• Journal of Environmental Health Sciences
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• v.49 no.5
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• pp.275-288
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• 2023

Background: When basic local governments want to improve their air quality management policies, they need fundamental evidence, such as the effectiveness of current policies or scenario results. Objectives: The purpose of this study is to lay the groundwork for a process to calculate air pollutant reduction from basic local government air quality policies and provide numerical estimates of PM_2.5 concentrations following improved policies. Methods: We calculated the amount of air pollutant reduction that can be expected in the research region based on the Gyeonggi-do Air Environment Management Implementation Plan issued in 2021 and guidelines from the Korean Ministry of Environment. The PM_2.5 concentration variations were numerically simulated using the CMAQ (photochemical air quality model). Results: The research regions selected were Suwon, Ansan, Yongin, Pyeongtaek, and Hwaseong in consideration of population, air pollutant emissions, and geographical requirements. The expected reduction ratios in 2024 compared to 2018 are CO (3.0%), NO_x (7.9%), VOCs (0.7%), SO_x (0.1%), PM₁₀ (2.4%), PM_2.5 (6.1%), NH₃ (0.05%). The reduced PM_2.5 concentration ratio was highest in July and lowest in April. The expected concentration reduction of yearly mean PM_2.5 in the research region is 0.12 ㎍/m³ (0.6%). Conclusions: Gyeonggi-do is now able to quickly provide air pollutant emission reduction calculations by respective policy scenario and PM_2.5 simulation results, including for secondary aerosol particles. In order to provide more generalized results to basic local governments, it is necessary to conduct additional research by expanding the analysis tools and periods.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.5
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• pp.708-726
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• 2018

In this study, we examined the contribution of nitrogen oxides and volatile organic compounds emitted from China and Japan to ozone concentrations over Gwangyang-bay, South Korea. We used a chemical transport model, Community Multi-scale Air Quality model, and its instrumented sensitivity tool, High-order Decoupled Direct Method. Intercontinental Chemical Transport Experiment-Phase B 2006 for East Asia and Clean Air Policy Support System 2007 emissions inventories for South Korea were used for the ozone simulation. During the study period, May 2007, the modeled maximum daily 8-hr average ozone concentration among seven air quality monitors in Gwangyang-bay was 68.8 ppb. The contribution of $NO_x$ emissions from China was 19.5 ppb (28%). The highest modeled ozone concentrations and Chinese contributions appeared when air parcels were originated from Shanghai area. The observed 8-hr average ozone concentrations in Gwangyang Bay exceeded the national ambient air quality standard (60 ppb) 203 times by daytime and 56 times by nighttime during the period. It was noticed that many exeedances happened when contribution of Chinese emissions to ozone concentrations over the area increased. Sensitivity analysis shows that a reduction in Chinese $NO_x$ and VOC emissions by 15% could lessen the total exceedance hours by 24%. This result indicates that high ozone concentrations over Gwangyang-bay are strongly enhanced by Chinese emissions.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.5
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• pp.71-80
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• 2012

To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

• Advances in aircraft and spacecraft science
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• v.1 no.3
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• pp.311-330
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• 2014

Environmental impact of aircraft emissions can be addressed in two ways. Air quality impact occurs during landings and takeoffs while in-flight impact during climbs and cruises influences climate change, ozone and UV-radiation. The aim of this paper is to investigate airports related local emissions and fuel consumption (FC). It gives flight path optimization model linked to a dispersion model as well as numerical methods. Operational factors are considered and the cost function integrates objectives taking into account FC and induced pollutant concentrations. We have compared pollutants emitted and their reduction during LTO cycles, optimized flight path and with analysis by Dopelheuer. Pollutants appearing from incomplete and complete combustion processes have been discussed. Because of calculation difficulties, no assessment has been made for the soot, $H_2O$ and $PM_{2.5}$. In addition, because of the low reliability of models quantifying pollutant emissions of the APU, an empirical evaluation has been done. This is based on Benson's fuel flow method. A new model, giving FC and predicting the in-flight emissions, has been developed. It fits with the Boeing FC model. We confirm that FC can be reduced by 3% for takeoffs and 27% for landings. This contributes to analyze the intelligent fuel gauge computing the in-flight fuel flow. Further research is needed to define the role of $NO_x$ which is emitted during the combustion process derived from the ambient air, not the fuel. Models are needed for analyzing the effects of fleet composition and engine combinations on emission factors and fuel flow assessment.

• International Journal of Automotive Technology
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• v.6 no.2
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• pp.95-105
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• 2005

Diesel engines have low specific fuel consumption, but high particulate emissions, mainly soot. Diesel soot is suspected to have significant effects on the health of living beings and might also affect global warming. Hence stringent measures have been put in place in a number of countries and will be even stronger in the near future. Diesel engines require either advanced integrated exhaust after treatment systems or modified engine models to meet the statutory norms. Experimental analysis to study the emission characteristics is a time consuming affair. In such situations, the real picture of engine control can be obtained by the modeling of trend prediction. In this article, an effort has been made to predict emissions smoke and NO$_{x}$ using cylinder combustion derived parameters and diesel particulate filter data, with artificial neural network techniques in MATLAB environment. The model is based on three layer neural network with a back propagation learning algorithm. The training and test data of emissions were collected from experimental set up in the laboratory for different loads. The network is trained to predict the values of emission with training values. Regression analysis between test and predicted value from neural network shows least error. This approach helps in the reduction of the experimentation required to determine the smoke and NO$_{x}$ for the catalyst coated filters.

