• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.46-51
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• 1996

본 연구는 MDD(modified direct denitration)공정의 주 우라늄염인 암노늄 우라닐 나이트레이트의 화학특성을 밝히고 이들 화합물의 열분해 및 환원반응의 반응기구에 대하여 조사되었다. 암모늄 우라닐 나이트레이트는 제조 조건에 따라 N $H_4$$UO_2$N $O_3$와 (N $H_4$)$_2$$UO_2$(N $O_3$)$_4$.2$H_2O$의 두가지 형태의 복염으로 존재함이 화학 및 원소분석, X산 회절 분석, 그리고 적외선 분광분석에 의하여 확인되었다. 암모늄 우라닐 나이트레이트는 질소분위기에서 N $H_4$$UO_2$(N $O_3$)$_3$$\longrightarrow$ Amorphous $UO_3$$\longrightarrow$ a-$UO_3$$\longrightarrow$ U$_3$ $O_{8}$$\longrightarrow$ $\alpha$-U$_3$ $O_{8}$의 경로를 따라서 열분해 되며, 수소분위기에서는 N $H_4$$UO_2$(N $O_3$)$_3$$\longrightarrow$ $UO_3$$\longrightarrow$ U$_3$ $O_{8}$$\longrightarrow$ U$_4$ $O_{9}$ $\longrightarrow$ $UO_2$의 경로로 환원되었다.

• Journal of the Korean Ceramic Society
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• v.30 no.4
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• pp.289-298
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• 1993

Properties in terms of the variation of the glass compositions, which were density (p), molar volume(Vm), atom/ion packing density (Dp), refractive index (nD), transformation temperature (Tg), dilatometric softening point (Td), thermal expansion coefficient (α), Young's modulus (E), and knoop hardness (KHN) were investigated in CaO-SiO2 glasses and CaO-P2O5-SiO2 glasses containing less than 10mole% of P2O5. Those properties were measured by density measurement kit, Abbe refractometer, dilatometer, ultrasonic pulse echo equipment, and micro hardness tester. When CaO content was increased in CaO-SiO2 glasses, p, Dp, nD, Tg, Td, α, E and KHN were increased, while Vm was decreased. When P2O5 was added to the CaO-SiO2 glasses with constant CaO/SiO2 ratio as 1.07, p, Dp, nD, Tg, Td, α, E and KHN were decreased, while Vm was increased. When the amount of P2O5 in glasses was kept constant, the changes of the properties with variation of CaO content in the CaO-P2O5-SiO2 glasses were very similar to those of CaO-SiO2 glasses. These phenomena could be explained by the structural role of P2O5 in the CaO-P2O5-SiO2 glasses, which was polymerization of siicate structures and resulted in [PO4] monomer structure in glasses. Due to this structural characteristics, the bond strength and packing density were changed with compositions. Proportional relationships between 1) np and Dp, 2) Tg, Td, α and CaO content, 3) E and Vm-1, and 4) KHN and P2O5 content were evaluated in this investigation.

• Journal of the Korean Ceramic Society
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• v.37 no.3
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• pp.280-287
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• 2000

Adsorption behavior and amount of phenolic resin followed silica (SiO2) formation onto silicon nitride(Si3N4) surface were investigated using electrokinetic sonic amplitude (ESA) technique and with UV spectrometer, to fabricate Si3N4/SiC nano-composite based on reaction between SiO2 formed and phenolic resin absorbed onto Si3N4 particle. The amount of SiO2 formed and carbon from phenolic resin absorbed onto Si3N4 surface were calculated quantitatively to adjust the reaction between SiO2 and phenolic resin, resulting in no residual SiO2 and carbon. As a result, pre-heated tempeature for optimized reaction was below 25$0^{\circ}C$, in which there was no residual SiO2 and carbon.

