• Title/Summary/Keyword: $NO_x$ and CO

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A Theoretical Analysis on Hydrogen Gas Fueled Turbine Engine with No Emissiom Gas (배기가스가 없는 수소가스용 터빈엔진에 대한 이론적 해석)

  • Oh, Byeong-Soo
    • Journal of Hydrogen and New Energy
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    • v.5 no.1
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    • pp.25-31
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    • 1994
  • It is very important factor to reduce air pollution from any engines. Some exhaust gases, as $CO_2$, $NO_X$ and $SO_X$, are the products by combustion of hydrocarbon fuel and air. Hydrogen is clean energy to keep our environment out of air pollution. In this study a turbine engine system is theoretically developed which produces pure water only with no exhaust gas by combustion of hydrogen and stoichiometric oxygen. The thermal efficiency of the whole system can be calculated by calculation of each part.

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A Study on Characteristics of Exhaust Emissions from Domestic Used Diesel Engines (國産 디이젤機關의 汚染物質 排出特性에 關한 硏究)

  • 趙康來;金良均;董宗仁;嚴明道
    • Journal of Korean Society for Atmospheric Environment
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    • v.1 no.1
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    • pp.83-92
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    • 1985
  • In odrder to survey the emission level of air pollutants from diesel vehicles, was measured CO, HC, NOx and smoke of 4 types of domestic-use diesel engines under various conditions. The emission of CO, HC and NOx tested by 6-Mode test method and smoke emission by full load test met the permissible vehicle emission standard. Pollutant emission rates of diesel engines were different according to engine operating conditions, that is, engine load and engine speed. Generally, CO and HC was emitted more at low load and NOx at high load but the trend was quite different by the type of engines. In exhaust gas, $NO_2$ portion of NOx emission was high, specially at low speed and low load. The correlation equation between CLD(NOx) and NDIR(NO) method of nitrogen of nitrogen oxides analysis was y = 1.10x - 3.48 (y: CLD method) as a result of 6-mode test.

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Effect of reaction temperature on the particle size and crystal shape of precipitated calcium carbonate (반응온도가 침강성탄산칼슘의 입도 및 형상에 미치는 영향)

  • 송영준;박찬훈;조동성
    • Resources Recycling
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    • v.4 no.1
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    • pp.38-45
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    • 1995
  • The objective of this study was to investigate the effect of temperature on the formation of CaCO, polymorphs(i.e.,calcite, aragonite, vaterite) and on the crystal shape of CaCO,.The reaction systems were rnvestigated at the temperature range of 2.0%-85.3r, at the fixed cmditions ofconcentration and pressure, 2X10-' M, atomospheric pressure, respectively.The reaction systems studied include a Ca(HCO.,),-Air bubble, O Ca(OH)s-CO,, @ Ca(OH),-H,CO, ,Ca(OH1,-Na>CO,, O Ca(OH),-K,CO,, @ Ca(OH),-(NH,),CO,, D CaC1,-Na,CO,, CaC1,-K3C03, 8 CaC1,-(NH,,),CO,, 0 Ca(N0,X-Na,CO,, 03 Ca(N0,X-QCO,. 0 Ca(NO,),-(NH,XCO,. The results obtained are summarizedas follows:Calcite is formed at the temperature range of 2t-80"C and the highest calcite yield was obtained at 30%.Aragonite begins to be formed at the temperature range of 41.0%-53.0%. and the higher temperature is thehigher yield is obtained. pH of the reaction system affect the yield of aragonite, and the yield reaches the highestpercentage at the pH range of 10.0-11.0, and at the conditions of pH 12.3 or over, aragonite is scarcely formed.Vaterlle is fnrmed at the temperature range of 40.0% or less, and transites utterly to calcite within 10-60mmutes in the case of bemg residenced in mother liqmd which C1 is not contained, and within 140hours inthe case of containing CI-.s in the case of containing CI-.

