• 제목/요약/키워드: $N_2O$ generation

검색결과 269건 처리시간 0.036초

로터리형 원자층 증착법을 이용한 Bi-Te계 소결체의 열전 성능 개선 (Thermoelectric Performance Enhancement of Sintered Bi-Te Pellets by Rotary-type Atomic Layer Deposition)

  • 정명준;박지영;은수민;최병준
    • 한국분말재료학회지
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    • 제30권2호
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    • pp.130-139
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    • 2023
  • Thermoelectric materials and devices are energy-harvesting devices that can effectively recycle waste heat into electricity. Thermoelectric power generation is widely used in factories, engines, and even in human bodies as they continuously generate heat. However, thermoelectric elements exhibit poor performance and low energy efficiency; research is being conducted to find new materials or improve the thermoelectric performance of existing materials, that is, by ensuring a high figure-of-merit (zT) value. For increasing zT, higher σ (electrical conductivity) and S (Seebeck coefficient) and a lower κ (thermal conductivity) are required. Here, interface engineering by atomic layer deposition (ALD) is used to increase zT of n-type BiTeSe (BTS) thermoelectric powders. ALD of the BTS powders is performed in a rotary-type ALD reactor, and 40 to 100 ALD cycles of ZnO thin films are conducted at 100℃. The physical and chemical properties and thermoelectric performance of the ALD-coated BTS powders and pellets are characterized. It is revealed that electrical conductivity and thermal conductivity are decoupled, and thus, zT of ALD-coated BTS pellets is increased by more than 60% compared to that of the uncoated BTS pellets. This result can be utilized in a novel method for improving the thermoelectric efficiency in materials processing.

Stratum Corneum Carbonylated Protein (SCCP)의 피부 생물학적 파라미터와의 관계 (Relationship between Stratum Corneum Carbonylated Protein (SCCP) and Skin Biophysical Parameters)

  • 이용직;남개원
    • 대한화장품학회지
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    • 제45권2호
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    • pp.131-138
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    • 2019
  • Carbonylated proteins (CPs)은 단백질의 염기성 아미노산 잔기들과 지질 과산화 중 생성되는 알데히드 화합물과의 화학적 반응을 통하여 만들어진다. CP는 UVA와 청색 광선 영역의 빛을 흡수하여 흥분하며, CP의 감광 반응을 통해 superoxide anion radicals ($^{\cdot}O_2{^-}$)이 생성되고 각질층(Stratum corneum, SC)에서 reactive oxygen species (ROS) 생성을 통해 새로운 protein carbonylation이 진행되는 것이 알려졌다. 또한, superoxide anion radicals이 SC에서 CP를 생성하며 색상과 수분 기능을 포함한 피부 상태에 영향을 미치는 것으로 보고되었다. 따라서, 본 연구의 목적은 피부 각질층에 존재하는 stratum corneum carbonylated protein (SCCP)의 생성량과 피부 탄력 개선의 상관정도를 알아보는 것이었다. 이를 위하여 46명의 건강한 피험자들을 대상으로 8주간 피부임상실험을 진행하였다. 8주간 진행한 피부임상시험은 피험자를 두 그룹으로 나누어, 한 그룹은 아무것도 함유하지 않은 크림을 사용하고, 다른 그룹은 탄력개선 원료가 함유된 크림을 사용하였다. 임상시험 측정 항목은 DUB scanner를 이용한 진피 치밀도 측정, Primos를 이용한 주름 측정을 진행하였으며 탄력 측정은 dermal torque meter (DTM310)와 Balistometer (BLS780)를 통해 진행하였다. SCCP측정은 피험자의 뺨에서cyanoacrylate를 이용한 skin surface biopsy (SSB)방법을 이용하여 각질을 채취한 후, 비침습적인 검출 방법을 이용해 SCCP의 양을 조사하였다. 측정은 0주, 4주, 8주 총 3회에 걸쳐서 진행하였으며 각 주차의 측정값을 각각 분석하여 종합적인 결과를 비교하였다. 그 결과, SC에 존재하는 CP의 양은 피부 주름 및 피부 탄력성과 관련된 생물학적 인자의 수치가 개선됨에 따라 감소하는 것을 확인하였다. 이를 통해 항노화 효과에 있어서 탄력 개선과 CP양의 상관관계를 확인하여, 차후 피부 항노화 시험방법에 응용할 수 있음을 확인하였다.