• Korean Journal of Agricultural Science
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• v.44 no.2
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• pp.211-220
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• 2017

We conducted this study to determine the recommended application rate of fertilizer for Houttuynia cordata Thunb cultivation. The effects of various application levels of N, $P_2O_5$, and $K_2O$ fertilizers on the growth of this plant were investigated and the associated changes in soil properties were evaluated in the field. Soil pH at harvest time of Houttuynia cordata Thunb did not differ from that before fertilization, whereas EC tended to decrease during cultivation. The soil organic matter (SOM) and available phosphorus increased after treatment, and the amount of applied fertilizer ($P_2O_5$) and available phosphorus were proportional. The nitrogen absorption amount increased in N 100% treatment, but decreased in N 150% treatment. The phosphorus absorption amount rose with the fertilizer treatment concentration until $P_2O_5$ 150% treatment. The amount of absorbed potassium decreased in treatments with $K_2O$ 150% and $K_2O$ 200%. The plant length was the longest in N 100%, $P_2O_5$ 150%, and $K_2O$ 200%. The stem diameter was estimated to be 3.46 - 3.67 mm in N 100 - 200% treatment, 3.55 - 3.67 mm in $P_2O_5$ 100 - 150%, and 3.79 mm in $K_2O$ 200%. The number of tillers did not differ amongst fertilization treatments. The fresh weight was summed to be 3.67 ton/10 a in N 100% treatment, 3.79 Mg/10 a in $P_2O_5$ 150%, and 3.83 Mg/10 a in $K_2O$ 150%. Thus, the relationship between the fertilizer amount and yields of the plant showed that the most economical quantity of fertilizers should be 10.2 N kg/10 a, 5.5 $P_2O_5$ kg/10 a, and 8.2 $K_2O$ kg/10 a for Houttuynia Cordata Thunb.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.47-50
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• 1986

Photodesorption of adsorbed $O_2^-$ on ZnO was investigated in ZnO-$O_2(N_2)$-rubrene-bromobenzene mixture. When the mixture was illuminated with the light having the energy greater than the band gap energy of ZnO (3.2eV), the amount of reacted rubrene increased as the amount of ZnO increased in the experimental condition. For the energy of light less than 3.2eV, however, the reacted amount of rubrene decreased as the amount of ZnO increased. There is a difference in the reacted amount of rubrene between ZnO-$O_2$-rubrene-bromobenzene and ZnO-$N_2$-rubrene-bromobenzene mixtures. From the results, it was suggested that the adsorbed $O_2^-$ on ZnO transform to singlet oxygen in the photodesorption process and the singlet oxygen reacted with rubrene.

• Korean Journal of Soil Science and Fertilizer
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• v.6 no.2
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• pp.107-113
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• 1973

A pot experiment on paddy rice was carried out to investigate the effect of temperature after heading with application of phosphate, potash and silica on the yield and nutrient uptake. The results obtained are as follows: 1. The Grain yield was greatly affected by temperature during ripening. The yield at $20^{\circ}C$ and at $15^{\circ}C$ decreased to 62.3% and to 37.2% of that at $25^{\circ}C$ respectively. However, the application of phosphate, potash and silica at transplanting increased the grain yield even at low temperature of $15^{\circ}C$. 2. Percentage of ripened grain and weight of 1,000 grains decreased with decreasing temperature but they were increased by the application of phosphate, potash and silica at the low temperature of $15^{\circ}C$. 3. The grain filling rate was fast in the early stage of ripening at high temperature while it was fast in the later stage at low temperature. Low temperature damage was severe in the early stage of ripening. 4. Accumulation of carbohydrate in the grain was small at low temperature of $15^{\circ}C$ and the application of phosphate, potash and silica was effective to increase carbohydrate content in the grain at low temperature. 5. The content of T-N and $P_2O_5$ in straw grown at low temperature were high whereaas those of $K_2O$ and $SiO_2$ were low which were increased by the application of potash and silica. 6. There was a positive correlation between the grain yield and rate of ripening, 1,000 grain weight, contents of $K_2O$ and $SiO_2$, $K_2O/N$ and $SiO_2/N$ ratio, but a negative correlation between grain yield and contents of T-N and $P_2O_5$ in the straw at harvesting stage. 7. Ripening rate and weight of 1,000 grains showed a significant positive correlation with $K_2O$, $SiO_2$, $K_2O/N$ and $SiO_2/N$ ratio in the straw. Further, there was a negative correlation between ripening rate and the contents of T-N and $P_2O_5$ but a positive correlation between weight of 1,000 grains and these elements.

