• Title/Summary/Keyword: $Na-ZnCl_2$

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Effects of Ultrasonic Cleaning and Chemical Pre-treatment on the Characteristics of Fast-stabilized Rayon Fabrics (빠르게 안정화된 레이온직물의 특성에 미치는 초음파세척 및 화학전처리 영향)

  • Cho, Chae Wook;Cho, Donghwan
    • Journal of Adhesion and Interface
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    • v.14 no.3
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    • pp.146-159
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    • 2013
  • In the present study, stabilized rayon fabrics were prepared from fast isothermal stabilization processes, which were carried out within four minutes at $350^{\circ}C$. The effects of ultrasonic cleaning and chemical pre-treatment on the chemical composition, physical characteristics, X-ray diffraction pattern, thermal stability and shape of the stabilized rayon fabrics were investigated extensively. In order to reduce the weight loss and thermal shrinkage of rayon fabrics occurring during the stabilization process, ultrasonic cleaning was first conducted and then chemical pre-treatments using $NH_4Cl$, $Na_3PO_4$, $H_3PO_4$, and $ZnCl_2$ were performed, respectively. The results indicated that both ultrasonic cleaning and chemical pre-treatment influenced the weight loss, thermal shrinkage, microstructure, carbon content, thermal stability and fabric shape of stabilized rayon fabrics. Also the results depended on the fast-stabilization time and the type of chemical pre-treatment agents used.

Quality Characteristics of Livestock Faeces Composts Commercially Produced in Gyeonggi Province in 2008

  • Kang, C.S.;Roh, A.S.;Kim, S.K.
    • Korean Journal of Organic Agriculture
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    • v.19 no.spc
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    • pp.186-189
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    • 2011
  • By surveying the 70 composting plants in Gyeonggi Province, the total commercial production of livestock faeces composts (LFCs) in 2008 was estimated to be about 480,000 Mg year-1 and they were manufactured mainly by using both mechanical mixer and bottom air blower. LFCs were composed mainly of chicken faeces 29.2%, pig+chicken faeces 23.1%, pig faeces 20.0%, livestock faeces+oil cake 12.3%, pig+chicken+cattle faeces 10.8% and pig+cattle faeces 4.6%. On the basis of the current official standard which was revised on March 2010, 11 composts out of surveyed 76 ones did not meet the LFCs quality standard (LQS) due to inadequate content of water (5), OM/N (1), NaCl (2) and Zn (3). The OM/N declined by adding chicken faeces and oil cake, while Ca content increased by the addition of chicken faeces and NaCl increased by adding cattle faeces.

Optimum Culture Conditions for ${\alpha}-Amylase$ Inhibitor Production of Streptomyces minoensis DMCJ-144, ${\alpha}-Amylase$ Inhibitor Producing Actinomycetes (${\alpha}$-아밀라아제 저해제 생성 방선균, Streptomyces minoensis DMCJ-144의 저해제 생산을 위한 최적 배양 조건)

  • Seo, Seong-Ok;Choi, Eung-Chil;Kim, Byong-Kak
    • YAKHAK HOEJI
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    • v.36 no.4
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    • pp.390-396
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    • 1992
  • Streptomyces minoensis DMCJ-144 isolated from soil produces the ${\alpha}-amylase$ inhibitor. Optimum culture conditions for ${\alpha}-amylase$ inhibitor production of the strain were determined in this experiment. The optimum composition of the culture medium was studied by supplementing various carbon sources, nitrogen sources, vitamins, and metal salts to the basal medium containing 1% glucose, 0.1% asparagine, 0.005% $MgSO_4{\cdot}7H_2O$, 0.005% $K_2HPO_4$, 0.005% NaCl. Other culture conditions such as the culture temperature, initial pH of the medium, aeration, and culture time were also investigated. When the strain was cultured in a 100 ml flask containing 20 ml of 2% glucose, 0.5% beef extract, 0.0002% riboflavin, 0.0002% thiamine HCI, 0.01% $ZnCl_2$, 0.005% $MgSO_4{\cdot}7H_2O$, 0.005% $CuSO_4{\cdot}5H_2O$, 0.005% NaCl, pH 7.2, 180 rpm at $30^{\circ}C$, the maximum production of the ${\alpha}-amylase$ inhibitor was observed after 5 days of the cultivation.

