• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1613-1618
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• 2014

Perovskite-type oxides are promising oxygen carriers in producing oxygen-enriched $CO_2$ gas stream for oxyfuel combustion. In this study, a new series of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ (x = 0.2, 0.4, 0.6, 0.8) was prepared and used to produce $O_2/CO_2$ mixture gas. The phase, crystal structure, and morphological properties of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ were investigated through X-ray diffraction, specific surface area measurements, and environmental scanning electron microscopy. The oxygen desorption performance of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ was studied in a fixed-bed reactor system. Results showed that the different x values of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ have no obvious effects on crystalline structure. However, the oxygen desorption performance of $SrCo_{1-x}Fe_xO_{3-{\delta}}$ is improved by Co doping. Moreover, $SrCo_{0.8}Fe_{0.2}O_{3-{\delta}}$ synthesized via a new EDTA method has a larger BET surface area ($40.396m^2/g$), smaller particle size (48.3 nm), and better oxygen production performance compared with that synthesized through a liquid citrate method.

• Particle and aerosol research
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• v.17 no.4
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• pp.133-148
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• 2021

This study aims to estimate the amount of air pollutants emitted from heavy industry facilities in North Korea. To compare the emission in 2017 from the heavy industry sector in North Korea with South Korea, the heavy industry sector was classified with the South Korean classification (Matching Heavy Industry sector) and air pollutant emissions by Matching Heavy Industry sector in North Korea were estimated. The CO, NO_x and SO_x emissions of Matching Heavy Industry sector in North Korea are 22%, 73%, and 31% of the emission in South Korea, respectively. The air pollutant emissions in the Matching Heavy Industry sector in North Korea for CO, NO_x and SO_x were 0.6%, 124%, and 24% of the total air pollutant emission in North Korea estimated from EDGAR, respectively. As for the distribution of emissions by administrative district of the Matching Heavy Industry sector in North Korea, NO_x was concentrated in the western part of North Korea, and CO and SO_x emissions were concentrated in Hamgyong-bukto.

• Journal of the Korean Ceramic Society
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• v.42 no.3 s.274
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• pp.211-217
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• 2005

[ $Zn_{1-x}Co_{x}O$ (x=0-0.3) films were grown on Corning 7059 glasses by asymmetrical bipolar pulsed dc magnetron sputtering. The c-axis orientation along (002) plane was enhanced with increasing Co concentration. The $Zn_{1-x}Co_{x}O$ films are grown with fibrous grains of tight dome shape. The transmittance spectra measured from UV-visible showed that sp-d exchange interactions and typical d-d transitions become activated with increasing Co concentration. The electrical resistivity of $Zn_{1-x}Co_{x}O$ films increased with increasing Co concentration, especially it increased greatly at $30at\% Co. X-ray photoelectron spectroscopy and alternating gradient magnetometer analyses indicated that no Co metal cluster is formed and the ferromagnetic properties are exhibited. The low electrical resistivity and room temperature ferromagnetism of $Zn_{1-x}Co_{x}O$ thin films suggested the possibility of the application to Diluted Magnetic Semiconductors (DMSs).

• New & Renewable Energy
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• v.16 no.3
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• pp.13-26
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• 2020

This study analyzed whether the diffusion of new and renewable energy contributed to mitigating emissions of various air pollutants, including particulate matter, using panel econometric models. The theoretical foundation of such econometric models is based on the Environmental Kuznets Curve (EKC) hypothesis, which assumes an inverted U-shaped relation between national income and environmental pollution, as originally proposed by Grossman and Krueger. We examined whether there are inverted U-, U-shaped, or N-shaped relations between national income and air pollution. We demonstrate that increases in new and renewable energy significantly mitigated emissions of CO, NO_X, and PM2.5. Additionally, we included NO_X, SO_X, PM10, and VOCs as secondary emission sources of PM2.5 and found that emission of PM10 resulted in the highest PM2.5 emissions, followed by NO_X and SO_X emissions. The impact of new and renewable energy on air pollution varied across regions. Increase of new and renewable energy in the Honam region significantly mitigated CO, NO_X, and TSP emissions, while that in the Youngnam and metropolitan areas did not significantly mitigate air pollution overall. There was a U-shaped relationship between air pollution and national income for CO, NO_X, PM2.5, and SO_X, while an inverted N-shape was observed for PM10.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.233-234
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• 2014

Lean-rich combustion system was composed both fuel-lean and fuel-rich flame at once. Each of fuel-lean and fuel-rich combustion types to reduce Thermal $NO_x$ and obtain flame stability. This study was confirmed a stability of flame through variation of flame shape that EGR was applied and compared the emission characteristics of EGR lean-rich combustion system to normal premixed combustion system at real condition to review a utility of the system. As a result, emission index of $NO_x$ and CO generated from EGR lean-rich combustion system at global equivalence ratio is 0.85 just half level($NO_x$ 0.31 g/kg, CO 0.08g/kg) compared to the amount generated from normal premixed combustion system at equivalence ratio is 0.78.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.7
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• pp.823-832
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• 2007