바이오가스의 성분 변화가 엔진 성능에 주는 영향 (Effects of Biogas Composition Variations on Engine Performance)

  • 박승현;박철웅;김영민;이선엽;김창기
    • 한국가스학회지
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    • 제15권5호
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    • pp.25-30
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    • 2011
  • 바이오가스는 Biomass, 유기성 폐기물 등의 혐기소화 공정을 통해 얻을 수 있는 대표적인 신재생연료로 저발열량에도 불구하고 탄소중립적인 특성이 있기 때문에 이를 엔진에 적용하여 에너지를 생산하고자 하는 노력이 계속되어왔다. 바이오가스는 원료의 종류 및 혐기소화 공정 조건에 따라 그 연료 조성이 달라질 수 있는데, 이러한 조성 변화는 엔진 성능에 큰 영향을 미칠 수 있기 때문에 이에 대한 연구가 필요한 실정이다. 따라서 이번 연구에서는 다양한 발열량을 갖는 바이오가스를 연료 내 불활성가스 비율을 변화시켜 모사하고 이를 이용하여 바이오가스 내 불활성가스 비율의 변화, 즉 발열량의 변화가 엔진 성능 및 배기 특성에 주는 영향을 파악하였다. 실험결과로 각 불활성가스 함량에 따른 최적 점화시기를 결정하였으며, 발열량 변화가 엔진 출력, 효율, 배기 성능에 미치는 영향을 제시하였다.

선택적 iNOS 억제에 의한 골격근 재관류 손상의 감소 (Selective iNOS Inhibition Attenuates Skeletal Muscle Reperfusion Injury)

  • 박종웅;이광석;김성곤;박정호;왕준호;전우주;이정일
    • Archives of Reconstructive Microsurgery
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    • 제15권1호
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    • pp.1-9
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    • 2006
  • The purpose of this study is to determine the effects of selective inducible nitric oxide synthase (iNOS) inhibitor N-[3-aminomethyl]benzyl]acetamidine (l400W) on the reperfused cremaster muscle. The extracellular superoxide dismutase knockout ($EC-SOD^{-/-}$) mice was used to make the experimental window for ischemia-reperfusion injury. The muscle was exposed to 4.5 h of ischemia followed by 90 min of reperfusion and the mice received either 3 mg/kg of 1400W or the same amount of phosphate buffered saline (PBS) subcutaneously at 10 min before the start of reperfusion. The results showed that 1400W treatment markedly improved the recovery of the vessel diameter and blood flow in the reperfused cremaster muscle compared to that of PBS group. Histological examination showed reduced edema in the interstitium and muscle fiber, and reduced nitrotyrosine formation (a marker of total peroxinitrite ($ONOO^-$) in 1400W-treated muscle compared to PBS. Our results suggest that iNOS and $ONOO^-$ products are involved in skeletal muscle I/R injury. Reduced I/R injury by using selective inhibition of iNOS is perhaps via limiting cytotoxic $ONOO^-$ generation, a reaction product of nitric oxide (NO) and superoxide anion ($O_2^-$). Thus, inhibition of iNOS appears to be a good treatment strategy in reducing clinical I/R injury.

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The Inhibition of Epileptogenesis During Status Epilepticus by Ginsenosides of Korean Red Ginseng and Ginseng Cell Culture (Dan25)

  • N.E., Chepurnova;Park, Jin-Kyu;O.M., Redkozubova;A.A., Pravdukhina;K.R., Abbasova;E.V., Buzinova;A.A., Mirina;D.A., Chepurnova;A.A., Dubina;U.A., Pirogov;M., De Curtis;L., Uva;S.A., Chepurnov
    • Journal of Ginseng Research
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    • 제31권3호
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    • pp.159-174
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    • 2007
  • Pharmacology of Korean Red ginseng gives us unique possibility to develop new class of antiepileptic drugs today and to improve one's biological activity. The chemical structures of ginsenosides (GS) have some principal differences from well-known antiepileptic new generation drugs. The antiepileptic effect of GS was also demonstrated in all models of epilepsy in rats (young and adult), which have studied, in all models of epilepsy including status epilepticus (SE), induced by lithium - pilocarpine. In our experiments in rats new evidences on protective effects were exerted as a result of premedication by GS. Pre-treatment of several GS could induce decrease of the seizures severity and brain structural damage (by MRI), neuronal degeneration in hippocampus. Wave nature of severity of motor seizures during convulsive SE was observed during lithium-pilocarpine model of SE in rats (the first increase of seizures was 30 min after the beginning of SE and the second - 90 min after. The efficacy of treatment on SE by ginsenoside as expected was observed after no less 3 weeks by daily GS i.p. administration. It is blocked SE or significantly decrease the severity of seizures during SE. The implication of presented data is that combination of ginsenosides from Korean Red ginseng and ginseng cell culture Dan25 that could be applied for prevention of epileptical status development. However, a development of optimal ratio of different ginsenosides $(Rb_1$ Rc, Rg, Rf,) should consummate in the new antiepileptic drug development.

