• 제목/요약/키워드: $NO_x$ removal

검색결과 252건 처리시간 0.033초

Study on Chemical Removal of Nitric Oxide (NO) as a Main Cause of Fine Dust (Air Pollution) and Acid Rain

  • Seo, Hyeon Jin;Jeong, Rak Hyun;Boo, Jang-Heon;Song, Jimin;Boo, Jin-Hyo
    • Applied Science and Convergence Technology
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    • 제26권6호
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    • pp.218-222
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    • 2017
  • This study was conducted to remove $NO_x$, which is the main cause of fine dust and air pollution as well as acid rain. $NO_x$ was tested using 3% NO (diluted in He) as a simulated gas. Experiments were sequentially carried out by oxidizing NO to $NO_2$ and absorbing $NO_2$. Especially, we focused on the changes of NO oxidation according to both oxidant ($NaClO_2$) concentration change (1~10 M) and oxidant pH change (pH = 1~5) by adding HCl. In addition, we tried to suggest a method to improve $NO_2$ absorption by conducting $NO_2$ reduction reaction with reducing agent (NaOH) concentration (40~60%). It was found that NO removal efficiency increased as both concentration of oxidant and flow rate of NO gas increased, and NO decreased more effectively as the pH of hydrochloric acid added to the oxidant was lower. The $NO_2$ adsorption was also better with increasing NaOH concentration, but the NO removal efficiency was ~20% lower than that of the selective NO reduction. Indeed, this experimental method is expected to be a new method that can be applied to the capture and removal of fine dust caused by air pollution because it is a method that can easily remove NO gas by a simple device without expensive giant equipment.

나노 이산화티타늄(TiO2)을 코팅한 기포 콘크리트 골재의 질소산화물(NOX) 제거성능 평가 (NOX Removal Capacities of Foamed concrete Granules Coated with TiO2 Nanoparticles)

  • 이재욱;양근혁;문주현
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2020년도 봄 학술논문 발표대회
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    • pp.130-131
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    • 2020
  • This study manufactured the porous foamed concrete granules coated with TiO2 Nanoparticles, to widen the specific surface area. The Removal rate of concrete granules coated with TiO2 Nanoparticles was average 56.7%, which was approximately 2.3 time higher than that of the conventional surface TiO2 coating.

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고정원에서 배출되는 $NO_x/SO_x$의 동시제거를 위한 SCR 촉매의 제조법에 관한 연구: I. $V_2O_5-MoO_3/TiO_2$ 촉매들의 표면특성과 반응성 (Studies on the Preparation for the Simultaneous Removal of NO and $SO_2$ from Stationary Sources I.Surface properties and reactivity of $V_2O_5-MoO_3/TiO_2$ catalysts)

  • 구미화;정석진
    • 한국대기환경학회지
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    • 제8권1호
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    • pp.58-67
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    • 1992
  • For removing $NO_x$ and $SO_x$ from the flue gases emitted from stationary sources, $V_2O_5-MoO_3/TiO_2$ catalysts were prepared by the conventional impregnation method (aqueous solution) and a sort of surface fixation method(nonaqueous solution) as reported excellent reproducibility catalysts. And these catalysts observed their catalytic activities as well as their surface properties. V-Mo-O oxide, prepared from nonaqueous solution of $VOCl_3$ and $Mo(CO)_6$ and aqeous solution method, was supported as amorphous state by XRD and SEM measurements. The infrared spectra of fresh and used catalysts showed that in used catalysts, V=O bands decreased and new bands of vanadium oxysulfate bands were very sensitive. So the catalysts prepared from nonaqueous solution may bring about the high activity. Results from catalytic activity measurements at 350$^\circ$C, in the presence of $SO_2, NO$ conversion was more increased than in absence of $SO_2$. As the $MoO_3$ was added to $V_2O_5/TiO_2 system, SO_2$ conversion increased. It found that from the results, $V_2O-5-MoO_3/TiO_2$ catalysts prepared from an nonaqueous solution may bring about the high activity for both the reaction of NO and $SO_2$ removal.