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Phosphorus Removal by DPAOs (Denitrifying Phosphorus Accumulating Organisms) in Aerobic Condition (호기 조건에서 DPAOs (Denitrifying Phosphorus Accumulation Organisms)에 의한 인 제거)

  • Jeong, No-Sung;Park, Young-Seek;Kim, Dong-Seog
    • KSBB Journal
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    • v.25 no.1
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    • pp.62-66
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    • 2010
  • This study was carried out to get phosphorus uptake rate in aerobic condition with nitrate and nitrite. Nitrate and nitrite inhibited phosphorus accumulating organisms' (PAOs') luxury uptake in aerobic condition. Nitrite awfully decreased the phosphorus uptake rate in aerobic condition. At the influent of 10 mg ${NO_3}^-$-NL, the phosphorus uptake was decreased to 52% comparing that at no influent of nitrate. And at the influent of 10 mg ${NO_2}^-$-NL, the phosphorus uptake was decreased to 28% comparing that at no influent of nitrite. At the influent of 20 mg ${NO_3}^-$-NL, nitrite and nitrate were co-existed and the phosphorus uptake rate was decreased to 16% comparing that at no influent of nitrite and nitrate. Also, the denitrification was occurred by denitrifying glycogen accumulating organisms (DGAOs)/denitrifying phosphorus accumulating organisms (OPAOs) in spite of aerobic condition, and the phosphorus uptake rate was increased by the decrease of influent nitrate concentration at the aerobic condition. The inflection point in the phosphorus uptake rate was shown at the nitrite concentration of 1.5~2 mg/L.

The Studies of Photocatalyst Development and the Optimum Operation Conditions for the Removal of Ammonia in a Mixed Reactor of Liquid-vapor Phase (기-액 복합 광반응기에서의 악취성 암모니아 제거를 위한 촉매개발과 반응시스템의 최적조건 색출 연구)

  • Kim, Hae-Ri;Jeon, Min-Kyu;Kim, Joon-Woo;Joo, Gwang-Tae;Choung, Suk-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.512-522
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    • 2008
  • Ammonia is a major compound of odor in livestock house. To enhance the performance of ammonia oxidation (decomposition). the gas-liquid, two phase photocatalytic oxidation system was designed and prepared in this study. Commercial P-25 as $TiO_2$ catalyst was used for ammonia decomposition. V/P-25 catalyst prepared by sol gel method was also used for the removal of by-producted $NO_x$ in $NH_3$ oxidation reaction. When $TiO_2$ was used as a photocatalyst, the conversion to $N_2$ in ammonia decomposition reached above 90% until 200hr (The air flow rate of 4L/min with the ammonia concentration up to 25ppm.). However, considerable amounts of NO and $NO_2$ were formed as a result of $NH_3$ oxidation (as a by-product). Therefore, we added Vanadia impregnated $TiO_2$(P-25) catalyst for the removal of $NO_x$ at the end of reaction trail. The results of a pilot-scale operation were successful to achieve the simultaneous removal of $NH_3\;and\;NO_x$ about 81 and 87%, respectively.

A Precipitation of Ammonium Uranyl Carbonate from Uranylnitrate Solution (UO$_2$(NO$_3$)$_2$ 용액으로부터 Ammonium Uranyl Carbonate 제조)

  • 김응호;김형수;이규암;유재형;최청송
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.559-568
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    • 1998
  • Studies of preparation condition and characteristics of AUC(ammonium uranyl carbonate) were carried out to optimize AUC process with different reactor sizes and precipitation methos. As results four types of precipitates with different chemical compositions and morphologies were obtained from the reaction of {{{{ {(NH }_{4 }) { }_{2 } {CO }_{3 } }} with {{{{ {UO }_{2 }( {NO }_{3 }) { }_{2 } }} solution. A phase diagram has been made and crystal structure and chemical composition of each phase have been characterized by using SEM X-ray IR and thermal analysis. It was found that ammonium uranyl carbonate {{{{ {(NH }_{4 }) { }_{4 } {UO }_{2 } {(CO }_{3 }) { }_{3 } }} with monoclinic crystal morphology could be syn-thesized when the mole ratio of in {{{{ {(NH }_{4 }) { }_{2 } {CO }_{3 }/ {UO }_{2 } {(NO }_{3 }) { }_{2 } }} in the solution was higher than 5 Also a mechanism and a precipitating condition on rounding of the AUC particle were examined in the course of the AUC pre-cipitation. The rounding of the AUC particle was possible only by external circulation using pump not by internal circulation using agitator.

