• Applied Chemistry for Engineering
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• v.29 no.1
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• pp.103-111
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• 2018

A plasma-catalytic combined process was used as an attempt to improve the conversion efficiency of nitrogen oxides ($NO_x$) over a wide temperature range ($150{\sim}500^{\circ}C$) to cope with the exhaust gas whose temperature varies greatly. Since the catalytic $NO_x$ reduction is effective at high temperatures where the activity of the catalyst itself is high, the $NO_x$ reduction was carried out without plasma generation in the high temperature region. On the other hand, in the low temperature region, the plasma was created in the catalyst bed to make up for the decreased catalytic activity, thereby increasing the $NO_x$ conversion efficiency. Effects of the types of catalysts, the reaction temperature, the concentration of the reducing agent (n-heptane), and the energy density on $NO_x$ conversion efficiency were examined. As a result of comparative analysis of various catalysts, the catalytic $NO_x$ conversion efficiency in the high temperature region was the highest in the case of the $Ag-Zn/{\gamma}-Al_2O_3$ catalyst of more than 90%. In the low temperature region, $NO_x$ was hardly removed by the hydrocarbon selective reduction process, but when the plasma was generated in the catalyst bed, the $NO_x$ conversion sharply increased to about 90%. The $NO_x$ conversion can be maintained high at temperatures of $150{\sim}500^{\circ}C$ by the combination of plasma in accordance with the temperature change of the exhaust gas.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.3
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• pp.330-336
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• 2005

The ozone injection method was proposed to improve the catalytic process for the removal of nitrogen oxides ($NO_x$). Nitric oxide (NO) in the exhaust gas was first oxidized to nitrogen dioxide ($NO_2$) by ozone produced by dielectric barrier discharge, and then the exhaust gas containing the mixture of NO and $NO_2$ was directed to the catalytic reactor where both NO and $NO_2$ were reduced to $N_2$ in the presence of ammonia as the reducing agent. A commercially available $V_2O_5-WO_3/TiO_2$ catalyst was used as the catalytic reactor. The $NO_2$ content in the mixture of NO and $NO_2$ was changed by the amount of ozone added the exhaust gas. The effect of reaction temperature, initial $NO_x$ concentration, feed gas flow rate, and ammonia concentration on the removal of $NO_x$ at various $NO_2$ contents was examined and discussed. The increase in the content of $NO_2$ by the ozone injection remarkably improved the performance of the catalytic reactor, especially at low temperatures. The present ozone injection method appears to be promising for the improvement of the catalytic reduction of $NO_x$.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.5
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• pp.659-667
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• 2018

$NO_x$ and $SO_2$ are mainly generated in the combustion of fossil fuels, and they cause secondary aerosol formation and acid rain in the atmosphere. Many studies have been conducted on the wet scrubbing process which can simultaneously reduce $NO_x$ and $SO_2$ at relatively low temperature. In this study, we conducted an experimental study on wet scrubbing by using NaOH solution. Especially, this study focuses on $NO_x$ and $SO_2$ removal characteristics by varying $NO_2/NO_x$ ratio and $SO_2$ concentration.

• KSBB Journal
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• v.25 no.1
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• pp.62-66
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• 2010

This study was carried out to get phosphorus uptake rate in aerobic condition with nitrate and nitrite. Nitrate and nitrite inhibited phosphorus accumulating organisms' (PAOs') luxury uptake in aerobic condition. Nitrite awfully decreased the phosphorus uptake rate in aerobic condition. At the influent of 10 mg ${NO_3}^-$-NL, the phosphorus uptake was decreased to 52% comparing that at no influent of nitrate. And at the influent of 10 mg ${NO_2}^-$-NL, the phosphorus uptake was decreased to 28% comparing that at no influent of nitrite. At the influent of 20 mg ${NO_3}^-$-NL, nitrite and nitrate were co-existed and the phosphorus uptake rate was decreased to 16% comparing that at no influent of nitrite and nitrate. Also, the denitrification was occurred by denitrifying glycogen accumulating organisms (DGAOs)/denitrifying phosphorus accumulating organisms (OPAOs) in spite of aerobic condition, and the phosphorus uptake rate was increased by the decrease of influent nitrate concentration at the aerobic condition. The inflection point in the phosphorus uptake rate was shown at the nitrite concentration of 1.5~2 mg/L.