• Korean Journal of Agricultural and Forest Meteorology
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• v.24 no.4
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• pp.285-294
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• 2022

In order to accurately calculate greenhouse gas emissions in the agricultural field, Korea has been developing national-specific emission factors through direct measurement of gas fluxes using the closed-chamber method. In the rice paddy, only national-specific emission factors for methane (CH₄) have been developed. It is thus necessary to develop those for nitrous oxide (N₂O) affected by the application of nitrogen fertilizer. However, since the concentration of N₂O emission from rice cultivation is very low, the QA/QC methods such as method detection and practical quantification limits are important. In this study, N₂O emission from a rice paddy was evaluated affected by the amount of nitrogen fertilizer, by taking into account both method detection and practical quantification limits for N₂O concentration. The N₂O emission from a rice paddy soils affected by the nitrogen fertilizer application was estimated in the following order. The method detection limit (MDL) of N₂O concentration was calculated at 95% confidence level based on the pooled standard deviation of concentration data sets using a standard gas with 98 nmol mol^-1 N₂O 10 times for 3 days. The practical quantification limit (PQL) of the N₂O concentration is estimated by multiplying 10 to the pooled standard deviation. For the N₂O flux data measured during the rice cultivation period in 2021, the MDL and PQL of N₂O concentration were 18 nmol mol^-1 and 87 nmol mol^-1, respectively. The measured values above the PQL were merely about 12% of the total data. The cumulative N₂O emission estimated based on the MDL and PQL was higher than the cumulative emission without nitrogen fertilizer application. This research would contribute to improving the reliability in quantification of the N₂O flux data for accurate estimates of greenhouse gas emissions and uncertainties.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.679-684
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• 1992

New Pd(IV) complexes have been prepared through the reactions of $trans-[Pd(en)_2Cl_2](ClO_4)_2 $(en = ethylenediamine) with Guanine, Adenine, or Uracil anion as purine and pyrimidine base. We identified the ratio of central metal versus ligands by $C{\cdot}H{\cdot}N$ elemental analysis and proposed the coordinating site of the base by infrared spectrum, $^1H-NMR,\; and\; ^{13}C$-NMR spectrum. Guanine or Adenine ligand coordinated at N7 site and an en ligand exchanged for $ClO_4^-$ counter ions of the starting material . As these results, the complexes showed the formula $[Pd(en)L_2(ClO_4)_2](ClO_4)_2{\cdot}(en)$, (L = Guanine, Adenine). But in the Uracil complex no exchange of the en ligand and $ClO_4^-$ occured and Uracil anion preferred the N1 to N3 as coordinating site, the complex $[Pd(en)_2(Urac)_2](ClO_4)_2(Urac = Uracil anion).$

• Proceedings of the Korean Information Science Society Conference
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• 2000.04a
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• pp.701-703
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• 2000

본 논문에서는 정규 기저 표현(normal bases repersentation)을 갖는 GF(2n)상에서의 병렬 멱승 연산에 있어서 2 가지의 개선 사항을 기술한다. 첫째는,k를 윈도우 길이로 할 때 라운드가 [log k]+[log[n/k]]로 고정된 경우에 현재까지 알려진 방법보다 더 작은 수의 프로세서를 갖는 방안이다. 둘째는 점근적인(asymptotic)분석을 통하여 GF(2n)상에서의 병렬 멱승 연산이 O(n/log2n)개의 프로세서로 O(logn)라운드에 수행될 수 있음을 보인다. 이것은 m로세서 $\times$라운드의 바운드를 O(n/logn)으로 하는 것으로 이전까지 알려졌던 O(n)을 개선한 것이다.

• Polymer(Korea)
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• v.39 no.1
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• pp.169-173
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• 2015

Metallocene was supported on the silica, which was functionalized with aminosilanes such as aminopropyltrimethoxysilane (1NS) or N-[3-(trimethoxysilyl)propyl]ethylenediamine (2NS), and ionic liquids such as 1-butyl-4-methylpyridinium chloride (Cl), tributylmethylammonium chloride (Amm), benzyldimethyltetradecylammonium chloride (Ben), 1-butyl-1-methylpyrrolidinium chloride (Pyr), and then ethylene polymerizations were performed. The Zr contents of $SiO_2/1NS/IL/(n-BuCp)_2ZrCl_2$ and $SiO_2/2NS/IL/(n-BuCp)_2ZrCl_2$ were lower than those of only aminosilane-treated silicas. However, the polymerization activity of $SiO_2/1NS/IL/(n-BuCp)_2ZrCl_2$ was higher than that of $SiO_2/1NS/(n-BuCp)_2ZrCl_2$. The polymerization activity of $SiO_2/2NS/IL/(n-BuCp)_2ZrCl_2$ was lower than that of $SiO_2/2NS/(n-BuCp)_2ZrCl_2$ due to much lower Zr content.