CMOS VLSI의 효율적인 IDDQ 테스트 생성을 위한 패턴 생성기의 구현 (Implementation of Pattern Generator for Efficient IDDQ Test Generation in CMOS VLSI)

  • 배성환;김관웅;전병실
    • 대한전자공학회논문지SD
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    • 제38권4호
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    • pp.292-301
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    • 2001
  • IDDQ 테스트는 CMOS VLSI 회로에서 발생 가능한 여러 종류의 물리적 결함을 효율적으로 검출 할 수 있는 테스트 방식이다. 본 논문에서는 CMOS에서 발생 빈도가 가장 높은 합선고장을 효과적으로 검출할 수 있는 IDDQ 테스트 알고리즘을 이용하여 패턴 생성기를 개발하였다. 고려한 합선고장 모델은 회로의 레이아웃 정보에 의존하지 않으며, 내부노드 혹은 외부노드에 한정시킨 합선고장이 아닌 테스트 대상회로의 모든 노드에서 발생 가능한 단락이다. 구현된 테스트 패턴 생성기는 O(n2)의 복잡도를 갖는 합선고장과 전압 테스트 방식에 비해 상대적으로 느린 IDDQ 테스트를 위해서 새롭게 제안한 이웃 조사 알고리즘과 고장 collapsing 알고리즘을 이용하여, 빠른 고장 시뮬레이션 시간과 높은 고장 검출율을 유지하면서 적은 수의 테스트 패턴 생성이 가능하다. ISCAS 벤치마크 회로의 모의실험을 통하여 기존의 다른 방식보다 우수한 성능을 보였다.

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Effect of abutment types and resin cements on the esthetics of implant-supported restorations

  • Asena Ceken;Hamiyet Kilinc;Sedanur Turgut
    • The Journal of Advanced Prosthodontics
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    • 제15권3호
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    • pp.114-125
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    • 2023
  • PURPOSE. The aim of the study was to evaluate the optical properties of new generation (3Y-TZP) monolithic zirconia (MZ) with different abutment types and resin cement shades. MATERIALS AND METHODS. A1/LT MZ specimens were prepared (10 × 12 × 1 mm, N = 30) and divided into 3 groups according to cement shades as transparent (Tr), yellow (Y) and opaque (O). Abutment specimens were obtained from 4 different materials including zirconia (Group Z), hybrid (Group H), titanium (Group T) and anodized yellow titanium (Group AT). MZ and abutment specimens were then cemented. L*, a*, and b* parameters were obtained from MZ, MZ + abutment, and MZ + abutment + cement. ∆E001* (between MZ and MZ + abutment), ∆E002* (between MZ and MZ + abutment + cement) and ∆E003* (between MZ + abutment and MZ + abutment + cement) values were calculated. Statistical analyses included 2-way ANOVA, Bonferroni, and Paired Sample t-Tests (P < .05). RESULTS. Abutment types and resin cements had significant effect on L*, a*, b*, ∆E001*, ∆E002*, and ∆E003* values (P < .001). Without cementation, whereas zirconia abutment resulted in the least discoloration (∆E001* = 0.68), titanium abutment caused the most discoloration (∆E001* = 4.99). The least ∆E002* = 0.68 value was seen using zirconia abutment after cementation with yellow shaded cement. Opaque shaded cement caused the most color change (∆E003* = 5.24). Cement application increased the L* values in all groups. CONCLUSION. The least color change with/without cement was observed in crown configurations created with zirconia abutments. Zirconia and hybrid abutments produced significantly lower ∆E002* and ∆E003* values in combination with yellow shaded cement. The usage of opaque shaded cement in titanium/anodized titanium groups may enable the clinically unacceptable ∆E00* value to reach the acceptable level.

전력반도체 응용을 위한 용액 공정 인듐-갈륨 산화물 반도체 박막 트랜지스터의 성능과 안정성 향상 연구 (Solution-Processed Indium-Gallium Oxide Thin-Film Transistors for Power Electronic Applications)

  • 김세현;이정민;;김민규;정유진;백강준
    • 한국전기전자재료학회논문지
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    • 제37권4호
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    • pp.400-406
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    • 2024
  • Next-generation wide-bandgap semiconductors such as SiC, GaN, and Ga2O3 are being considered as potential replacements for current silicon-based power devices due to their high mobility, larger size, and production of high-quality wafers at a moderate cost. In this study, we investigate the gradual modulation of chemical composition in multi-stacked metal oxide semiconductor thin films to enhance the performance and bias stability of thin-film transistors (TFTs). It demonstrates that adjusting the Ga ratio in the indium gallium oxide (IGO) semiconductor allows for precise control over the threshold voltage and enhances device stability. Moreover, employing multiple deposition techniques addresses the inherent limitations of solution-processed amorphous oxide semiconductor TFTs by mitigating porosity induced by solvent evaporation. It is anticipated that solution-processed indium gallium oxide (IGO) semiconductors, with a Ga ratio exceeding 50%, can be utilized in the production of oxide semiconductors with wide band gaps. These materials hold promise for power electronic applications necessitating high voltage and current capabilities.

