (FiO2 = 20.9%, N trial), moderate hypoxia (FiO2 = 16.5%, MH trial), and severe hypoxia (FiO2 = 12.8%, SH trial). They undertook endurance exercise for 30 min on a cycle ergometer at the same relative exercise intensity equivalent to 80% maximal heart rate under all conditions. Capillary blood samples were obtained to determine acid-base and ion balance at rest and after exercise. [Results] Exercise-induced blood lactate elevations were significantly increased as hypoxic conditions became more severe; SH > MH > N trials (P = 0.003). After exercise, blood glucose levels were significantly higher in the SH trial than in the N and MH trials (P = 0.001). Capillary oxygen saturation (SCO2) levels were significantly lowered as hypoxic conditions became more severe; SH > MH > N trials (P < 0.001). The pH levels were significantly lower in the MH trial than that in the N trial (P = 0.010). Moreover, HCO3- levels were significantly lower in the SH trial than in the N trial, with significant interaction (P = 0.003). There were no significant differences in blood Na+, K+, and Ca2+ levels between the trials. [Conclusion] MH and SH trials induced greater differences in glucose, lactate, SCO2, pH, and HCO3- levels in capillary blood compared to the N trial. Additionally, lactate, SCO2, and HCO3- levels showed greater changes in the SH trial than in the MH trial. However, there were no significant differences in Na+, K+, and Ca2+ levels in MH and SH trials compared to the N trial.