• Journal of the Korean earth science society
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• v.42 no.2
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• pp.149-163
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• 2021

In this study, the changes in ozone (O3) concentrations due to the removal of power plant emissions were analyzed using a community multi-scale air quality (CMAQ) model. Two different CMAQ model simulations, one considering the emissions from the Hadong power plant and one without considering the emissions, were conducted to investigate the effect of the emissions on the changes in the O3 concentrations in the surrounding areas. Subsequently, the CMAQ simulations exhibited an increase in the O3 concentration (25.24%) despite a decrease in the NOx (-18.87%) and volatile organic carbon (VOC, -11.27%) concentrations, which are major O3 precursors. The changes in the NO and O3 concentrations due to the removal of power plant emissions presented a strong negative correlation (r= -0.72). This indicated that the increase in the O3 concentration was mainly attributed to the significantly decreased NO concentration, thus, mitigating the O3 titration reaction (NO+O3→NO2+O2). Additionally, due to the VOC-limited (i.e., NOx-saturated) conditions in the study region, NO affected the O3 concentration, indicating that the O3 concentrations in a particular region are not only proportional to the increase or decrease in emissions. Therefore, an in-depth understanding of the chemical O3 production and loss in a particular region is necessary to accurately evaluate the effect of emission control on the changes in the O3 concentration.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.8 no.2
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• pp.179-184
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• 2007

In this paper, the ventilation characteristics of an underground parking lot with 17 buses has been investigated for two cases by computational fluid dynamics. It has been found that the average concentration of CO and $NO_x$ gas in the parking lot were 1.3 and 0.3 ppm respectively, when four buses operated. When the fifteen vehicles stopped in the parking lot, the average concentration of CO and $NO_x$ gas was 2.9 and 0.8 ppm respectively. The average concentration of two pollutants$(CO,\;NO_x)$ are lower than the standard values. Therefore the facilities and its location is proper to ventilation.

• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.328-336
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• 2005

In order to remove the NO contained in exhaust gas by the non-selective catalyst reduction method, the catalysts were prepared by varing the loading amount of Ag and V into ${\gamma}-Al_2O_3$. The conversion of $NO_x$ using the prepared catalysts was studied by varying the temperatures, $O_2$ concentrations and $SO_2$ concentrations using. The influence of the catalyst structure on $NO_x$ conversion was studied through the analysis of the physical properties of the prepared catalysts. In the case of $AgV/{\gamma}-Al_2O_3$ catalyst, the $NO_x$ conversion was lower than that of $Ag/{\gamma}-Al_2O_3$ at higher temperatures but higher than that of $Ag/{\gamma}-Al_2O_3$ at lower temperatures. Even though $SO_2$ was contained in the reaction gas, the $NO_x$ conversion did not decrease. Based on the analysis including XRD, XPS, TPR, and UV-Vis DRS before and after the experiments, the experimental results were examined. The results indicated that, $NO_x$ conversion decreased at higher temperatures since Ag oxide could not be maintained well due to the addition of V, whereas it increased at temperatures lower than $300^{\circ}C$ due to the catalytic action of V.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2004.11a
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• pp.451-452
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• 2004

• Journal of agriculture & life science
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• v.46 no.6
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• pp.51-57
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• 2012

This study was carried out to analyze chemical compositions of the fog water of a forest area, Jinju and to provide basic information for establishing measures on the acid fog water of forest area. The results are as follows: The pH of fog water was 4.3 in 2010, whereas the pH in 2011 was 4.0. The electrical conductivity of the fog water was $477.2{\mu}s$ in 2010, and $562.7{\mu}s$ in 2011. Among the anions, the concentration of $NO^{3-}$ was the highest, which recorded 267.1 mg/L in spring season and 279.1 mg/L in summer season, followed by $SO{_4}^{2-}$ at the concentration of 177.2 mg/L in spring season and 198.6mg/L in summer season. In autumn and winter, the concentration of $NO^{3-}$ was highest as 217.7 mg/L and 237.9 mg/L, respectively and followed by $SO{_4}^{2-}$, which concentration was 164.2 mg/L in autumn season and 190.1 mg/L in winter season (p<0.05). Among the cations, the concentration of $Ca^{2+}$ was 221.3 mg/L in spring and 233.7mg/L in summer, followed by $Na^+$ at 125.1 mg/L in spring season and 131.7 mg/L in summer In autumn and winter, the concentration of $Ca^{2+}$ was highest at 196.8 mg/L and 198.8 mg/L, followed by $Na^+$ at the concentration of 97.1 mg/L in autumn and 117.2 mg/L in winter (p<0.05). The pH of the fog rain that causes acid mist showed the correlation with $Ca^{++}$ (1% of level), $EC(r=-0.9861^{**})$, $NO^{3-}$ ($r=-0.9677^{**}$), and $SO{_4}^{2-}$ ($r=-0.9510^{**}$). The regression equation on the factors affecting the generation of acidic fog rain was estimated to be a $Y(pH)=6.4627+0.9723X_2(EC)+0.9364X_4(NO_3{^-})+0.9044X_5(SO{_4}^{2-})+0.8049X_{10}(Ca^{2+})+0.6709X_8(K^+)\;(r^2=0.8787)$.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.411-412
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• 1999

대기 독성물질과 이산화질소, 이산화탄소를 포함한 다른 오염물질은 인간의 건강과 쾌적함이라는 개념하에서 시각화되었고 그 중에서 질소산화물의 상태는 CO와 HC를 다루는 것보다 도시에서 훨씬 어려운 실정이다. 도시지역에서 대기오염물질 농도는 오염물질의 누적을 유발하는 요소와 오염물질의 확산을 유발하는 요소사이의 균형에 의해서 제어를 받고 있다.(중략)