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하수처리시설의 질산화 진단기반 제어 방법의 개발 및 실규모 플랜트 적용을 통한 평가 (Evaluation of Diagnosis-based Control Strategy for NH4-N and NOX-N Removal of a Full-scale Wastewater Treatment Process)

  • 김예진;김효수
    • 한국환경과학회지
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    • 제27권6호
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    • pp.447-456
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    • 2018
  • In this research, the target process was a modified type of a conventional aeration tank with four different influent feeding points and alternated aeration to obtain nitrogen removal. For more accurate switching of influent feeding, the process was operated under a designed control strategy based on monitoring of $NH_4-N$ and $NO_X-N$ concentrations in the tank. However, the strategy did have some limitations. For example, it was not sensitive to detecting the end of each reaction when losing the balance between nitrification and denitrification of each opposite part of biological tank. To overcome the limitations of the existing control strategy, a diagnosis-based control strategy was suggested in this research using the diagnosis results classified as normal (N), ammonia accumulation (AA) and nitrate accumulation (NA). Using the pre-designed rules for control actions, the aeration and volume of the aerated part of the reactor could be increased or decreased at a fixed mode time. In simulations of the suggested diagnosis-based control strategy, the $NH_4-N$ and $NO_X-N$ removal rates in the reactor were maintained at higher levels than those of the existing control strategy.

박용 디젤기관의 $NO_x$ 및 매연 배출물에 미치는 스크러버형 EGR 시스템 재순환배기의 영향에 관한 연구 (A Study on Effects of Recirculated Exhaust Gas upon $NO_x$ and Soot Emissions of a Marine Diesel Engine with Scrubber EGR System)

  • 배명환;하정호
    • Journal of Advanced Marine Engineering and Technology
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    • 제24권3호
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    • pp.70-78
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    • 2000
  • The effects of recirculated exhaust gas on the characteristics of ;$NO_x$ and soot emissions under a wide range of engine load have been experimentally investigated by a water-cooled, four-cylinder, indirect injection, four cycle and marine diesel engine operating at two kinds of engine speeds. The purpose of the present study is to develop the EGR control system for reducing $NO_x$ and soot emissions simultaneously in diesel engines. The EGR system is used to reduce NOx emissions, and a novel diesel soot removal apparatus with a cylinder-type scrubber for the experiment system which has 6 water injectors(A water injector is made up 144 nozzles with 1.0mm in diameter) is specially designed and manufactured to reduce the soot contents in the recirculated exhaust gas to intake system of the engines. The intake oxygen concentration obtained by the intake air flow and the oxygen concentration in the recirculated exhaust gas, and the exhaust oxygen concentration measured in exhaust manifold are used to analyse and discuss the influences of EGR on NOx and soot emissions. The experiments are performed at the fixed fuel injection timing of $15.3^{\circ}$ BTDC regardless of experimental conditions. It is found that $NO_x$ emissions decrease and soot emissions increase owing to the drop of intake oxygen concentration and exhaust oxygen concentration as EGR rate rises. Also, one can conclude that it is sufficient for the scrubber EGR system with a novel diesel soot removal apparatus to reduce $NO_x$ emissions, but not to reduce soot emissions.

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Biological nitrogen removal of ammonium-rich industrial wastewater by suspended bacterial growth

  • 임준택;성세현;황석환
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2002년도 생물공학의 동향 (X)
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    • pp.399-402
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    • 2002
  • Industrial wastewater with high ammonium concentration was treated in batch biological systems which was a modified Ludzack- Ettinger process. Up to 78% conversion of $NH_4\;^+-N$ to $NO_x\;^--N$ was achieved in batch culture condition. Under anoxic condition with methanol as the carbon source, the denitrifiers decreased $NO_x\;^--N$ concentration from 608 mg/L to 5.6 mg/L in 22 d. As well as anoxic denitrification of $NO_x\;^-$ to $N_2$, dissimilatory nitrate reduction to ammonium also occurred under the condition as respiratory denitrification.

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먼지$/SO_x/NO_x$ 동시처리용 세라믹 필터 개발에 관한 연구 (The development of a ceramic filter with dust $/SO_x/NO_x$ removal ability (II))

  • 신현규;김영배;엄우식;이희수;김영길
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.461-462
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    • 1999
  • 고온고압의 연소 분위기를 생성시키는 석탄이용 발전 시스템 및 소각로, 유리공장 등에서 발생되는 먼지 및 유해가스 제거 기술은 세계적으로 문제시되고 있는 환경오염 차원에서 필수적으로 요구되어지는 기술이라 할 수 있다. 이러한 고온고압의 시스템에서 사용될 수 있는 필터로 현재 세라믹이 가장 적절한 재질로 평가되고 있는데 이는 세라믹 자체가 지닌 열적 안정성 때문이라고 할 수 있다.(중략)

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