This paper presents the static characteristics of EGR-WI combined system. The water injection system was statically characterized by recording the engine exhaust outlet $NO_x$ emissions for comparison with baseline $NO_x$ emissions. Effects of the water injection system on CO and HC emissions and fuel consumption were examined. The research engine used for these experiments was a 103 kW turbocharged, intercooled, 2.5 L VM Motori CIDI engine equipped with a cooled EGR system. Water injection in the intake system demonstrated the potential for significant reductions in engine outlet $NO_x$ emissions. The system has reduced engine outlet $NO_x$ emissions by 40-50%, but caused significant increases in CO and HC emissions, particularly at low loads. Fuel consumption effects were minimal.

• Microbiology and Biotechnology Letters
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• v.22 no.2
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• pp.164-168
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• 1994

Identification of the Actinomycetes isolate strain No. 1372, a producer of Actinomycin X$_{2}$ was performed by using ISP method.l The strain, designated as No. 1372, was identified as Streptomyces floridae based on its morphological, physiological and biochemical characteristics. The highest production of the antibiotics by the strain was achieved in a fermentation medium containing soluble starch, yeast extract, (NH$_{4}$)SO$_{4}$, K$_{2}$HPO$_{4}$, NaCl$_{2}$, CaCO$_{3}$, and trace element.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.7
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• pp.70-75
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• 2014

The experiment was done on traveling at the speed of 20km/h, 60km/h and 100km/h using the performance testing mode for chassis dynamometer. The experimental method were employed to measure the waveform of secondary ignition coil and exhaust emission. In this experiment, the correlation between the secondary waveform coming from ignition coil and exhaust emission were measured in decrepit vehicle. The secondary waveform characterized by the value of effective discharge energy. The following results are obtained by analyzing the data relativity between the effective discharge energy and exhaust emission. The variation rate of effective discharge energy was largest 60km/h, 20km/h, 100km/h velocity in the ordered named. As the vehicle velocity increases, the average variation rate of CO and $NO_X$ decreases and that of HC and $CO_2$ decrease. The value of effective discharge energy, CO, $NO_X$ and fuel consumption is measured badly in case of car with failures in MAP, spark plug and good in case of car with before and after maintenance regardless of vehicle velocities. The value of effective discharge energy is to be nearly parabolic shape as vehicle velocity increases. As the value of effective discharge energy increases, the value of $NO_X$, HC and $CO_2$ decrease, the value of CO increase. The most sensible factors of exhaust emission were CO, $NO_X$, and the small variation factors were HC, $CO_2$.

• Journal of the Korean Society for Precision Engineering
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• v.16 no.7
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• pp.196-202
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• 1999

Recent trend changes a criterion for evaluation of burner that environmental problem is raised as global issue. For efficient driving problem, the higher thermal efficiency and the lower oxygen in exhaust gas, burner is evaluated the better. For environmental problem, burner must satisfy $NO_{X}$ limit and CO limit. Consequently, 'good burner' means on whose thermal efficiency is high under the constraint of $NO_{X}$ and CO consistency. To make existing burner satisfy recent criterion, it is highly recommended to develop feedback control scheme whose output is the consistency of $NO_{X}$ and CO. This paper describes development of real time flame diagnosis technique that evaluate and diagnose combustion state such as consistency of components in exhaust gas, stability of flame in quantitative sense. This study focuses on wave length of luminescence from chemical reaction measurement of the luminescence via optical measuring apparatus and derive correlation with consistency of components in exhaust gas by image processing technique.

• Bulletin of the Korean Chemical Society
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• v.18 no.12
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• pp.1249-1256
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• 1997

Single phase La1-xSrxCoO3 (x≤0.2) was synthesized as a uniform sized 100 nm particulates with relatively high surface area of 20-30 m2/g, at low temperature (≥600 ℃), from a polymeric gel precursors prepared by using poly(vinyl alcohol) as homogenizer. No minor phase developed during the crystallization when polymer/metal mole ratio was higher than 3. As the polymer/metal mole ratio was raised in the gel, the amount of carbonaceous residues in the amorphous solid precursor prepared by heating the gel at 300 ℃ increased. Most of the residues were eliminated by exothermic thermal decomposition around 400 ℃. The amount of residual carbon (less than 1%) left in the crystalline La1-xSrxCoO3 decreased as more polymer was used, eliminating detrimental effect which might be posed by using large amount of organic homogenizer. The crystal structure of La1-xSrxCoO3 synthesized at temperature lower than 800 ℃ was observed to be shifted from rhombohedral to more symmetric cubic. The structure shifted back to rhombohedral as the cubic sample was annealed at 1000 ℃.