Amorphous Indium-Tin-Zinc-Oxide (ITZO) Thin Film Transistors

  • 조광민;이기창;성상윤;김세윤;김정주;이준형;허영우
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.170-170
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    • 2010
  • Thin-film transistors (TFT) have become the key components of electronic and optoelectronic devices. Most conventional thin-film field-effect transistors in display applications use an amorphous or polycrystal Si:H layer as the channel. This silicon layers are opaque in the visible range and severely restrict the amount of light detected by the observer due to its bandgap energy smaller than the visible light. Therefore, Si:H TFT devices reduce the efficiency of light transmittance and brightness. One method to increase the efficiency is to use the transparent oxides for the channel, electrode, and gate insulator. The development of transparent oxides for the components of thin-film field-effect transistors and the room-temperature fabrication with low voltage operations of the devices can offer the flexibility in designing the devices and contribute to the progress of next generation display technologies based on transparent displays and flexible displays. In this thesis, I report on the dc performance of transparent thin-film transistors using amorphous indium tin zinc oxides for an active layer. $SiO_2$ was employed as the gate dielectric oxide. The amorphous indium tin zinc oxides were deposited by RF magnetron sputtering. The carrier concentration of amorphous indium tin zinc oxides was controlled by oxygen pressure in the sputtering ambient. Devices are realized that display a threshold voltage of 4.17V and an on/off ration of ${\sim}10^9$ operated as an n-type enhancement mode with saturation mobility with $15.8\;cm^2/Vs$. In conclusion, the fabrication and characterization of thin-film transistors using amorphous indium tin zinc oxides for an active layer were reported. The devices were fabricated at room temperature by RF magnetron sputtering. The operation of the devices was an n-type enhancement mode with good saturation characteristics.

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복숭아혹진딧물의 살충제 저항성(抵抗性)에 관한 연구(硏究) III. Acephate저항성(抵抗性) 발달(發達), 교차저항성(交叉抵抗性) 및 Esterase Isozymes (Studies of Insecticide Resistance in Green Peach Aphids, Myzus persicae(Sulz) III. Acephate Resistance, Cross-Resistance, and Esterase Isozymes)

  • 최승윤;김길하
    • 한국응용곤충학회지
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    • 제25권2호
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    • pp.99-105
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    • 1986
  • 본(本) 시험(試驗)은 실내(室內)에서 복숭아혹진딧물(Myzus persicae)을 OP계(系) 살충제 acephate로 누대도태(累代淘汰)시켜 저항성(抵抗性) 발달속도(發達速度)와 정도(程度), 다른 살충제와의 교차저항성(交叉抵抗性) 유무(有無), 나아가 그들 계통(系統)에서 esterase isozyme을 검출(檢出)하여 살충제) 저항성(抵抗性)과의 관계를 검토(檢討)코자 하였다. 1. 복숭아혹진딧물의 acephate 저항성(抵抗性) 발달(發達) 속도(速度)는 5세대(世代) 도태(淘汰)에서 $1.0{\sim}1.6$배(倍), 10세대(世代) 도태(淘汰)에서 $2.2{\sim}2.8$배(倍), 15세대(世代) 도태(淘汰)에서 $3.5{\sim}5.1$배(倍), 20세대(世代) 도태(淘汰)에서 $6.7{\sim}9.3$배(倍)로 증대(增大)되었다. 2. Acephate 20세대(世代) 도태저항성(淘汰抵抗性) 계통(系統)은 24시간(時間) 조사(調査)에서는 acephate자체(自體)에 대하여 31.7배(倍), cypermethrin에 대해서는 507.3배(倍), oxydometon-methyl에 대해서는 49.7배(倍), pirimicarb에 대해서는 7.5배(倍)이었고 48시간((時間) 조사(調査)에서는 acephate 자체(自體)에 대하여 32.0배(倍), cypermetherin에 대하여 475.6배(倍), oxydemeton-methyl에 대하여 21.5배(倍), pirimicarb에 대(對)하여 8.9배(倍)이었다. 3. Acephate 저항성(抵抗性) 계통(系統)은 cypermethrin과 oxydemeton-methyl에 대하여 높은 교차저항성(交叉抵抗性)을 나타내었고 pirimicarb에 대해서는 낮은 교차저항성(交叉抵抗性)을 나타내었다. 4. Esterase isozyme의 영동대(泳動帶)에 있어서 $Est\;{\alpha}-1,\;Est\;{\alpha}-2,\;{\beta}-1$는 저항성(抵抗性), 감수성(感受性) 두 계통(系統) 모두에서 검출(檢出)되었으나 $Est\;{\beta}-2$는 acephate 저항성(抵抗性) 계통(系統)에서만 검출(檢出)되었다.

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