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Effect of the Calpain System on Volatile Flavor Compounds in the Beef Longissimus lumborum Muscle

  • Yang, Jieun;Dashdorj, Dashmaa;Hwang, Inho
    • Food Science of Animal Resources
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    • v.38 no.3
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    • pp.515-529
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    • 2018
  • The present study was designed to investigate the effects of calpain system on the formation of volatile flavor compounds in Hanwoo beef. In the first experiment (exp.1), Longissimus lumborum (LL) muscle samples were injected with solutions containing 50 mM $CaCl_2$ or 50 mM $ZnCl_2$ and 154 mM NaCl respectively, and aged for 7 d at $4^{\circ}C$. In the second experiment (exp.2), the ground LL muscle was incubated with the aforementioned solutions containing cathepsin inhibitor. The injection with $CaCl_2$ solution greatly elevated the calpain activity and concomitantly, significantly decreased the Warner-Bratzler shear force (p<0.05). The pH, meat color and cooking loss did not differ (p>0.05) between the treatment groups. A total of 51 volatile compounds were identified using the solid phase microextraction with gas chromatography (SPME-GC). Results on volatile analyses from the both experiments showed that the injection with calcium ions led to significant increase (p<0.05) concentrations of pyrazines and sulfuric compounds. These results coincide with a higher rate of protein degradation due to the $CaCl_2$ injection as compared to the control group. Significantly (p<0.05) higher levels of lipid oxidation derived-aldehydes were found in the samples with $ZnCl_2$. The exp.1 showed that cathepsin inhibitors had no effect on the formation of volatile flavor components after 7 d of aging. These results imply that the proteolytic activity of the calpain system is associated with generation of volatile compounds of chiller-aged beef, while the role of cathepsins is likely very limited.

Chemical Analysis of Fly Ashes from Municipal Solid Waste Incinerators (생활폐기물 처리시설 배출 비산재의 조성분석)

  • Jang, Seong-Ki;Choi, Duk-Il;Lim, Chang-Ho;Lee, Jin-Sook
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.215-221
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    • 2000
  • Analysis of fly ashes from the MSW incinerators was carried out using XRF, ICP-MS and ICP-AES. It was found that the major elements of fly ash were Ca, K, Na, Si, Al, S, Cl and O by the XRF analysis. The XRD spectra showed that the fly ashes were mainly consisted with the chlorides, hydroxides, carbonates and also oxides of former elements. For the determination of minor elements such as Zn, Pb, Cu, Cr, and Cd, we used ICP-AES and ICP-MS after microwave digestion and the results were compared with the result of XRF.

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Studies on Geology and Mineral Resources of the Okcheon Belts -Mineralization in the Vicinity of the Muamsa Granite Stock- (옥천대(沃川帶)의 지질(地質) 및 광물자원(鑛物資源)에 관(關)한 연구(硏究) -무암사화강암(務岩寺花崗岩) 주위에서의 광화작용(鑛化作用)에 관(關)하여-)

  • Yun, Suckew;Kim, Kyu Han;Woo, Jong Sang
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.3-17
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    • 1986
  • Hundred mineral deposits including W-Mo, Pb-Zn-Cu, fluorite and talc occur in the Cambre-Ordovician limestone contacting with the Cretaceous Muamsa and Wolak granitoids in the Susanri-Hwanggangri mineralized zone. In most mineral deposits characterized by metasomatic replacement, skarn and hydrothermal vein types, two distinct tendencies were found as W-Mo mineralization in or/and near granitoid batholith and ($Pb-Zn-Cu(CaF_2)$) mineralization which is gradually increased toward the batholith. W-Mo veins of extensive vein system occupy northly striking fractures whilst $Pb-Zn-Cu-CaF_2$ veins strike northeast or northwest. In this work, three representative lead-zinc-copper deposits choosing the Dangdu, Useog and Eoksu mines were dealt with in detail. Skarn ore bodies in the Dangdu mine were grouped into early diopside rich clinopyoxene-garnet, barren skarn and ore bearing late hedenbergite rich clinopyroxene-garnet skarn. Temperature and $X_{CO_2}$, obtained from hedenbergite-andradite-calcite-quartz mineral equilibria in the Dangdu ore deposits were $580{\sim}650^{\circ}C$ and 0.15~0.3, respectively. Fluid inclusien evidence in the Useog mine indicates that main stage mineralization temperature ranges from 224 to $389^{\circ}C$ with a salinity of 2~17 equivalent wt. percent NaCl. Sphalerites from the Dangdu and Useog mines have 16~17.7 mole percent in FeS which is relatively consistent to those of some other lend-zinc ore deposits in South Korea. Filling tcmjCerature of fluid inclusion frem the Eoksu mine shows deposition of ore within the temperature ranges from 237 to $347^{\circ}C$ and within the salinity ranges from 2.6 to 10.77 equivalent wt. percent NaCl.