• Asian Journal of Atmospheric Environment
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• v.11 no.1
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• pp.33-36
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• 2017

China is suffering from severe air pollution especially fine $PM_{2.5}$ pollution. In 2015, the annual average $PM_{2.5}$ concentration of the 338 municipal cities was $50{\mu}g/m^3$, 78% cities at or above the prefectural level failed to comply with the $PM_{2.5}$ concentration standards. The $13^{th}$ Five-Year Plan for National Economic and Social Development set the goal that the annual average concentration of $PM_{2.5}$ in the municipal cities which failed to attain the ambient air quality standards shall be decreased by 18% by 2020 (CCCPC, 2016). In this study, an air pollution control scenario during the $13^{th}$ Five-Year Plan period was proposed and the $SO_2$, $NO_x$ and PM emission reductions in response to different measures in 31 provincial-level regions mainland China by 2020 were estimated. The air quality in the target year (2020) was simulated using the WRF-CMAQ model. The results showed that by 2020, the emissions of $SO_2$, $NO_x$ and primary PM in mainland China will be reduced by 4.19 million tons, 3.94 million tons and 4.41 million tons, a drop of 23%, 21% and 25% respectively compared with that in 2015, and the annual average concentration of $PM_{2.5}$ will decrease by 19%. Coal-fired power plant contributes the most pollutant emission reduction.

• Progress in Medical Physics
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• v.27 no.4
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• pp.241-249
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• 2016

The present study used a digital angiography x-ray device to measure the space dose and exposure dose of patients and practitioners using x-ray tube shielding devices developed in our laboratory. The intent of the study was to reduce the space dose within the test room, and to reduce the exposure dose of patients and practitioners. The patient and practitioner exposure doses were measured in five configurations in a human body model. The glass dosimeter was placed on the eye lenses, thyroid glands, left shoulder, right shoulder, and gonads. The beam was collimated at full size and at a 48% reduction for a comparative analysis of the measurements. The space dose was measured with an ion chamber at distances of 50 cm, 100 cm, and 150 cm from the x-ray tube under the following conditions: no shielding device; a shielding device made of 3-mm-thick lead (Pb) [Pb 3 mm shield], and a shielding device made of 3-mm-thick Pb (outside) and 3-mm-thick aluminum (Al) (inside) [Pb 3 mm＋Al 3 mm shield]. The absorbed dose was the lowest when the 3-mm-thick Pb＋3-mm-thick Al shield was used. For measurements made with collimated beams with a 48% reduction, the dose was the lowest at $154{\mu}Gy$ when the 3-mm-thick Pb＋3-mm-thick Al shield was used, and was $9{\mu}Gy$ lower than the measurements made with no shielding device. If the space dose can be reduced by 20% in all situations where the C-arm is employed by using the x-ray tube shielding devices developed in our laboratory, this is expected to play an important role in reducing the annual exposure dose for patients, practitioners, and assistants.

• KSBB Journal
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• v.16 no.4
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• pp.351-355
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• 2001

The information about organic and biomass fractions in sewage is essential for the optimal operation and model calibration of biological treatment processes. In the respect of that oxygen is directly associated with respiration and growth of biomass as well as substrate reduction, the respirometry is well known as a suitable method for the analysis of wastewater composition and active biomass. Thus, the organic and biomass fractions in sewage were measured using respirometry. The fraction of readily biodegradable substrate, slowly biodegradable substrate, inert soluble substrate and inert particular substrate are about 10-16%, 1-8%, 32-50% and 2-47%, respectively. The active heterotrophic biomass fraction is about 10-24%, but the autotrophic biomass was not detected in influent sewage.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.10
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• pp.911-918
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• 2013

The combustion characteristics of an EV (Environmental Vortex) burner (double-cone burner) adopted in a gas turbines are numerically investigated. The mixing of fuel and air is analyzed for reduction of NO emission. To predict the correlation between NO emission and fuel-air mixedness, 1-step and 2-step chemistry models are adopted. The results calculated by 1-step chemistry showed that NO emissions increased by 2% in the case of degraded mixedness and by 169% in the case of improved mixedness, where the temperature in the flame zone was overestimated upstream of the cone. However, the corresponding results calculated by 2-step chemistry showed that NO emission increased by 3% and decreased by 5%, where the flame zone was not formed inside the cone. The latter results agree well with the experimental ones indicating an increase of 63% and decrease of 11% in the respective cases. Despite quantitative errors, NO emissions can be predicted reasonably by the application of the 2-step chemistry model adopted here and design modification of burner for NO reduction can be proposed based on the numerical data.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.12
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• pp.1017-1026
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• 2014

A multi-perforated tube is generally installed between the muffler inlet and in front of selective catalytic reduction (SCR) catalysts in the integrated urea-SCR muffler system in order to disperse the urea-water solution spray uniformly and to make better use of the SCR catalyst, which would result in an increase nitrogen oxide ($NO_x$) reduction efficiency and a decrease in the ammonia slip. The effects of the multi-perforated tube orifice area ratios on the internal flow characteristics were investigated analytically by using a general-purpose commercial software package. From the results, it was clarified that the multi-perforated tube geometry sensitively affected the generation of the bulk swirling motion inside the plenum chamber set in front of the SCR catalyst and to the uniformity index of the velocity distribution produced at the inlet of the catalyst. To verify the analytical results, engine tests were carried out in the ESC and ETC modes. Results of these tests indicated that the larger flow model in the longitudinal direction showed the highest NOx reduction efficiency, which was a good agreement with the analytical results.