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Physico-chemical Changes of Commercial Ssamjang during Storage (공장식 쌈장의 저장기간에 따른 이화학적 성분변화)

  • Kim, Yong-Kook;Kim, Seong-Ju;Han, Min-Soo;Chang, Young-Il;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.389-396
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    • 2005
  • Physico-chemical properties of ssamjang prepared by industrial process were investigated. Overall experiments were planned by central composite design for five independent variables, kochujang mash aging period $(X_{1})$, doenjang aging period $(X_{2})$, doenjang content $(X_{3})$, sterilization temperature $(X_{4})$, and storage temperature $(X_{5})$. Storage period had no consistent effect on moisture content of ssamjang. Doenjang having longer aging period showed lower moisture content than that having shorter aging period. Titratable acidity and pH of ssamjang gradually increased and decreased with storage period, respectively, with pH of ssamjang significantly affected by aging period of doenjang and kochujang mashes, and sterilization and storage temperatures. Amino nitrogen contents of ssamjang increased during storage and were more affected by sterilization temperature than by aging period and content of doenjang, and storage temperature. Crude protein content of ssamjang irregularly changed during storage, and was slightly affected by content of doenjang.

Air pollution study using factor analysis and univariate Box-Jenkins modeling for the northwest of Tehran

  • Asadollahfardi, Gholamreza;Zamanian, Mehran;Mirmohammadi, Mohsen;Asadi, Mohsen;Tameh, Fatemeh Izadi
    • Advances in environmental research
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    • v.4 no.4
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    • pp.233-246
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    • 2015
  • High amounts of air pollution in crowded urban areas are always considered as one of the major environmental challenges especially in developing countries. Despite the errors in air pollution prediction, the forecasting of future data helps air quality management make decisions promptly and properly. We studied the air quality of the Aqdasiyeh location in Tehran using factor analysis and the Box-Jenkins time series methods. The Air Quality Control Company (AQCC) of the Municipality of Tehran monitors seven daily air quality parameters, including carbon monoxide (CO), Nitrogen Monoxide (NO), Nitrogen dioxide ($NO_2$), $NO_x$, ozone ($O_3$), particulate matter ($PM_{10}$) and sulfur dioxide ($SO_2$). We applied the AQCC data for our study. According to the results of the factor analysis, the air quality parameters were divided into two factors. The first factor included CO, $NO_2$, NO, $NO_x$, and $O_3$, and the second was $SO_2$ and $PM_{10}$. Subsequently, the Box- Jenkins time series was applied to the two mentioned factors. The results of the statistical testing and comparison of the factor data with the predicted data indicated Auto Regressive Integrated Moving Average (0, 0, 1) was appropriate for the first factor, and ARIMA (1, 0, 1) was proper for the second one. The coefficient of determination between the factor data and the predicted data for both models were 0.98 and 0.983 which may indicate the accuracy of the models. The application of these methods could be beneficial for the reduction of developing numbers of mathematical modeling.

Magnetoresistance of the Ferromagnetic Combined System

  • Park, Seung-Iel;Kim, Chul Sung
    • Journal of Magnetics
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    • v.9 no.1
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    • pp.5-8
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    • 2004
  • For the ferromagnetic combined samples, results of x-ray diffraction patterns showed no evidence of reaction between the $La_{0.67}Ca_{0.33}MnO_3, La_{0.67}Sr_{0.33}MnO_3$ and $CoFe_2O_4$. For the amount of $CoFe_2O_4$ increased, the Curie temperature of combined samples showed no appreciable change, whereas a metal-semiconductor transition temperature rapidly decreased. For the $La_{0.67}Sr_{0.33}MnO_3$ and 20 wt % $CoFe_2O_4$ combined sample, the metal-semiconductor transition temperature was decreased to 160 K compared with the $La_{0.67}Sr_{0.33}MnO_3$ with 192 K.

Structural and Magnetic Properties of perpendicular Recording Medium CoCrMo thin Film (수직자기기록매체 CoCrMo 박막의 구조와 자기적 성질)

  • 남인탁;홍양기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.46-46
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    • 1988
  • Structural and magnetic properties of Co-Cr-Mo films were investigated in connection with sputtering conditions. Films were prepared using a convention RF sputtering system. X-ray diffractometry, scanning electron microscopy and transmission electron microscopy were employed to investigate structure properties. Vibrating sample magnetometry was used for coercivity and saturation magnetization measurements. Co-Cr-Mo films displayed reasonable values of perpendicular coercivity and saturation magnetization for perpendicular recording media and showed good perpendicular orientation of the hcp c-axis to the film surface. Perpendicular coercivity was strongly dependent upon substrate technique showed better c-axis orientation than hose using the stationary substrate. Co-Cr-Mo films of 2.9 at. % Mo content showed maximum perpendicular coercivity and saturation magnetization. The films deposited at lower Ar pressure showed good magnetic properties. There was no explicit relationship between the columnar structure and c-axis orientation. Co-Cr-Mo films was found to have suitable structural and magnetic properties for perpendicular recording media.

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