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Study on the Immersion Corrosion Characteristics of Thermal Spray Coating for Sea Water Heat Exchanger (해수용 열교환기 적용을 위한 열분사 코팅의 침지부식특성 연구)

  • Huh, Cheol;Cho, Meang-Ik;Kwon, Jeong-Tae;Kwon, Young-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.32-38
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    • 2014
  • In the present study, immersion corrosion characteristics of Zn and Al thermal spray coating with sealer for the seawater heat exchanger are experimentally investigated. Total 8 coating types of Zn and Al thermal spray coating with silicone and epoxy sealer were tested with immersion corrosion testing in $80^{\circ}C$ 3.5%w NaCl solution and compared the corrosion characteristics between each coatings. To investigate the corrosion characteristics of the specimens, AC impedance, SEM, and thermal diffusivity were acquired and analyzed. As a result, on the surface of the specimens with silicone and epoxy sealer, blister did not occurred, so the sealers might be effective at increasing the corrosion resistance of the specimens immersed in the NaCl solution.

Properties Analysis of Zn-Mg Alloy Thin Films Prepared by Plasma Enhanced PVD Method (Plasma-PVD법에 의해 제작한 Zn-Mg합금 박막의 특성 분석)

  • Lee, K.H.;Bae, I.Y.;Kim, Y.J.;Moon, K.M.;Lee, M.H.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.194-195
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    • 2005
  • (100-x)Zn xMg alloy films are prepared onto cold-rolled steel substrates; where x ranged from 0 to about 38 atomic %. The alloy films show microcrystalline and grain structures respectively, according to preparation conditions such as composition ratio of zinc and magnesium or gas pressures etc.. And X-ray diffraction analysis indicates not only the presence of Zn-Mg thin films with forced solid solution but also the one of $MgZn_2$ alloy films partly. In addition the influence of Mg/Zn composition ratio and morphology of the Zn-Mg alloy films on corrosion behavior is evaluated by electro-chemical anodic polarization tests in deaerated 3% NaCl solution. From this experimental results, all the prepared Zn-Mg alloy films showed obviously good corrosion resistance to compare with 99.99% Zn and 99.99% Mg Ingots for evaporation metal. It is thought that the Zn-Mg films with effective forced solid solution prepared by plasma enhanced PVD method, produces smaller and denser grain structure so that may improve the formation of homogeneous passive layer in corrosion environment.

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Corrosion of Zinc Coated Steel in Magnetically Treated 3% Sodium Chloride Solution

  • Chiba, A.;Ohki, T.;Wu, Wen-Chang
    • Corrosion Science and Technology
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    • v.5 no.2
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    • pp.39-44
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    • 2006
  • The dissolution amount of Zn plate was $0.058mg/cm^2$ in the non-magnetically treated solution, and was $0.059mg/cm^2$ in the magnetically treated solution after 24 hours of immersion. The magnetic treatment had no effect to corrosion of Zn plate as pH on surface was not recognized the difference. The addition of Zn(II) ion in the solution was prepared to the effects of corrosion and dissolution of Fe. The regularity was not obtained the effect of the magnetic treatment on the dissolution of Fe plate.

Corrosion Behavior of Zn and Zn-AI Alloy Coated Steels under Cyclic Wet-dry Environments

  • Nishikata, Atsushi;Yadav, Amar Prasad;Tsutsumi, Yusuke;Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.165-170
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    • 2003
  • Atmospheric corrosion behaviors of Zn, Zn-5%Al and Zn-55%A l coated steels have been investigated under cyclic wet-dry environments containing chloride ions. The wet-dry cycle was carried out by alternate exposure to immersion in 0.5 M (or 0.05 M) NaCl solutions and drying at $25^{\circ}C$ and 60 %RH. The polarization resistance $R_p$ and solution resistance $R_s$ were monitored by AC impedance technique. From the obtained $1/R_p$ and $1/R_s$ values, the corrosion rate of the coatings and the Time of Wetness (TOW) were estimated, respectively. Effects of chloride ions and TOW on the corrosion rates of Zn, Zn-5%Al, Zn-55%Al coatings and appearance of red rust (onset of underlying steel corrosion) under wet-dry cycles are discussed on the basis of the corrosion monitoring data.